ETHYL ACETATE (ETL ASETAT)
ETHYL ACETATE(ETL ASETAT)
CAS No.: 141-78-6
EC No.: 205-500-4
Synonyms:
ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; 141-78-6; Ethyl ethanoate; Acetic acid ethyl ester; Acetoxyethane; Acetic ether; Ethyl acetic ester; Vinegar naphtha; Acetic acid, ethyl ester; Acetidin; Ethylacetate; Essigester; Acetic ester; EtOAc; Aethylacetat; Ethylacetat; 1-acetoxyethane; Ethyl ester; RCRA waste number U112; AcOEt; Ethylacetaat; Octan etylu; Etile (acetato di); Essigester [German]; Ethylacetaat [Dutch]; Aethylacetat [German]; Caswell No. 429; Ethyle (acetate d’); Octan etylu [Polish]; Ethylazetat; ethyl-acetate; Ethyl acetate (natural); CHEBI:27750; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethylester kyseliny octove; acetic acid ethyl; Acetate d’ethyle [French]; Ethyl ester of acetic acid; Acetato de etilo [Spanish]; MFCD00009171; NSC 70930; Essigsaeureethylester; HSDB 83; UNII-76845O8NMZ; Etile (acetato di) [Italian]; FEMA No. 2414; CCRIS 6036; Ethyl acetate [NF]; Ethyle (acetate d’) [French]; acetic-acid-ethylester; ethyl acetate solution; Ethylester kyseliny octove [Czech]; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; EINECS 205-500-4; UN1173; CH3COOC2H5; RCRA waste no. U112; EPA Pesticide Chemical Code 044003; CH3-CO-O-CH3; ethyl acetat; AI3-00404; 76845O8NMZ; Ethyl acetate (NF); ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; NCGC00091766-01; E1504; DSSTox_CID_2001; Ethyl acetate, ACS reagent; DSSTox_RID_76453; DSSTox_GSID_22001; Ethyl acetate, 99+%, extra pure; Acetate d’ethyle; Acetato de etilo; Ethyl acetate, 99.5%, for analysis; Ethyl acetate, 99.5+%, for HPLC; Ethyl acetate, 99.6%, ACS reagent; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethyl acetate, ACS reagent, >=99.5%; CAS-141-78-6; Ethyl acetate, 99.5+%, for spectroscopy; Ethyl acetate, for pesticide residue analysis; Ethyl acetate, 99.5%, for spectroscopy ACS; Ethyl acetate, 99.9%, Extra Dry, AcroSeal(R); Ethyl acetate, 99.8%, for biochemistry, AcroSeal(R); ethylaceate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ethylactate; ethylacteate; Etylacetate; acet-ethylester; ehtyl acetate; ethanol acetate; ethly acetate; ethyl acteate; ethyl_acetate; ehyl acetate; ethl acetate; ethy acetate; ethyl aceate; ethyl actate; etyl acetate; Acetyl ester; acet-eth-ester; Ethyl acetate, 99.9%, Extra Dry over Molecular Sieve, AcroSeal(R); 1-ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 2~ethyl acetate; Ethyl Acetate.; acetic ethyl ester; Etile(acetato di); Nat.Ethyl Acetate; Et-OAc; Ethyle(acetate d’); acetic acid ethylester; Ethyl Acetate Natural; Ethyl Acetate, HPLC; CH3CO2Et; ACMC-1BTXP; Ethyl acetate HPLC grade; Ethyl acetate, for HPLC; Ethyl acetate, 99.9%; Ethyl acetate, ACS grade; CH3CO2CH2CH3; Epitope ID:116868; EC 205-500-4; CH3CO2C2H5; ETHYL ACETATE 100ML; Ethyl acetate, >=99.5%; ETHYL ACETATE; ETL ASETAT; 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ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; NCGC00260061-01; SC-22781; Ethyl acetate, biotech. grade, >=99.8%; Ethyl acetate, ReagentPlus(R), >=99.5%; Ethyl acetate, ReagentPlus(R), >=99.8%; Ethyl acetate, tested according to Ph.Eur.; 936-EP0930075A1; 936-EP1441224A2; 936-EP2269610A2; 936-EP2269651A2; 936-EP2269975A2; 936-EP2269977A2; 936-EP2269986A1; 936-EP2269987A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2269988A2; 936-EP2269989A1; 936-EP2269990A1; 936-EP2269992A1; 936-EP2269993A1; 936-EP2269994A1; 936-EP2269997A2; 936-EP2270000A1; 936-EP2270003A1; 936-EP2270004A1; 936-EP2270006A1; 936-EP2270008A1; 936-EP2270009A1; 936-EP2270011A1; 936-EP2270014A1; 936-EP2270015A1; 936-EP2270113A1; 936-EP2270114A1; 936-EP2272509A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272516A2; 