LITHIUM CHLORIDE ( Lityum Klorr)
Lithium chloride is a chemical compound with the formula LiCl.
Preferred IUPAC name: Lithium chloride
Synonym(s): Hydrochloric acid lithium salt
Linear Formula: LiCl
Systematic IUPAC name: Lithium(1+) chloride
CAS Number: 7447-41-8
EC Number:231-212-3
Chemical formula: LiCl
Molar mass: 42.39 g·mol−1
Appearance: white solid hygroscopic, sharp
Density: 2.068 g/cm3
Melting point: 605–614 °C (1,121–1,137 °F; 878–887 K)
Boiling point: 1,382 °C (2,520 °F; 1,655 K)
Lithium Chloride (LiCl) is an ionic compound or salt highly polar and soluble in water.
Lithium Chloride is more soluble in organic solvents such as acetone and methanol than potassium chloride or sodium chloride.
Lithium chloride is widely used in several industrial applications.
Lithium chloride is a chemical compound with the formula LiCl.
Lithium chloride is a relatively typical ionic compound, although the Li+ ion is very small.
The salt is hygroscopic, highly soluble in water, and highly polar.
Lithium chloride is more soluble in polar organic solvents such as methanol and acetone than sodium chloride or potassium chloride.
Lithium Chloride is used in the following products: coating products, metal surface treatment products, non-metal-surface treatment products, adhesives and sealants, inks and toners, pH regulators and water treatment products, photo-chemicals, polishes and waxes, and welding & soldering products.
Molten salt chemistry and metallurgy, brazing fluxes, the catalyst for organic oxidation reactions, the electrolyte in dry cells used in low temperatures, and stabilizer in textile fiber spinning solutions.
Solubilizer for polyamides and cellulose when used with amide solvents, chlorinating agent for steroid agents.
Desiccant for drying applications, tracer in wastewater.
The rise in demand for this chemical in the automotive sector is a significant driver of the global lithium chloride market.
Lithium Chloride is utilized in vehicle battery applications.
The lithium Chloride industry is expected to benefit from increased consumption of LiCl in the field of biomedicine.
The recent worldwide trend of electrification of cars is expected to drive revenue growth in the market.
Rising demand for lithium metal manufacturing paired with its increasing applicability in electricity and transportation advancements are expected to drive market revenue growth since it is utilized as feed material.
LiCl is used as an electrolyte in nuclear fuel reprocessing.
Solubility in water:
68.29 g/100 mL (0 °C)
74.48 g/100 mL (10 °C)
84.25 g/100 mL (25 °C)
88.7 g/100 mL (40 °C)
123.44 g/100 mL (100 °C)
Solubility: soluble in hydrazine, methyl formamide, butanol, selenium(IV) oxychloride, 1-propanol
Solubility in methanol
45.2 g/100 g (0 °C)
43.8 g/100 g (20 °C)
42.36 g/100 g (25 °C)
44.6 g/100 g (60 °C)
Solubility in ethanol
14.42 g/100 g (0 °C)
24.28 g/100 g (20 °C)
25.1 g/100 g (30 °C)
23.46 g/100 g (60 °C)
Solubility in formic acid
26.6 g/100 g (18 °C)
27.5 g/100 g (25 °C)
Solubility in acetone
1.2 g/100 g (20 °C)
0.83 g/100 g (25 °C)
0.61 g/100 g (50 °C)
Solubility in liquid ammonia
0.54 g/100 g (-34 °C)
3.02 g/100 g (25 °C)
Vapor pressure
1 torr (785 °C)
10 torr (934 °C)
100 torr (1130 °C)
Magnetic susceptibility (χ): −24.3·10−6 cm3/mol
Refractive index (nD): 1.662 (24 °C)
Viscosity: 0.87 cP (807 °C)[1]
Heat capacity (C): 48.03 J/mol·K[1]
Std molar entropy (S⦵298): 59.31 J/mol·K[1]
Std enthalpy of formation (ΔfH⦵298): -408.27 kJ/mol
Gibbs free energy (ΔfG⦵): -384 kJ/mol[1]
The salt is a typical ionic compound (with specific covalent characteristics).
However, the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Lithium Chloride has a sharp, saline taste and cubic crystals, crystalline powder, or granule appearance.
