TCPP (TRIS(2-CHLOROISOPROPYL)-PHOSPATE – (TRS(2-KLOROIZOPROPL)-FOSFAT)
TCPP (TRIS(2-CHLOROISOPROPYL)-PHOSPATE
SYNONYMS:
TCPP; tcpp; Tcpp; 2-Propanol; 1-chloro; phosphate (3:1); Tris(monochloroisopropyl) phosphate (TMCP); Tris(2-chloroisopropyl) phosphate (TCIP); Phosphoric acid; tris(2-chloro-1-methylethyl) ester; tcpp; Tris(beta-chloroisopropyl) phosphate,; tcpp; 1-Chloro-2-propanol phosphate (3:1); Tris(2-chloroisopropyl) phosphate; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Triozephosphate tris(2-chloroisopropyl) phosphate; Tcpp; Phosphoric acid tris(2-chloro-1-methylethyl) ester; Triozepropylphosphate; triis2-chloroisopropylfosfat; TCpp; Tris(2-chloroisopropyl)phosphate; triphosphate; Triosephosphate; (2-kloropropil); tris(2chloropropyl)phosphate; TRISPHOSPHATE; TCPP; Trisphospate; Tris(2kloropropyl)phospate; tcpp; Tris(2-chloropropyl)phospate; tcpp; TRIS(2-CHLOROPROPYL)PHOSPATE; tcpp; tris(2-chloropropyl)phosphate(2-chloroisopropyl)phosphate; Tris(2-chloro-1-methylethyl)phosphate; Trioz-fosfat triozfosfat; triosphospate; triosfosfat; triozphospate; tcpp; tris2-chloroisopropyphospate; tris2-Chloroisopropilphospate; TCPP; tris2chloroisopropylphospate; TRIS(2 KLOROISOPROPIL) FOSFAT; tcpp; TRS(2-KLOROSOPROPL)FOSFAT; TCPP; tcpp; Tcpp; Tris (2-kloroizopropil) fosfat; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Phosphoric acid tris(2-chloro-1-methylethyl) ester; Tcpp; Triozfosfat tris (2-kloroizopropil) fosfat; Triozepropilfosfat; tri-kloroizopropil) fosfat; trifosfat; Triosfosfat; (2-kloropropil); tris (2-kloropropil) fosfat; TCPP; TRISPHOSPHATE; Trisfosfat; Tris (2-kloropropil) fosfat; Tris (2-kloropropil); TRIS (2-CHLPOPPOPR); (2-kloropropil); 2-kloropropil fosfat; Amgard TMCP; Tris(1-chloro-2-propyl)phosphate; TCPP; amgardtmcp; hostaflamop820; TCPP (FYROL PCF); Flame Retardant TCPP; TCPP; mixture of isomers; Tris(1-chloropropan-2-yl); 1-chloro-2-propano phosphate; TRIS(1-CHLOROPROPYL)PHOSPHATE;Tri(chloroisopropyl)phosphate; 2-propanol; 1-chloro,phosphate; alev geciktirici; Alev geciktirici; Alev geciktirici TCPP; Tris (2-kloroizopropil) fosfat; Trioz-fosfat; triofosfat; triosfosfat; triozfosfat; tris2-kloroizopropil fosfat; top2-KloroFenopropil; TCPP; tcpp; Tcpp; Tris(2-chloroisopropyl)phosphate; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT; (TCPP); Triozephosphate; tris(2-chloroisopropyl) phosphate; Triozepropylphosphate; triis2-chloroisopropylfosfat; Tris(2-chloroisopropyl)phosphate; triphosphate; Triosephosphate; (2-kloropropil); tris(2-TRIS(2-CHLOROPROPYL)PHOSPATE; chloropropyl)phosphate; Tris(2chloroisopropyl)phosphate; triozfosfat; triosphospate; triosfosfat; triozphospate; tcpp; tris2chloroisopropylphospate; TCPP; tris2Chloroisopropilphospate; TRIS(2KLOROISOPROPIL)FOSFAT; TRS(2-KLOROSOPROPL)FOSFAT; TCPP; tcpp; Tcpp; Tris (2-kloroizopropil) fosfat; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Triozfosfat tris (2-kloroizopropil) fosfat; TCPP; Triozepropilfosfat; tri-kloroizopropil) fosfat; trifosfat; Tcpp; Triosfosfat; (2-kloropropil); tris (2-kloropropil) fosfat; TRISPHOSPHATE; Trisfosat; Tris (2-kloropropil) fosfat; Tris (2-kloropropil); TCPP; TRIS (2-CHLPOPPOPR); (2-kloropropil); (2-kloropropil) fosfat; alev geciktirici; Tris (2-kloroizopropil) fosfat; Trioz-fosfat; triozfosfat; tcpp; triosfosfat; triozfosfat; tris2-kloroizopropil