936-EP2272517A1; 936-EP2272537A2; 936-EP2272813A2; 936-EP2272817A1; 936-EP2272822A1; 936-EP2272825A2; 936-EP2272827A1; 936-EP2272829A2; 936-EP2272830A1; 936-EP2272832A1; 936-EP2272834A1; 936-EP2272835A1; 936-EP2272839A1; 936-EP2272840A1; 936-EP2272841A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272842A1; 936-EP2272843A1; 936-EP2272844A1; 936-EP2272847A1; 936-EP2272848A1; 936-EP2272849A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272935A1; 936-EP2272972A1; 936-EP2272973A1; 936-EP2274983A1; 936-EP2275102A1; 936-EP2275105A1; 936-EP2275395A2; 936-EP2275398A1; 936-EP2275401A1; 936-EP2275403A1; 936-EP2275404A1; 936-EP2275407A1; 936-EP2275410A1; 936-EP2275411A2; 936-EP2275412A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2275413A1; 936-EP2275414A1; 936-EP2275415A2; 936-EP2275419A2; 936-EP2275420A1; A0030; Ethyl acetate [UN1173] [Flammable liquid]; Ethyl acetate, natural, >=99%, FCC, FG; Ethyl acetate, SAJ first grade, >=99.0%; FT-0621744; FT-0693343; NS00004207; Q0040; Ethyl acetate [UN1173] [Flammable liquid]; Ethyl acetate, for HPLC, >=99.8% (GC); Ethyl acetate, JIS special grade, >=99.5%; J3.639.860D; 6822-EP1441224A2; C00849; D02319; Ethyl acetate, capillary GC grade, >=99.5%; 37556-EP2305808A1; 37556-EP2311802A1; 37556-EP2311803A1; A807811; Q407153; Ethyl acetate, Laboratory Reagent, >=99.0% (GC); J-007556; J-521240; ethyl acetate;ETHYL ACETATE;Acetic acid ethyl ester; F0001-0489; UNII-LM8ZO3J16V component XEKOWRVHYACXOJ-UHFFFAOYSA-N; Ethyl acetate, 99.9%, for electronic use (MOS), residue free; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethyl acetate, puriss. p.a., ACS reagent, >=99.5% (GC); Ethyl acetate, for residue analysis, suitable for 5000 per JIS; Ethyl acetate, United States Pharmacopeia (USP) Reference Standard; Ethyl acetate, HPLC Plus, for HPLC, GC, and residue analysis, 99.9%; Ethyl acetate, suitable for 1000 per JIS, >=99.5%, for residue analysis; Ethyl acetate, suitable for 300 per JIS, >=99.5%, for residue analysis; Ethyl Acetate, Pharmaceutical Secondary Standard; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Certified Reference Material; Ethyl acetate, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., >=99.5% (GC); Ethyl acetate, puriss. p.a., free of higher boiling impurities, >=99.9% (GC); Ethyl acetate, puriss., meets analytical specification of Ph. Eur., BP, NF, >=99.5% (GC); ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; 141-78-6; Ethyl ethanoate; Acetic acid ethyl ester; Acetoxyethane; Acetic ether; Ethyl acetic ester; Vinegar naphtha; Acetic acid, ethyl ester; Acetidin; Ethylacetate; Essigester; Acetic ester; EtOAc; Aethylacetat; Ethylacetat; 1-acetoxyethane; Ethyl ester; RCRA waste number U112; AcOEt; Ethylacetaat; Octan etylu; Etile (acetato di); Essigester [German]; Ethylacetaat [Dutch]; Aethylacetat [German]; Caswell No. 429; Ethyle (acetate d’); Octan etylu [Polish]; Ethylazetat; ethyl-acetate; Ethyl acetate (natural); CHEBI:27750; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethylester kyseliny octove; acetic acid ethyl; Acetate d’ethyle [French]; Ethyl ester of acetic acid; Acetato de etilo [Spanish]; MFCD00009171; NSC 70930; Essigsaeureethylester; HSDB 83; UNII-76845O8NMZ; Etile (acetato di) [Italian]; FEMA No. 2414; CCRIS 6036; Ethyl acetate [NF]; Ethyle (acetate d’) [French]; acetic-acid-ethylester; ethyl acetate solution; Ethylester kyseliny octove [Czech]; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; EINECS 205-500-4; UN1173; CH3COOC2H5; RCRA waste no. U112; EPA Pesticide Chemical Code 044003; CH3-CO-O-CH3; ethyl acetat; AI3-00404; 76845O8NMZ; Ethyl acetate (NF); ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; NCGC00091766-01; E1504; DSSTox_CID_2001; Ethyl