It has a melting point of 121°F and 2.068 density at 77°F
Its aqueous solution is neutral and a bit alkaline
Lithium Chloride is soluble in ether, nitrobenzene, and water alcohols
Chemical Properties of Lithium Chloride:
The salt forms crystalline hydrates, unlike the other alkali metal chlorides.
Mono-, tri-, and pentahydrates are known.
The anhydrous salt can be regenerated by heating the hydrates.
LiCl also absorbs up to four equivalents of ammonia/mol.
As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate:
LiCl + AgNO3 → AgCl + LiNO3
Preparation of Lithium chloride
Lithium chloride may be prepared most simply by reaction of lithium hydroxide or lithium carbonate with hydrochloric acid.
Anhydrous LiCl is prepared from the hydrate by heating in a stream of hydrogen chloride.
Lithium chloride may also be prepared by the highly exothermic reaction of lithium metal with either chlorine or anhydrous hydrogen chloride gas.
Anhydrous LiCl is prepared from the hydrate by gently heating under an atmosphere of hydrogen chloride, used to prevent hydrolysis.
Reaction with Sulfuric Acid
The lithium chloride and sulfuric acid reaction form hydrogen chloride and lithium sulfate.
Here is the reaction’s chemical equation:
2LiCl+H2SO4→2HCl+Li2SO4
Reaction with Base
Lithium chloride reacts with an alkali (such as Sodium Hydroxide) to form Sodium Chloride and Lithium Hydroxide.
LiCl+NaOH→LiOH+NaCl
Like other metal chlorides, lithium chloride salt produces crystalline hydrates.
You can regenerate its anhydrous salts after heating the hydrates.
Besides, it can easily absorb four equivalents of ammonia per mol.
However, lithium chloride can mainly serve as a chloride ion source when combined with an ionic chloride.
Lithium chloride can react as a source of chloride ions.
As with any other soluble ionic chloride, it will precipitate insoluble chlorides when added to a solution of an appropriate metal salt such as lead(II) nitrate:
2 LiCl(aq) + Pb(NO3)2(aq) → PbCl2(s) + 2 LiNO3(aq)
The Li+ ion acts as a weak Lewis acid under certain circumstances; for example, one mole of lithium chloride can absorb up to four moles of ammonia.
Uses of Lithium chloride
Lithium chloride, one of the most well-known mood stabilizers with antisuicidal effects, is currently being utilized as an agent for acute mania and as a maintenance treatment for bipolar disorder.
Commercial applications of Lithium Chloride
Lithium chloride is mainly used to produce lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F).
Lithium chloride is also used as a brazing flux for aluminum in automobile parts.
Lithium chloride is used in several salt mixtures with low melting points, allowing the material to be used in brazing fluxes and baths.
LiCl is used as a desiccant for drying air streams.
Lithium chloride is used in organic synthesis in more specialized applications, e.g., as an additive in the Stille reaction.
Also, Lithium chloride can be used in biochemical applications to precipitate RNA from cellular extracts.
Lithium chloride is also a flame colorant to produce dark red flames.
Niche uses of Lithium Chloride:
Lithium chloride is used as a relative humidity standard in calibrating hygrometers.
At 25 °C (77 °F), a saturated solution (45.8%) of the salt will yield an equilibrium relative humidity of 11.30%.
Additionally, lithium chloride can be used as a hygrometer.
This deliquescent salt forms a self-solution when exposed to air.
The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air.
The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first-order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass.
Molten LiCl is used to prepare carbon nanotubes, graphene, and lithium niobate.
Lithium chloride has been shown to have acaricidal solid properties, being effective against Varroa destructor in populations of honey bees.
Lithium chloride is used as an aversive agent in lab animals to study conditioned place preference and aversion.
Lithium chloride can be used to prepare LiCl-PAM (polyacrylamide), an ion-conducting neutral polymer electrolyte with an ionic conductivity >10 mS cm-1.
Lithium chloride is an efficient catalyst in the cyanosilylation of aldehydes and ketones to the corresponding silylated cyanohydrins.
As a reaction medium in combination with N, N-dimethylacetamide for the esterification of cellulose.
Electrochemistry
Lithium metal is produced by electrolysis of lithium chloride and potassium chloride, which melts at 450°C.
High-purity lithium chloride is used as the feedstock in the process and makes about 99.5% pure lithium metal.
Molten lithium is contained in a carbon steel pot, while the chlorine gas is collected in a stainless steel or glass pipe for applications in other processes.