fosfat; TRS2-KloroFenopropil; TCPP; ALEV GECKTRC; Tris(2-chlTCPP); Tris(2-chloroisopropyl)phosphate; (TCPP); TCPP; tcpp; Tcpp; 2-Propanol; 1-chloro; phosphate (3:1); tcpp; Tris(monochloroisopropyl) phosphate; Phosphoric acid tris(2-chloro-1-methylethyl) ester; (TMCP); Tris(2-chloroisopropyl)phosphate; (TCIP); Phosphoric acid; tris(2-chloro-1-methylethyl) ester; Tris(beta-chloroisopropyl) phosphate; 1-Chloro-2-propanol phosphate (3:1); Tris(2-chloroisopropyl) phosphate; tcpp; Tcpp; tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Triozephosphate; tris(2-chloroisopropyl) phosphate; Triozepropylphosphate; triis2-chloroisopropylfosfat; Tcpp; Tris(2-chloroisopropyl)phosphate; triphosphate; Triosephosphate; (2 kloropropil); tris(2chloropropyl)phosphate; TRISPHOSPHATE; Trisphospate; Tris(2 kloropropyl)phospate; KLOROISOPROPIL)FOSFAT; TRS(2-KLOROSOPROPL)FOSFAT; TCPP; tcpp; Tcpp; Tris (2-kloroizopropil) fosfat; tcpp,; Tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Triozfosfat; tris (2-kloroizopropil) fosfat; tcpp; Triozepropilfosfat; tri-kloroizopropil) fosfat; tcpp; trifosfat; Triosfosfat; (2-kloropropil); tris (2-kloropropil) fosfat; TCPP; TRISPHOSPHATE; Trisfosfat; Tris (2-kloropropil) fosfat; Tris (2-kloropropil); TRIS (2-CHLPOPPOPR); (2-kloropropil) fosfat; alev geciktirici; Alev geciktirici; Tcpp; Alev geciktirici TCPP; Tris (2-kloroizopropil) fosfat; TCPP; Trioz-fosfat; tcpp; triofosfat; triosfosfat; triozfosfat; tris2-kloroizopropil fosfat; top2-KloroFenopropil; TCPP; tcpp; Tcpp; Tris(2-chloroisopropyl)phosphate; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT; (TCPP); Triozephosphate; Tcpp; tris(2-chloroisopropyl) phosphate; Triozepropylphosphate; triis2-chloroisopropylfosfat; Tris(2-chloroisopropyl)phosphate; triphosphate; Triosephosphate; (2 kloropropil); tris(2-TRIS(2-CHLOROPROPYL)PHOSPATE; chloropropyl)phosphate; TRISPHOSPHATE; TCPP; Trisphospate; Tris(2-kloropropyl)phospate; Tris(2-chloropropyl)phospate; tris(2 chloropropyl)phosphate; Tcpp; TCPP; Tris(2chloroisopropyl)phosphate; triozfosfat; tcpp; triosphospate; triosfosfat; TCPP; triozphospate; tris2chloroisopropylphospate; tris2Chloroisopropilphospate; tris2chloroisopropylphospate; TRIS(2-KLOROISOPROPIL)FOSFAT; TRS(2-KLOROSOPROPL)FOSFAT; TCPP; tcpp; Tcpp; tcpp; Tris (2-kloroizopropil) fosfat; tcpp; Tcpp; TRIS (2-KLOROPROPL) FOSFAT (TCPP); Triozfosfat tris (2-kloroizopropil) fosfat; Triozepropilfosfat; tri-kloroizopropil) fosfat; trifosfat; Triosfosfat; (2-kloropropil); tris (2-kloropropil) fosfat; TRISPHOSPHATE; tcpp; Trisfosat; Tris (2-kloropropil) fosfat; Tris (2-kloropropil); tcpp; TRIS (2-CHLPOPPOPR); (2-kloropropil) 2-kloropropil fosfat; alev geciktirici; Tris (2-kloroizopropil) fosfat; Trioz-fosfat; tcpp; triozfosfat; triosfosfat; triozfosfat; tris2-kloroizopropil fosfat; tcpp; TRS2-KloroFenopropil ALEV GECKTRC; tcpp; Tris(2-chlTCPP); tcpp; Tris(2-chloroisopropyl)phosphate; (TCPP); Tris(1-chloro-2-propyl) phosphate; tris(1-chloropropan-2-yl) phosphate; Amgard TMCP; Tris(1-chloro-2-propyl)phosphate; TCPP; amgardtmcp; hostaflamop820; TCPP (FYROL PCF); Flame Retardant TCPP; TCPP; mixture of isomers; Tris(1-chloropropan-2-yl); 1-chloro-2-propano phosphate; TRIS(1-CHLOROPROPYL)PHOSPHATE;Tri(chloroisopropyl)phosphate;2-propanol,1-chloro,phosphate.