acetate, ACS reagent; DSSTox_RID_76453; DSSTox_GSID_22001; Ethyl acetate, 99+%, extra pure; Acetate d’ethyle; Acetato de etilo; Ethyl acetate, 99.5%, for analysis; Ethyl acetate, 99.5+%, for HPLC; Ethyl acetate, 99.6%, ACS reagent; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethyl acetate, ACS reagent, >=99.5%; CAS-141-78-6; Ethyl acetate, 99.5+%, for spectroscopy; Ethyl acetate, for pesticide residue analysis; Ethyl acetate, 99.5%, for spectroscopy ACS; Ethyl acetate, 99.9%, Extra Dry, AcroSeal(R); Ethyl acetate, 99.8%, for biochemistry, AcroSeal(R); ethylaceate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ethylactate; ethylacteate; Etylacetate; acet-ethylester; ehtyl acetate; ethanol acetate; ethly acetate; ethyl acteate; ethyl_acetate; ehyl acetate; ethl acetate; ethy acetate; ethyl aceate; ethyl actate; etyl acetate; Acetyl ester; acet-eth-ester; Ethyl acetate, 99.9%, Extra Dry over Molecular Sieve, AcroSeal(R); 1-ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 2~ethyl acetate; Ethyl Acetate.; acetic ethyl ester; Etile(acetato di); Nat.Ethyl Acetate; Et-OAc; Ethyle(acetate d’); acetic acid ethylester; Ethyl Acetate Natural; Ethyl Acetate, HPLC; CH3CO2Et; ACMC-1BTXP; Ethyl acetate HPLC grade; Ethyl acetate, for HPLC; Ethyl acetate, 99.9%; Ethyl acetate, ACS grade; CH3CO2CH2CH3; Epitope ID:116868; EC 205-500-4; CH3CO2C2H5; ETHYL ACETATE 100ML; Ethyl acetate, >=99.5%; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; KSC492C3D; WLN: 2OV1; [C]C(=O)OCC; CHEMBL14152; ACETIC ACID,ETHYL ESTER; Ethyl acetate, AR, >=99%; Ethyl acetate, LR, >=99%; DTXSID1022001; CTK3J2131; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethyl Acetate Reagent Grade ACS; KS-00000URG; 2-Oxo-2-ethoxyethylidyne radical; Ethyl acetate, analytical standard; ZINC895412; Ethyl acetate, anhydrous, 99.8%; NSC70930; Tox21_111166; Tox21_202512; ANW-42221; BDBM50128823; c0036; LS-831; NSC-70930; STL282717; Ethyl acetate, >=99%, FCC, FG; Ethyl acetate, HPLC grade, 99.8%; AKOS000121947; Ethyl Acetate Ethanol Solution (3:1); MCULE-6628539781; UN 1173; Ethyl acetate, for HPLC, >=99.5%; Ethyl acetate, for HPLC, >=99.7%; Ethyl acetate, for HPLC, >=99.8%; Ethyl acetate, PRA grade, >=99.5%; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; NCGC00260061-01; SC-22781; Ethyl acetate, biotech. grade, >=99.8%; Ethyl acetate, ReagentPlus(R), >=99.5%; Ethyl acetate, ReagentPlus(R), >=99.8%; Ethyl acetate, tested according to Ph.Eur.; 936-EP0930075A1; 936-EP1441224A2; 936-EP2269610A2; 936-EP2269651A2; 936-EP2269975A2; 936-EP2269977A2; 936-EP2269986A1; 936-EP2269987A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2269988A2; 936-EP2269989A1; 936-EP2269990A1; 936-EP2269992A1; 936-EP2269993A1; 936-EP2269994A1; 936-EP2269997A2; 936-EP2270000A1; 936-EP2270003A1; 936-EP2270004A1; 936-EP2270006A1; 936-EP2270008A1; 936-EP2270009A1; 936-EP2270011A1; 936-EP2270014A1; 936-EP2270015A1; 936-EP2270113A1; 936-EP2270114A1; 936-EP2272509A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272516A2; 936-EP2272517A1; 936-EP2272537A2; 936-EP2272813A2; 936-EP2272817A1; 936-EP2272822A1; 936-EP2272825A2; 936-EP2272827A1; 936-EP2272829A2; 936-EP2272830A1; 936-EP2272832A1; 936-EP2272834A1; 936-EP2272835A1; 936-EP2272839A1; 936-EP2272840A1; 936-EP2272841A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272842A1; 936-EP2272843A1; 936-EP2272844A1; 936-EP2272847A1; 936-EP2272848A1; 936-EP2272849A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2272935A1; 936-EP2272972A1; 936-EP2272973A1; 936-EP2274983A1; 936-EP2275102A1; 936-EP2275105A1; 936-EP2275395A2; 936-EP2275398A1; 936-EP2275401A1; 936-EP2275403A1; 936-EP2275404A1; 936-EP2275407A1; 936-EP2275410A1; 