The molten lithium flows into a collecting tank and is later cast into ingots.
A mesh or stainless-steel screen separates the two compartments to prevent the products from mixing.
Other Applications of Lithium Chloride
Lithium Chloride is used as a flame colorant to form dark crimson flames.
It is used in the precipitation of RNA in biological applications.
Lithium Chloride is an aluminum blazing flux in automobile parts.
It is used for soldering, welding techniques, and salt bath heat treatment at low temperatures.
Lithium chloride is used in massive dehumidification systems in the Air Conditioning industry.
This depends on the low equilibrium pressure of vapor above lithium chloride solutions.
Lithium chloride produces lithium metal by electrolysis of a LiCl/KCl melt at 450 °C.
LiCl is also used as a brazing flux for aluminum in automobile parts.
LiCl can be used to improve the efficiency of the Stille reaction.
Its desiccant properties can generate potable water by absorbing moisture from the air, which is then released by heating the salt.
For a short time in the 1940s, lithium chloride was manufactured as a substitute for salt, but this was prohibited after the toxic effects of the compound were recognised.
Precautions
Lithium salts affect the central nervous system in a variety of ways.
While citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts, including chloride, were used in the past.
For a short time in the 1940s, lithium chloride was manufactured as a salt substitute for people with hypertension, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea) were recognized.
It was, however, noted by J. H. Talbott that many symptoms attributed to lithium chloride toxicity may have also been attributable to sodium chloride deficiency, to the diuretics often administered to patients who were given lithium chloride, or to the patients’ underlying conditions.
Chloride, Lithium
Lithium Chloride
LITHIUM CHLORIDE
7447-41-8
LiCl
Lithiumchloride
chlorure de lithium
Chlorku litu
chlorolithium
Lithiumchlorid
Lithium chloride (LiCl)
lithium;chloride
CCRIS 5924
CHEBI:48607
lithii chloridum
HSDB 4281
Lithium Cholride
cloruro de litio
Lithium chloride (powder)
EINECS 231-212-3
MFCD00011078
NSC 327172
UNII-G4962QA067
LITHIUM MURIATICUM
G4962QA067
NSC-327172
Lithium Chloride, Anhydrous
LithiumChlorideGr(Anhydrous)
CHEMBL69710
DTXSID2025509
EC 231-212-3
NSC327172
ClLi
Lithium chloride, ultra dry
Chlorku litu [Polish]
Luthium chloride
Chloride, Lithium
Chlorure de lithium [French]
2M Lithium Chloride Electrolyte, Electrode Filling Solution
Lithium Chloride (2.3% in Tetrahydrofuran, ca. 0.5mol/L)
lithim chloride
Lithium chloride, anhydrous, chunks, 99.99% trace metals basis
Lithium chloride anhydrous
Lopac-L-4408
LITHIUM MONOCHLORIDE
MolMap_000071
WLN: LI G
Lithium chloride, ACS grade
Lopac0_000604
LITHIUM CHLORIDE [MI]
Lithium chloride battery grade
Lithium chloride, ACS reagent
DTXCID105509
LITHIUM CHLORIDE [HSDB]
LITHIUM CHLORIDE [INCI]
LITHIUM MURIATICUM [HPUS]
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
LITHIUM CHLORIDE [WHO-DD]
Lithium chloride, 3-5% in THF
HMS3261J10
Tox21_500604
BDBM50494542
AKOS015902822
AKOS015950647
AKOS024438070
CCG-204693
lithium chloride, gamma irradiated, 8m
LP00604
SDCCGSBI-0050586.P002
Lithium chloride, ACS reagent, >=99%
Lithium chloride, ReagentPlus(R), 99%
NCGC00015607-01
NCGC00015607-02
NCGC00015607-03
NCGC00015607-04
NCGC00015607-07
NCGC00093980-01
NCGC00093980-02