Description of TCPP:
Light yellow oily liquid. Slightly creamy. It is soluble in organic solvents such as ethanol, acetone, chloroform, carbon tetrachloride, etc. and slightly soluble in water.
Application of TCPP:
TCPP Mainly used in polyurethane foam flame retardant and PVC flame retardant plasticization, etc.TCPP Widely used in chemical fiber fabrics and cellulose acetate as flame retardant, it can improve water resistance, cold resistance, and antistatic property in addition to self-extinguishing. The general dosage is 5-10 parts. Flame retardant TCPP widely used in cellulose acetate, nitrocellulose, ethyl cellulose, polyvinyl chloride, polyurethane, polyvinyl acetate, and phenolic resin. Used as a flame retardant plasticizer. TCPP can also be used as a metal extractant, lubricating oil and gasoline additive, and polyimide processing modifier. Tcpp the oral toxicity LD50 of rats was 1410mg/kg. Lithium batteries are commonly used as flame retardants. TCPP is used as a flammability agent due to phosphorus and chlorine in its structure. It also has a plasticizer effect. It has low temperature resistance. It is resistant to moisture because it is difficult hydrolysis. It is soluble in benzene and alcohol, while its solubility in water, oil and other hydrocarbons is low. PVC, rigid, flexible polyurethane foam and epoxy resin, polyacrylic fiber, ethyl cellulose resin, phenol-formaldehyde resin .
Benefits and Features of TCPP :A low cost chlorine and phosphorous based flame retardant. TCPP has the best hydrolysis stability among currently available halogenated organic phosphates. Can not dissolve in water, dissolve in most organic solvent, and have good compatibility with resins.
Typical Properties of TCPP:
Appearance Pale yellow transparent Liquid.
Color ( APHA ) 50 max.
Acid Value (mg KOH/g) 0.1max.
Water content %. 0.1 max.
Viscosity (25°C, mPa∙s) . 60-70
Specific gravity(20°C) 1.285 – 1.295
P content % .9.0 – 9.8
Cl content % 32 – 32.8
1% weight loss 10°C
5% weight loss 172°C
10% weight loss 208°C
Refractive index (25℃) 1.460-1.466
These properties are typical but do not constitute a specification either in part or as a whole. TCPP specification data is available on request from sales, customer service or customer technical service.
Tris (2-chloroisopropyl) phosphate (TCPP) Packaging specifications 250 kg / barrel, 1250k / IBC barrel, ISO Tank, flexible container etc. Flame retardant, a flame retardant, plasticizer and viscosity regulator of various polymer types including d-Myo-inositol-1,4,5-rifosphate polyurethanes, polyester resins and polyacrylates. It is believed to replace Tris (2-chloroisopropyl) phosphate (TCPP), an analog of TCEP. However, little is known about the toxicological effects of TCPP compared to TCEP. We used RNA sequencing as an objective and sensitive tool to identify and compare the effects on TCEP and TCPP at the transcriptome level in the human hepatose carcinoma cell line.
We found that TCPP had little cytotoxicity compared to other flame retardants. Treatment with lower cytotoxic concentrations of the two compounds revealed that both chemicals had similar effects; It was found that both compounds affected genes involved in immune responses and steroid hormone biosynthesis, and similarly affected xenobiotic metabolism pathways. Specifically for effects on immune responses, both compounds have been shown to alter the expression of the receptor of the potent and pleiotropic complement component C5a. In addition, it was found that genes encoding effector proteins in the complement cascade were altered in response to TCEP and TCPP, as well as other potent inflammatory regulators, highlighting their potential effects on immune function. Taken together, TCPP has similar effects compared to TCEP, and at low concentrations, the potential health effects of TCPP have similar effects compared to TCEP, where TCPP will need to be further studied for a full risk assessment of the compound. At concentrations, the potential health effects of TCPP are considered to be further studied for a complete risk assessment of the compound. TCPP is a general purpose chlorinated phosphate ester flame retardant used. The superiority is low odor, high heat stability, excellent hydrolysis stability, low viscosity, superior compatibility with resin which shows rigid and flexible polyurethane foams. TCPP is recommended as flame retardant for PU foams, PVC and adhesives.