936-EP2275411A2; 936-EP2275412A1; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; 936-EP2275413A1; 936-EP2275414A1; 936-EP2275415A2; 936-EP2275419A2; 936-EP2275420A1; A0030; Ethyl acetate [UN1173] [Flammable liquid]; Ethyl acetate, natural, >=99%, FCC, FG; Ethyl acetate, SAJ first grade, >=99.0%; FT-0621744; FT-0693343; NS00004207; Q0040; Ethyl acetate [UN1173] [Flammable liquid]; Ethyl acetate, for HPLC, >=99.8% (GC); Ethyl acetate, JIS special grade, >=99.5%; J3.639.860D; 6822-EP1441224A2; C00849; D02319; Ethyl acetate, capillary GC grade, >=99.5%; 37556-EP2305808A1; 37556-EP2311802A1; 37556-EP2311803A1; A807811; Q407153; Ethyl acetate, Laboratory Reagent, >=99.0% (GC); J-007556; J-521240; ethyl acetate;ETHYL ACETATE;Acetic acid ethyl ester; F0001-0489; UNII-LM8ZO3J16V component XEKOWRVHYACXOJ-UHFFFAOYSA-N; Ethyl acetate, 99.9%, for electronic use (MOS), residue free; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Ethyl acetate, puriss. p.a., ACS reagent, >=99.5% (GC); Ethyl acetate, for residue analysis, suitable for 5000 per JIS; Ethyl acetate, United States Pharmacopeia (USP) Reference Standard; Ethyl acetate, HPLC Plus, for HPLC, GC, and residue analysis, 99.9%; Ethyl acetate, suitable for 1000 per JIS, >=99.5%, for residue analysis; Ethyl acetate, suitable for 300 per JIS, >=99.5%, for residue analysis; Ethyl Acetate, Pharmaceutical Secondary Standard; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate; Certified Reference Material; Ethyl acetate, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., >=99.5% (GC); Ethyl acetate, puriss. p.a., free of higher boiling impurities, >=99.9% (GC); Ethyl acetate, puriss., meets analytical specification of Ph. Eur., BP, NF, >=99.5% (GC); ETHYL ACETATE; ETL ASETAT; etil asetat; ethyl acetate
ETHYL ACETATE
Ethyl acetate
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Ethyl acetate
Skeletal formula
Ball-and-stick model
Names
Preferred IUPAC name
Ethyl acetate
Systematic IUPAC name
Methyl acetate,
Infobox references
Ethyl acetate (systematically ethyl ethanoate, commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula CH
2. This colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, and in the decaffeination process of tea and coffee. Ethyl acetate is the ester of ethanol and acetic acid; it is manufactured on a large scale for use as a solvent.[4]
Contents
1 Production and synthesis
2 Uses
2.1 Laboratory uses
2.2 Occurrence in wines
3 Reactions
4 Safety
5 References
6 External links
Production and synthesis
Ethyl acetate was first synthesised by Count de Lauraguais in 1759 by distilling a mixture of ethanol and acetic acid. [5]
In 2004, an estimated 1.3 million tonnes were produced worldwide.[4][6] The combined annual production in 1985 of Japan, North America, and Europe was about 400,000 tonnes. The global ethyl acetate market was valued at $3.3 billion in 2018.[7]
Ethyl acetate is synthesized in industry mainly via the classic Fischer esterification reaction of ethanol and acetic acid. This mixture converts to the ester in about 65% yield at room temperature:
Silicotungstic acid is used to manufacture ethyl acetate by the alkylation of acetic acid by ethylene:[8]
Uses
Ethyl acetate is used primarily as a solvent and diluent, being favored because of its low cost, low toxicity, and agreeable odor.[9] For example, it is commonly used to clean circuit boards and in some nail varnish removers (acetone is also used). Coffee beans and tea leaves are decaffeinated with this solvent.[10] It is also used in paints as an activator or hardener. Ethyl acetate is present in confectionery, perfumes, and fruits. In perfumes, it evaporates quickly, leaving only the scent of the perfume on the skin.