NCGC00261289-01
BP-13612
SY002997
Lithium chloride, Vetec(TM) reagent grade
EU-0100604
FT-0627896
L0204
L0222
Lithium chloride, Trace metals grade 99.9%
L 4408
Lithium chloride, SAJ first grade, >=98.0%
Lithium chloride, for molecular biology, >=99%
Lithium chloride, SAJ special grade, >=99.0%
A838146
Lithium chloride, BioXtra, >=99.0% (titration)
Q422930
SR-01000076252
SR-01000076252-1
Lithium chloride, powder, >=99.99% trace metals basis
Lithium chloride, puriss. p.a., anhydrous, >=99.0% (AT)
Lithium chloride, anhydrous, beads, -10 mesh, >=99.9% trace metals basis
Lithium chloride, anhydrous, beads, -10 mesh, 99.998% trace metals basis
Lithium chloride, puriss. p.a., ACS reagent, anhydrous, >=99.0% (AT)
Lithium chloride, anhydrous, free-flowing, Redi-Dri(TM), ACS reagent, >=99%
Lithium chloride, anhydrous, free-flowing, Redi-Dri(TM), ReagentPlus(R), 99%
Lithium chloride, BioUltra, for molecular biology, anhydrous, >=99.0% (AT)
59217-69-5
Substance names and other identifiers
Regulatory process names
Lithium chloride
EC Inventory
lithium chloride
Pre-Registration process
Lithium chloride (LiCl)
IUPAC names
LITHIUM CHLORIDE
Lithium Chloride
Lithium chloride
lithium chloride
Lithium Chloride
Lithium Chloride Anhydrous
Lithium chloride anhydrous
Lithium chloride, anhydrous
Lithium monochloride
lithium(1+) chloride
lithium(1+) ion chloride
LITHIUM-CHLORIDE-
lithium;chloride
Lithiumchlorid
lithiumchloride
lithuim chloride
Trade names
Chloride Lithium Anhydrous
Lithium chloride
Lithium chloride [ACD/IUPAC Name] [Wiki]
231-212-3 [EINECS]
7447-41-8 [RN]
Chloride, Lithium
Chlorku litu [Polish]
Chlorure de lithium [French] [ACD/IUPAC Name]
cloruro de litio [Italian]
G4962QA067
hydrochloric acid lithium salt
LiCl [Formula]
Lithiumchlorid [German] [ACD/IUPAC Name]
[7447-41-8] [RN]
16712-20-2 [RN]
20233-17-4 [RN]
404596-80-1 [RN]
7789-01-7 [RN]
85144-11-2 [RN]
CHEMBL69710
Chlorku Litu
Chlorku litu [Polish]
chlorolithium
Chlorure de lithium [French]
cloruro de litio
D018021
EINECS 231-212-3
Electrolytemissing
LiCl231-212-3MFCD00011078
lithii chloridum [Latin]
lithii chloridum
Lithium chloride (powder)
Lithium chloride, anhydrous
Lithium chloridemissing
LITHIUM MONOCHLORIDE
lithium;chloride
LITHIUM-7LI CHLORIDE
lithiumchloride
Lithiummissing
Lopac0_000604
MFCD00011078 [MDL number]
MFCD00149764
MFCD00190539
MolMap_000071
OmniPur(R) Lithium Chloride
UNII:G4962QA067
UNII-G4962QA067
WLN: LI G
氯化锂 [Chinese]
OTHER PRODUCTS OF ATAMAN CHEMICALS THAT MIGHT BE OF INTEREST:
Lithium astatide
Lithium bromide
Lithium carbonate
Lithium fluoride
Lithium Hydroxide
Lithium iodide
Lithium Nitrate
Lityum klorür, LiCl formülüne sahip kimyasal bir bileiktir.
Tercih edilen IUPAC ad: Lityum klorür
E anlaml(lar): Hidroklorik asit lityum tuzu
Dorusal Formül: LiCl
Sistematik IUPAC ad: Lityum(1+) klorür
CAS Numaras: 7447-41-8
EC Numaras:231-212-3
Kimyasal formül: LiCl
Molar kütle: 42,39 g·mol−1
Görünüm: beyaz kat higroskopik, keskin
Younluk: 2,068 g/cm3
Erime noktas: 605–614 °C (1,121–1,137 °F; 878–887 K)
Kaynama noktas: 1.382 °C (2.520 °F; 1.655 K)
Lityum Klorür (LiCl), oldukça polar ve suda çözünebilen iyonik bir bileik veya tuzdur.
Lityum Klorür, aseton ve metanol gibi organik çözücülerde potasyum klorür veya sodyum klorürden daha fazla çözünür.
Lityum klorür birçok endüstriyel uygulamada yaygn olarak kullanlmaktadr.
Lityum klorür, LiCl formülüne sahip kimyasal bir bileiktir.
Lityum klorür nispeten tipik bir iyonik bileiktir, ancak Li+ iyonu çok küçüktür.