TCPP is primarily used as flame retardant in rigid and flexible polyurethane foams.
TCPP is insoluble in water and aliphatic hydrocarbons, relative density 1.27 -1.31, refractive index Due to both molecules containing phosphorus and chlorine elements, 1.4916 (21.5), viscosity 58mm2 / S, 32.8% chlorine content, 9.5% phosphorus content, flame retardant properties For polyvinyl plastic, TCPP moisture (2-chloropropyl) phosphate Chloride, polystyrene, phenolic resin and rubber, paint flame retardant, usually used together with antimony chloride, used to increase the Flame Retardant TCPP Effectiveness of Antimony Chloride 3. TCPP Application (2-chloropropyl) phosphate TCPP is mainly used for soft and hard polyurethane foam, chlorinated resin, polyethylene, cellulose acetate, ethyl cellulose resin and phenolic plastic and gun type foam insulation material. TCPP Thermal conductivity and especially for hard polyurethane foams Hydraulic stability, especially for ASTM84 (II), Polyurethane foams for compounds and unsaturated resins and phenolic plastics have low viscosity at low temperatures. TCPP Antioxidants are used together to increase flame retardant effectiveness.
TCPP can be produced in a batch or continuous process. TCPP, the reaction of phosphorus oxychloride with propylene oxide in presses is the cell of a catalyst. The reaction is carried out in a closed reactor. The crude product is washed and dried in a closed vessel to remove acidic impurities and residual catalyst. All transfers are made using closed lines. TCPP The product is then filtered, transferred and packaged using closed pumps via closed lines. Storage is located in closed containers under nitrogen to exclude moisture and oxygen. TCPP is used as flame retardant in rigid and flexible polyurethane foam.
TCPP Genel Özellikler
Açk sar yal sv. Hafifçe kremsi. Etanol, aseton, kloroform, karbon tetraklorür vb. Gibi organik çözücülerde çözünür ve suda az çözünür.
TCPP Uygulamas:
TCPP Esas olarak poliüretan köpüklü alev geciktirici ve PVC alev geciktirici plastikletirme vb. Genel dozaj 5-10 ksmdr. Selüloz asetat, nitroselüloz, etil selüloz, polivinil klorür, poliüretan, polivinil asetat ve fenolik reçinede yaygn olarak kullanlan alev geciktirici TCPP. Alev geciktirici plastikletirici olarak kullanlr. TCPP ayrca metal özütleyici, yalama ya ve benzin katks ve poliimid ileme deitiricisi olarak da kullanlabilir. Tcpp, oral toksisite sçanlarn LD50’si 1410 mg / kg idi. Lityum piller genellikle alev geciktirici olarak kullanlr. TCPP, yapsndaki fosfor ve klor nedeniyle yanclk maddesi olarak kullanlr. Ayn zamanda bir plastikletirici etkiye sahiptir. Düük scaklk direncine sahiptir. Neme kar dayankldr, çünkü hidroliz zordur. TCPP benzen ve alkolde çözünür, su, ya ve dier hidrokarbonlarda çözünürlüü düüktür. PVC, sert, esnek poliüretan köpük ve epoksi reçine, poliakrilik elyaf, etil selüloz reçine, fenol-formaldehit reçine.
TCPP’nin Faydalar ve Özellikleri:
Düük maliyetli bir klor ve fosfor bazl alev geciktirici. TCPP u anda mevcut halojenli organik fosfatlar arasnda en iyi hidroliz stabilitesine sahiptir. Suda çözünemez, çou organik çözücü içinde çözülemez ve reçinelerle iyi bir uyumlulua sahiptir.
Görünü Soluk sar effaf Sv.
Renk (APHA) 50 maks.
Asit Deeri (mg KOH / g) 0.1 max.
Su içerii%. 0,1 maks.