Laboratory uses
In the laboratory, mixtures containing ethyl acetate are commonly used in column chromatography and extractions.[11] Ethyl acetate is rarely selected as a reaction solvent because it is prone to hydrolysis, transesterification, and condensations.
Occurrence in wines
Ethyl acetate is the most common ester in wine, being the product of the most common volatile organic acid – acetic acid, and the ethyl alcohol generated during the fermentation. The aroma of ethyl acetate is most vivid in younger wines and contributes towards the general perception of “fruitiness” in the wine. Sensitivity varies, with most people having a perception threshold around 120 mg/L. Excessive amounts of ethyl acetate are considered a wine fault.
Reactions
Ethyl acetate is only weakly Lewis basic. It forms 1:1 adducts with I2, phenol, and bis(hexafloroacetylacetonato)copper(II).
Ethyl acetate hydrolyses to give acetic acid and ethanol. Bases accelerate the hydrolysis, which is subject to the Fischer equilibrium mentioned above. In the laboratory, and usually for illustrative purposes only, ethyl esters are typically hydrolyzed in a two-step process starting with a stoichiometric amount of a strong base, such as sodium hydroxide. This reaction gives ethanol and sodium acetate, which is unreactive toward ethanol:
Under anhydrous conditions, strong bases induce the Claisen condensation to give ethyl acetoacetate:[12]
Preparation of ethyl acetoacetate.
Safety
The LD50 for rats is 5620 mg/kg,[13] indicating low toxicity. Given that the chemical is naturally present in many organisms, there is little risk of toxicity.
In the field of entomology, ethyl acetate is an effective asphyxiant for use in insect collecting and study. In a killing jar charged with ethyl acetate, the vapors will kill the collected insect quickly without destroying it. Because it is not hygroscopic, ethyl acetate also keeps the insect soft enough to allow proper mounting suitable for a collection.
Overexposure to ethyl acetate may cause irritation of the eyes, nose, and throat. Severe overexposure may cause weakness, drowsiness, and unconsciousness.[14] Humans exposed to a concentration of 400 ppm in 1.4 mg/L ethyl acetate for a short time were affected by nose and throat irritation.[15] Ethyl acetate is an irritant of the conjunctiva and mucous membrane of the respiratory tract. Animal experiments have shown that, at very high concentrations, the ester has central nervous system depressant and lethal effects; at concentrations of 20,000 to 43,000 ppm (2.0–4.3%), there may be pulmonary edema with hemorrhages, symptoms of central nervous system depression, secondary anemia and liver damage. In humans, concentrations of 400 ppm cause irritation of the nose and pharynx; cases have also been known of irritation of the conjunctiva with temporary opacity of the cornea. In rare cases exposure may cause sensitization of the mucous membrane and eruptions of the skin. The irritant effect of ethyl acetate is weaker than that of propyl acetate or butyl acetate.[16]
Ethyl Acetate
What is Ethyl Acetate?
Ethyl acetate is a carboxylate ester with the chemical formula CH3COOC2H5. It is a colorless liquid that has a sweet, fruity odor that most people find pleasant.
Ethyl acetate is a polar aprotic solvent. It has two dipole moments, generated by its two high electronegative oxygen atoms, which are on the carbonyl and ethyl groups.
Sigma Aldrich Ethyl Acetate Lewis Structure
Ethyl acetate results from the reaction between ethanol and acetic acid. It is most widely commercially synthesized via the Fischer esterification reaction. An alternative method is via the Tishchenko reaction.
Ethyl acetate is a standard solvent. Used especially for paints, varnishes, lacquers, cleaning, and perfumes. In the lab, ethyl acetate is a universal solvent for column and thin-layer chromatography.
Ethyl acetate is present in alcoholic drinks, cereal crops, radishes, fruit juices, beer, wine, and spirits.
Whether you need HPLC ethyl acetate, ACS ethyl acetate, anhydrous ethyl acetate or one of the other grades available, we offer the right product for your application.
Ethyl Acetate Formulas and Structures
Ethyl acetate, also know as ethyl ethanoate, or acetic acid ethyl ester, consists of four carbon atoms, eight hydrogen atoms, and two oxygen atom.