Tuz higroskopiktir, suda oldukça çözünür ve oldukça polardr.
Lityum klorür, metanol ve aseton gibi polar organik çözücülerde, sodyum klorür veya potasyum klorürden daha fazla çözünür.
Lityum Klorür aadaki ürünlerde kullanlr: kaplama ürünleri, metal yüzey ileme ürünleri, metal olmayan yüzey ileme ürünleri, yaptrclar ve szdrmazlk malzemeleri, mürekkepler ve tonerler, pH düzenleyiciler ve su artma ürünleri, fotokimyasallar, cilalar ve mumlar ve kaynak & lehimleme ürünleri.
Erimi tuz kimyas ve metalurjisi, lehim tozlar, organik oksidasyon reaksiyonlar için katalizör, düük scaklklarda kullanlan kuru hücrelerdeki elektrolit ve tekstil elyaf eirme çözümlerinde stabilizatör.
Amit çözücülerle birlikte kullanldnda poliamidler ve selüloz için çözündürücü, steroid maddeler için klorlama maddesi.
Kurutma uygulamalar için kurutucu, atk sularda izleyici.
Otomotiv sektöründe bu kimyasala olan talebin artmas, küresel lityum klorür pazarnn önemli bir itici gücüdür.
Lityum Klorür araç aküsü uygulamalarnda kullanlmaktadr.
Lityum Klorür endüstrisinin biyotp alannda artan LiCl tüketiminden faydalanmas bekleniyor.
Son dönemde dünya çapnda otomobillerin elektrifikasyonu eiliminin pazardaki gelir artn artrmas bekleniyor.
Lityum metal üretimine yönelik artan talebin, elektrik ve ulamdaki artan uygulanabilirliiyle bir araya gelmesiyle birlikte, yem malzemesi olarak kullanld için pazar gelirinde arta yol açmas bekleniyor.
LiCl, nükleer yaktn yeniden ilenmesinde elektrolit olarak kullanlr.
Sudaki çözünürlük:
68,29 g/100 mL (0 °C)
74,48 g/100 mL (10°C)
84,25 g/100 mL (25°C)
88,7 g/100 mL (40 °C)
123,44 g/100 mL (100°C)
Çözünürlük: hidrazin, metil formamid, bütanol, selenyum(IV) oksiklorür, 1-propanolde çözünür
Metanolde çözünürlük
45,2 g/100 g (0 °C)
43,8 gr/100 gr (20 °C)
42,36 gr/100 gr (25°C)
44,6 g/100 g (60 °C)
Etanolde çözünürlük
14,42 g/100 g (0 °C)
24,28 gr/100 gr (20°C)
25,1 gr/100 gr (30 °C)
23,46 gr/100 gr (60 °C)
Formik asitte çözünürlük
26,6 gr/100 gr (18 °C)
27,5 gr/100 gr (25°C)
Asetonda çözünürlük
1,2 g/100 g (20 °C)
0,83 gr/100 gr (25°C)
0,61 gr/100 gr (50°C)
Sv amonyakta çözünürlük
0,54 gr/100 gr (-34°C)
3,02 gr/100 gr (25°C)
Buhar basnc
1 torr (785 °C)
10 tor (934 °C)
100 tor (1130°C)
Manyetik duyarllk (χ): −24,3·10−6 cm3/mol
Krlma indeksi (nD): 1,662 (24 °C)
Viskozite: 0,87 cP (807 °C)[1]
Is kapasitesi (C): 48,03 J/mol·K[1]
Std molar entropi (S⦵298): 59,31 J/mol·K[1]
Std oluum entalpisi (ΔfH⦵298): -408,27 kJ/mol
Gibbs serbest enerjisi (ΔfG⦵): -384 kJ/mol[1]
Tuz tipik bir iyonik bileiktir (belirli kovalent özelliklere sahiptir).
Ancak Li+ iyonunun küçük boyutu, polar solventlerde olaanüstü çözünürlük (20 °C’de 83,05 g/100 mL su) ve higroskopik özellikleri gibi dier alkali metal klorürlerde görülmeyen özelliklere yol açar.
Lityum Klorür keskin, tuzlu bir tada ve kübik kristallere, kristal toz veya granül görünümüne sahiptir.
121°F erime noktasna ve 77°F’de 2.068 younlua sahiptir.