Viskozite (25 ° C, mPa s). 60-70
Özgül arlk (20 ° C) 1.285 – 1.295
P içerii% .9.0 – 9.8
Cl içerii% 32 – 32.8
% 1 kilo kayb 10 ° C
% 5 kilo kayb 172 ° C
% 10 kilo kayb 208 ° C
Krlma indisi (25 ℃) 1.460-1.466
Bu özellikler tipiktir ancak ksmen veya bir bütün olarak bir spesifikasyon oluturmaz. TCPP artname verileri, sat, müteri hizmetleri veya müteri teknik servislerinden talep üzerine temin edilebilir.
Tris (2-kloroizopropil) fosfat (TCPP) Ambalaj özellikleri 250 kg / varil, 1250k / IBC varil, ISO Tank, esnek kap vb. Alev geciktirici, alev geciktirici, plastikletirici ve d-Myo-inositol dahil çeitli polimer tiplerinin viskozite düzenleyicisi -1,4,5-rifosfat poliüretanlar, polyester reçineler ve poliakrilatlar. Bir TCEP analou olan Tris (2-kloroizopropil) fosfatn (TCPP) deitirildiine inanlmaktadr. Bununla birlikte, TCPP’nin TCEP’ye kyasla toksikolojik etkileri hakknda çok az ey bilinmektedir. nsan hepatoz karsinom hücre hattndaki TCEP ve TCPP üzerindeki etkilerini tanmlamak ve karlatrmak için objektif ve duyarl bir araç olarak RNA sralamasn kullandk.
TCPP’nin dier alev geciktiricilere kyasla çok az sitotoksisite olduunu bulduk. ki bileiin düük sitotoksik konsantrasyonlar ile muamele, her iki kimyasaln da benzer etkilere sahip olduunu ortaya koydu; Her iki bileiin de immün tepkilere ve steroid hormonu biyosentezine katlan genleri etkiledii ve benzer ekilde ksenobiyotik metabolizma yollarn etkiledii bulundu. Baklk tepkileri üzerindeki etkiler için spesifik olarak, her iki bileiin de güçlü ve pleiotropik tamamlayc bileen C5a’nn reseptörünün ekspresyonunu deitirdii gösterilmitir. Ek olarak, tamamlayc kaskad içerisindeki efektör proteinleri kodlayan genlerin, TCEP ve TCPP’ye ve ayrca dier güçlü enflamatuar düzenleyicilere cevap olarak, immün fonksiyon üzerindeki potansiyel etkilerini vurgulayarak deitii bulunmutur. Birlikte ele alndnda, TCPP, TCEP ile karlatrldnda benzer etkilere sahiptir ve düük konsantrasyonlarda, TCPP’nin potansiyel salk etkileri, bileiin tam bir risk deerlendirmesi için daha fazla çallmas gereken TCEP ile benzer etkilere sahiptir. Konsantrasyonlarda, TCPP’nin potansiyel salk etkilerinin, bileiin tam bir risk deerlendirmesi için daha fazla çalld düünülmektedir. TCPP kullanlan genel amaçl klorlu fosfat ester alev geciktiricidir. Üstünlük düük koku, yüksek s stabilitesi, mükemmel hidroliz stabilitesi, düük viskozite, sert ve esnek poliüretan köpükler gösteren reçine ile üstün uyumluluktur. TCPP, PU köpükler, PVC ve yaptrclar için alev geciktirici olarak önerilir.
TCPP, sert ve esnek poliüretan köpüklerde esas olarak alev geciktirici olarak kullanlr. TCPP, suda ve alifatik hidrokarbonlarda çözünmez, bal younluk 1.27 -1.31, krlma indisi Fosfor ve klor elementleri içeren her iki molekül nedeniyle, 1.4916 (21.5), viskozite 58mm2 / S,% 32.8 klor içerii,% 9.5 fosfor içerii, alev geciktirici özellikleri Polivinil plastik için, TCPP nemi (2-kloropropil) fosfat Klorür, polistiren, fenolik reçine ve kauçuk, boya alev geciktirici, genellikle antimon klorür ile birlikte kullanlr, Alev Geciktirici TCPP Antimon Klorürün Etkinliini arttrmak için kullanlr 3. TCPP Uygulamas (2- kloropropil) fosfat TCPP, çounlukla yumuak ve sert poliüretan köpük, klorlu reçine, polietilen, selüloz asetat, etil selüloz reçine ve fenolik plastik ve tabanca tipi köpük yaltm malzemesi için kullanlr.