Type Formula or Structure
Ethyl Acetate Molecular Formulas C4H8O2 or CH3COOC2H5
Ethyl Acetate Ball and Sticks Structural Model Sigma Aldrich Ethyl Acetate Ball-Stick Structure
Ethyl Acetate Sticks Structural Model Sigma Aldrich Ethyl Acetate Stick Structure
Ethyl Acetate Skeletal Structural Model Sigma Aldrich Ethyl Acetate Wire-Frame Structure
Ethyl Acetate Space-Filling Structural Model Sigma Aldrich Ethyl Acetate Space-Filling Structure
Ethyl Acetate Identification
Chart listing the various names, identifiers and synonyms of ethyl acetate.
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All Ethyl Acetate Ethyl Acetate by Grade
HPLC Ethyl Acetate ACS Ethyl Acetate Anhydrous Products
Ethyl Acetate Physical and Chemical Properties
Chart including the physical and chemical properties of ethyl acetate.
Ethyl Acetate Miscibility and Immiscibility
Property Chemical
Miscible Acetic Acid, Acetone, Acetonitrile, Benzene, Butanol, Methyl ethyl ketone (MEK), Butyl Acetate (n-), Methyl tert-butyl ether (MTBE), Carbon Tetrachloride, Chloroform, Cyclohexane, Dichloroethane (1,2-), Dichloromethane, Diethyl ether, Diisopropyl ether, Dimethylformamide, Dimethyl Sulfoxide (DMSO), Dioxane, Ethanol, Ethyl Acetate, Heptane, Hexane, Methanol, Pentane, 1-Propanol, Isopropanol, Tetrahydrofuran (THF), Toluene, Trichloroethylene, Isooctane, Xylene
Immiscible Water
Miscibility Information and Solvent Miscibility Table
ethyl acetate miscibility and immiscibility chart
Ethyl Acetate Hazard Statements
Ethyl Acetate SDS Information
An SDS (Safety Data Sheet) is available for each ethyl acetate product. Start your search for an SDS.
What is Ethyl Acetate Used For?
Some of the common uses of ethyl acetate are:
Why is Ethyl Acetate Used in Entomology?
Entomology is the study of insects and their relationship to organisms, and
Ethyl acetate is an effective asphyxiant for use in insect collection and study.
Usually, etymologists charge a jar with this substance. Its vapors will kill the collected (usually adult) insect suddenly without destroying it. Because ethyl acetate is not hygroscopic the insect remains soft enough to allow mounting suitable for a collection.
What Foods Contain Ethyl Acetate?
Ethyl acetate is present in some fruits, particularly apples and pears, and some wines.
Ethyl acetate is also used to decaffeinate cigarettes, coffee, and tea leaves.
ETL ASETAT
Etil asetat
Vikipedi, özgür ansiklopedi
Gezintiye atlaArama yapmak için atla
Etil asetat
skelet formülü
Top ve sopa modeli
simler
Tercih edilen IUPAC ad
Etil asetat
Sistematik IUPAC ad
Metil asetat,
Bilgi kutusu referanslar
Etil asetat (sistematik olarak etil etanoat, genellikle ksaltlm EtOAc, ETAC veya EA), CH formülüne sahip organik bileiktir.
2. Bu renksiz svnn karakteristik bir tatl kokusu vardr (armut damlalarna benzer) ve yaptrclarda, oje çkarclarda ve çay ve kahvenin kafeinsizletirme ileminde kullanlr. Etil asetat, etanol ve asetik asidin esteridir; çözücü olarak kullanlmak üzere büyük ölçekte üretilmitir. [4]
çindekiler
1 Üretim ve sentez
2 Kullanmlar
2.1 Laboratuvar kullanmlar
2.2 araplarda görülmesi
3 Reaksiyonlar
4 Güvenlik
5 Kaynaklar
6 D balantlar
Üretim ve sentez
Etil asetat ilk olarak 1759’da Count de Lauraguais tarafndan bir etanol ve asetik asit karm damtlarak sentezlendi. [5]
2004 ylnda, dünya çapnda tahmini 1,3 milyon ton üretildi. [4] [6] 1985’te Japonya, Kuzey Amerika ve Avrupa’nn toplam yllk üretimi yaklak 400.000 tondu. Küresel etil asetat pazar 2018’de 3,3 milyar dolar deerinde idi. [7]
Etil asetat, endüstride esas olarak etanol ve asetik asidin klasik Fischer esterifikasyon reaksiyonu yoluyla sentezlenir. Bu karm, oda scaklnda yaklak% 65 verimle estere dönüür:
Silikotungstik asit, asetik asidin etilen ile alkilasyonu yoluyla etil asetat üretmek için kullanlr: [8]
Kullanmlar
Etil asetat, düük maliyeti, düük toksisitesi ve ho kokusu nedeniyle tercih edilen bir çözücü ve seyreltici olarak öncelikle kullanlr. [9] Örnein, devre kartlarn temizlemek için ve baz trnak cilas sökücülerinde (aseton da kullanlr) yaygn olarak kullanlr. Kahve çekirdekleri ve çay yapraklar bu çözücü ile kafeinsizletirilir. [10] Boyalarda aktivatör veya sertletirici olarak da kullanlr. Etil asetat ekerlemelerde, parfümlerde ve meyvelerde bulunur. Parfümlerde ise ciltte sadece parfümün kokusunu brakarak hzla buharlar.