Sulu çözeltisi nötr ve biraz alkalidir
Lityum Klorür eter, nitrobenzen ve su alkollerinde çözünür
Lityum Klorürün Kimyasal Özellikleri:
Tuz, dier alkali metal klorürlerden farkl olarak kristalin hidratlar oluturur.
Mono-, tri- ve pentahidratlar bilinmektedir.
Susuz tuz, hidratlarn stlmasyla yeniden üretilebilir.
LiCl ayrca dört edeer amonyak/mol’e kadar emer.
Dier herhangi bir iyonik klorürde olduu gibi, lityum klorür çözeltileri bir klorür iyonu kayna olarak hizmet edebilir, örnein gümü nitratla ilemden sonra bir çökelti oluturabilir:
LiCl + AgNO3 → AgCl + LiNO3
Lityum klorürün hazrlanmas
Lityum klorür, en basit ekilde lityum hidroksit veya lityum karbonatn hidroklorik asitle reaksiyonuyla hazrlanabilir.
Susuz LiCl, hidrattan bir hidrojen klorür aknda stlarak hazrlanr.
Susuz LiCl, hidrolizi önlemek için kullanlan bir hidrojen klorür atmosferi altnda hafifçe stlarak hidrattan hazrlanr.
Sülfürik Asit ile Reaksiyon
Lityum klorür ve sülfürik asit reaksiyonu, hidrojen klorür ve lityum sülfat oluturur.
Reaksiyonun kimyasal denklemi öyledir:
2LiCl+H2SO4→2HCl+Li2SO4
Baz ile Reaksiyon
Lityum klorür bir alkaliyle (Sodyum Hidroksit gibi) reaksiyona girerek Sodyum Klorür ve Lityum Hidroksit oluturur.
LiCl+NaOH→LiOH+NaCl
Dier metal klorürler gibi lityum klorür tuzu da kristal hidratlar üretir.
Hidratlar sttktan sonra susuz tuzlarn yeniden üretebilirsiniz.
Ayrca mol bana dört edeer amonya kolaylkla emebilir.
Bununla birlikte, lityum klorür, bir iyonik klorür ile birletirildiinde esas olarak bir klorür iyonu kayna olarak görev yapabilir.
Lityum klorür, klorür iyonlarnn kayna olarak reaksiyona girebilir.
Dier herhangi bir çözünür iyonik klorürde olduu gibi, kurun (II) nitrat gibi uygun bir metal tuzu içeren bir çözeltiye eklendiinde çözünmeyen klorürleri çökeltecektir:
2 LiCl(sulu) + Pb(NO3)2(sulu) → PbCl2(ler) + 2 LiNO3(sulu)
Li+ iyonu belirli koullar altnda zayf bir Lewis asidi gibi davranr; örnein bir mol lityum klorür, dört mol amonyaa kadar emebilir.
Lityum klorürün kullanm alanlar
ntihara kar etkileri olan en iyi bilinen duygudurum dengeleyicilerden biri olan lityum klorür, u anda akut mani için bir ajan ve bipolar bozukluk için bir idame tedavisi olarak kullanlmaktadr.
Lityum Klorürün ticari uygulamalar
Lityum klorür esas olarak 450 °C’de (842 °F) LiCl/KCl eriyiinin elektrolizi yoluyla lityum metali üretmek için kullanlr.
Lityum klorür ayn zamanda otomobil parçalarnda alüminyum için lehimleme fluksu olarak da kullanlr.
Lityum klorür, düük erime noktalarna sahip çeitli tuz karmlarnda kullanlr ve bu da malzemenin sert lehim eritkenlerinde ve banyolarda kullanlmasna olanak tanr.
LiCl, hava akmlarn kurutmak için kurutucu olarak kullanlr.
Lityum klorür, daha özel uygulamalarda organik sentezde, örnein Stille reaksiyonunda bir katk maddesi olarak kullanlr.
Ayrca, lityum klorür biyokimyasal uygulamalarda hücresel ekstraktlardan RNA’y çökeltmek için kullanlabilir.
Lityum klorür ayn zamanda koyu krmz alevler üreten bir alev renklendiricidir.
Lityum Klorürün ni kullanmlar:
Higrometrelerin kalibrasyonunda bal nem standard olarak lityum klorür kullanlr.
25 °C’de (77 °F), doymu tuz çözeltisi (%45,8) %11,30’luk bir denge bal nemi verecektir.
Ek olarak lityum klorür higrometre olarak kullanlabilir.