Laboratuvar kullanmlar
Laboratuvarda etil asetat içeren karmlar kolon kromatografisi ve ekstraksiyonlarnda yaygn olarak kullanlmaktadr. [11] Etil asetat, hidroliz, transesterifikasyon ve younlamaya eilimli olduu için reaksiyon çözücüsü olarak nadiren seçilir.
araplarda oluum
Etil asetat, arapta en yaygn esterdir, en yaygn uçucu organik asit olan asetik asit ve fermantasyon srasnda oluan etil alkolün ürünüdür. Etil asetatn aromas en çok genç araplarda canldr ve arabn genel “meyvemsi” algsna katkda bulunur. Duyarllk deiir, çou insan 120 mg / L civarnda bir alglama eiine sahiptir. Ar miktarda etil asetat bir arap hatas olarak kabul edilir.
Tepkiler
Etil asetat sadece zayf bir ekilde Lewis baziktir. I2, fenol ve bis (heksafloroasetilasetonato) bakr (II) ile 1: 1 eklenti oluturur.
Etil asetat, asetik asit ve etanol vermek üzere hidrolize olur. Bazlar, yukarda bahsedilen Fischer dengesine tabi olan hidrolizi hzlandrr. Laboratuvarda ve genellikle sadece açklama amacyla, etil esterler tipik olarak, sodyum hidroksit gibi güçlü bir bazn stoikiometrik bir miktar ile balayan iki aamal bir ilemde hidrolize edilir. Bu reaksiyon, etanole kar reaktif olmayan etanol ve sodyum asetat verir:
Susuz koullar altnda, güçlü bazlar Claisen younlamasna neden olarak etil asetoasetat verir: [12]
Etil asetoasetatn hazrlanmas.
Emniyet
Sçanlar için LD50, 5620 mg / kg’dr [13], bu düük toksisiteyi gösterir. Kimyasaln birçok organizmada doal olarak bulunduu göz önüne alndnda, çok az toksisite riski vardr.
Entomoloji alannda, etil asetat, böcek toplama ve incelemede kullanm için etkili bir boucudur. Etil asetatla doldurulmu bir öldürme kavanozunda, buharlar toplanan böcei yok etmeden hzla öldürecektir. Higroskopik olmadndan, etil asetat ayn zamanda böcei, bir koleksiyon için uygun bir ekilde yerletirmeye izin verecek kadar yumuak tutar.
Etil asetata ar maruz kalma gözler, burun ve boazda tahrie neden olabilir. iddetli ar maruz kalma halsizlik, uyuukluk ve bilinç kaybna neden olabilir. [14] Ksa bir süre 1.4 mg / L etil asetatta 400 ppm konsantrasyonuna maruz kalan insanlar burun ve boaz tahriinden etkilenmitir. [15] Etil asetat, solunum yolunun konjunktiva ve mukoza zarn tahri edicidir. Hayvan deneyleri, çok yüksek konsantrasyonlarda esterin, merkezi sinir sistemini basklayc ve öldürücü etkilere sahip olduunu göstermitir; 20.000 ila 43.000 ppm (% 2.0-4.3) konsantrasyonlarda, kanamal pulmoner ödem, merkezi sinir sistemi depresyonu semptomlar, ikincil anemi ve karacier hasar olabilir. nsanlarda 400 ppm’lik konsantrasyonlar burun ve yutakta tahrie neden olur; korneann geçici opasitesi ile birlikte konjunktivann tahri olduu da bilinmektedir. Nadir durumlarda maruziyet, mukoza zarnda hassasiyete ve ciltte döküntülere neden olabilir. Etil asetatn tahri edici etkisi propil asetat veya bütil asetata göre daha zayftr. [16]
Etil asetat
Etil Asetat nedir?
Etil asetat, CH3COOC2H5 kimyasal formülüne sahip bir karboksilat esterdir. Çou insann ho bulduu tatl, meyvemsi bir kokuya sahip renksiz bir svdr.
Etil asetat, polar aprotik bir çözücüdür. Karbonil ve etil gruplar üzerinde bulunan iki yüksek elektronegatif oksijen atomu tarafndan üretilen iki dipol momentine sahiptir.
Sigma Aldrich Etil Asetat Lewis Yaps
Etil asetat, etanol ve asetik asit arasndaki reaksiyondan kaynaklanr. En yaygn olarak ticari olarak Fischer esterleme reaksiyonu yoluyla sentezlenir. Alternatif bir yöntem Tishchenko reaksiyonudur.
Etil asetat standart bir çözücüdür. Özellikle boyalar, vernikler, cilalar, temizlik ve parfümlerde kullanlr. Laboratuarda etil asetat, kolon ve ince tabaka kromatografisi için evrensel bir çözücüdür.
Etil asetat alkollü içeceklerde, tahl mahsullerinde, turplarda, meyve sularnda, bira, arap ve alkollü içeceklerde bulunur.
HPLC etil asetat, ACS etil asetat, susuz etil asetat veya mevcut dier snflardan birine ihtiyacnz olsun, uygulamanz için doru ürünü sunuyoruz.
Etil Asetat Formülleri ve Yaplar
Etil asetat veya asetik asit etil ester olarak da bilinen etil asetat, dört karbon atomu, sekiz hidrojen atomu ve iki oksijen atomundan oluur.
Formül veya Yapy Yazn
Etil Asetat Moleküler Formüller C4H8O2 veya CH3COOC2H5
Etil Asetat Topu ve Çubuklar Yapsal Model Sigma Aldrich Etil Asetat Top Çubuk Yaps
Etil Asetat Çubuklar Yapsal Model Sigma Aldrich Etil Asetat Çubuk Yaps
Etil Asetat skelet Yapsal Modeli Sigma Aldrich Etil Asetat Tel Çerçeve Yaps
Etil Asetat Boluk Dolduran Yapsal Model Sigma Aldrich Etil Asetat Boluk Doldurma Yaps
Etil Asetat Tanmlamas
Etil asetatn çeitli isimlerini, tanmlayclarn ve eanlamllarn listeleyen tablo.
Etil Asetat Ürünlerini Karlatrn ve Satn Aln
Dereceye Göre Tüm Etil Asetat Etil Asetat
HPLC Etil Asetat ACS Etil Asetat Susuz Ürünler
Etil Asetat Fiziksel ve Kimyasal Özellikler
Etil asetatn fiziksel ve kimyasal özelliklerini içeren çizelge.
Etil Asetat Karabilirlii ve Karmazl
Emlak Kimyasal
Karabilir Asetik Asit, Aseton, Asetonitril, Benzen, Butanol, Metil etil keton (MEK), Butil Asetat (n-), Metil tert-butil eter (MTBE), Karbon Tetraklorür, Kloroform, Sikloheksan, Dikloroetan (1,2-), Diklorometan, Dietil eter, Diizopropil eter, Dimetilformamid, Dimetil Sülfoksit (DMSO), Dioksan, Etanol, Etil Asetat, Heptan, Heksan, Metanol, Pentan, 1-Propanol, zopropanol, Tetrahidrofuran (THF), Toluen, Trikloretilen
Karmayan Su
Karabilirlik Bilgileri ve Çözücü Karabilirlik Tablosu
etil asetat karabilirlik ve karmazlk tablosu
Etil Asetat Tehlike Açklamalar
Etil Asetat SDS Bilgisi
Her etil asetat ürünü için bir SDS (Güvenlik Veri Sayfas) mevcuttur. Bir SDS aramanz balatn.
Etil Asetat Ne çin Kullanlr?
Etil asetatn yaygn kullanmlarndan bazlar unlardr:
Etil Asetat Neden Entomolojide Kullanlr?
Entomoloji, böceklerin ve organizmalarla ilikilerinin incelenmesidir ve
Etil asetat, böcek toplama ve incelemede kullanm için etkili bir boucudur.
Genellikle etimologlar bu maddeyle bir kavanoz yüklerler. Buharlar, toplanan (genellikle yetikin) böcei, onu yok etmeden aniden öldürecektir. Etil asetat higroskopik olmadndan, böcek toplama için uygun yerletirmeye izin verecek kadar yumuak kalr.
Hangi Gdalar Etil Asetat çerir?
Etil asetat baz meyvelerde, özellikle elma ve armutta ve baz araplarda bulunur.
Etil asetat ayrca sigara, kahve ve çay yapraklarn kafeinsizletirmek için kullanlr.