Bu nemle eriyen tuz, havaya maruz kaldnda kendi kendine bir çözüm oluturur.
Ortaya çkan çözeltideki denge LiCl konsantrasyonu dorudan havann bal nemi ile ilgilidir.
25 °C’deki (77 °F) bal nem yüzdesi, 10–30 °C (50–86 °F) aralnda minimum hatayla aadaki birinci dereceden denklemden tahmin edilebilir: RH=107,93-2,11C burada C kütlece yüzde olarak çözelti LiCl konsantrasyonudur.
Erimi LiCl, karbon nanotüpleri, grafen ve lityum niyobat hazrlamak için kullanlr.
Lityum klorürün akarisit kat özelliklere sahip olduu ve bal ars popülasyonlarnda Varroa ykcsna kar etkili olduu gösterilmitir.
Lityum klorür, koullu yer tercihi ve kaçnmay incelemek için laboratuar hayvanlarnda caydrc bir madde olarak kullanlr.
Lityum klorür, >10 mS cm-1 iyonik iletkenlie sahip iyon iletken nötr polimer elektrolit olan LiCl-PAM’i (poliakrilamid) hazrlamak için kullanlabilir.
Lityum klorür, aldehitlerin ve ketonlarn karlk gelen silile edilmi siyanohidrinlere siyanosililasyonunda etkili bir katalizördür.
Selülozun esterifikasyonu için N,N-dimetilasetamid ile kombinasyon halinde bir reaksiyon ortam olarak.
Elektrokimya
Lityum metali, 450°C’de eriyen lityum klorür ve potasyum klorürün elektrolizi ile üretilir.
lemde hammadde olarak yüksek saflkta lityum klorür kullanlr ve yaklak %99,5 saf lityum metali elde edilir.
Erimi lityum, karbon çelii bir kapta tutulurken, klor gaz, dier ilemlerdeki uygulamalar için paslanmaz çelik veya cam bir boruda toplanr.
Erimi lityum bir toplama tankna akar ve daha sonra külçelere dökülür.
Ürünlerin karmasn önlemek için iki bölmeyi bir örgü veya paslanmaz çelik elek ayrr.
Lityum Klorürün Dier Uygulamalar
Lityum Klorür, koyu krmz alevler oluturmak için alev renklendirici olarak kullanlr.
Biyolojik uygulamalarda RNA’nn çökeltilmesinde kullanlr.
Lityum Klorür, otomobil parçalarnda alüminyum yanan bir aktr.
Düük scaklklarda lehimleme, kaynak teknikleri ve tuz banyosu sl ilemlerinde kullanlr.
Lityum klorür, klimlendirme endüstrisindeki büyük nem alma sistemlerinde kullanlr.
Bu, lityum klorür çözeltilerinin üzerindeki buharn düük denge basncna baldr.
Lityum klorür, LiCl/KCl eriyiinin 450 °C’de elektrolizi yoluyla lityum metali üretir.
LiCl ayrca otomobil parçalarnda alüminyum için lehim pastas olarak da kullanlr.
LiCl, Stille reaksiyonunun verimliliini arttrmak için kullanlabilir.
1940’larda ksa bir süre için tuz yerine lityum klorür üretildi, ancak bileiin toksik etkilerinin anlalmasndan sonra bu yasakland.
Önlemler
Lityum tuzlar merkezi sinir sistemini çeitli ekillerde etkiler.
Günümüzde bipolar bozukluu tedavi etmek için sitrat, karbonat ve orotat tuzlar kullanlrken, geçmite klorür dahil dier lityum tuzlar da kullanlyordu.
1940’larda ksa bir süre için, hipertansiyonu olan insanlar için tuz yerine kullanlan lityum klorür üretildi, ancak bileiin toksik etkileri (titreme, yorgunluk, mide bulants) fark edildikten sonra bu yasakland.
Bununla birlikte, J. H. Talbott, lityum klorür toksisitesine atfedilen birçok semptomun ayn zamanda sodyum klorür eksikliine, lityum klorür verilen hastalara sklkla uygulanan diüretiklere veya hastalarn altta yatan koullarna da atfedilebileceini belirtmitir.
Klorür, Lityum
Lityum Klorür
LTYUM KLORÜR
7447-41-8
LiCl
Lityumklorür
lityum klorür
Chlorku litu
klorolityum
Lityumklorür
Lityum klorür (LiCl)
lityum;klorür
CCRIS 5924
CHEBI:48607
lithii kloridum
HSDB4281
Lityum Klorür
litio’nun rengi
Lityum klorür (toz)
EINECS 231-212-3
MFCD00011078
NSC 327172
UNII-G4962QA067
LTYUM MURIATIKUM
G4962QA067
NSC-327172
Lityum Klorür, Susuz
LityumKlorürGr(Susuz)
CHEMBL69710
DTXSID2025509
EC 231-212-3
NSC327172
ClLi
Lityum klorür, ultra kuru
Chlorku litu [Lehçe]
Lutyum klorür
Klorür, Lityum
Chlorure de lityum [Franszca]
2M Lityum Klorür Elektrolit, Elektrot Dolum Solüsyonu
Lityum Klorür (Tetrahidrofuranda %2,3, yaklak 0,5mol/L)
lityum klorür
Lityum klorür, susuz, parçalar, %99,99 eser metal baznda
Lityum klorür susuz
Lopac-L-4408
LTYUM MONOKLORÜR
MolMap_000071
WLN: LI G
Lityum klorür, ACS snf
Lopac0_000604
LTYUM KLORÜR [MI]
Lityum klorür pil snf
Lityum klorür, ACS reaktifi
DTXCID105509
LTYUM KLORÜR [HSDB]
LTYUM KLORÜR [INCI]
LTYUM MURIATIKUM [HPUS]
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
LTYUM KLORÜR [WHO-DD]
Lityum klorür, THF’de %3-5
HMS3261J10
Tox21_500604
BDBM50494542
AKOS015902822
AKOS015950647
AKOS024438070
CCG-204693
lityum klorür, gama nlanm, 8 m
LP00604
SDCCGSBI-0050586.P002
Lityum klorür, ACS reaktifi, >=%99
Lityum klorür, ReagentPlus®, %99
NCGC00015607-01
NCGC00015607-02
NCGC00015607-03
NCGC00015607-04
NCGC00015607-07
NCGC00093980-01
NCGC00093980-02
NCGC00261289-01
BP-13612
SY002997
Lityum klorür, Vetec™ reaktif snf
AB-0100604
FT-0627896
L0204
L0222
Lityum klorür, Eser metal snf %99,9
L 4408
Lityum klorür, SAJ birinci snf, >=%98,0
Lityum klorür, moleküler biyoloji için, >=%99
Lityum klorür, SAJ özel snf, >=%99,0
A838146
Lityum klorür, BioXtra, >=%99,0 (titrasyon)
Q422930
SR-01000076252
SR-01000076252-1
Lityum klorür, toz, >=%99,99 eser metal baznda
Lityum klorür, puris. pa., susuz, >=%99,0 (AT)
Lityum klorür, susuz, boncuklar, -10 a gözü, >=%99,9 eser metal baznda
Lityum klorür, susuz, boncuklar, -10 gözenekli, %99,998 eser metal bazl
Lityum klorür, puris. pa.a., ACS reaktifi, susuz, >=%99,0 (AT)
Lityum klorür, susuz, serbest akl, Redi-Dri(TM), ACS reaktifi, >=%99
Lityum klorür, susuz, serbest akl, Redi-Dri(TM), ReagentPlus(R), %99
Lityum klorür, BioUltra, moleküler biyoloji için, susuz, >=%99,0 (AT)
59217-69-5
Madde adlar ve dier tanmlayclar
Düzenleyici süreç adlar
Lityum klorür
EC Envanteri
lityum klorür
Ön Kayt süreci
Lityum klorür (LiCl)
IUPAC adlar
LTYUM KLORÜR
Lityum Klorür
Lityum klorür
lityum klorür
Lityum Klorür
Lityum Klorür Susuz
Lityum klorür susuz
Lityum klorür, susuz
Lityum monoklorür
lityum(1+) klorür
lityum(1+) iyon klorür
LTYUM-KLORÜR-
lityum;klorür
Lityumklorür
lityumklorür
lityum klorür
Ticari isimler
Klorür Lityum Susuz
Lityum klorür
Lityum klorür [ACD/IUPAC Ad] [Wiki]
231-212-3 [EINECS]
7447-41-8 [RN]
Klorür, Lityum
Chlorku litu [Lehçe]
Lityum klorür [Franszca] [ACD/IUPAC Ad]
cloruro de litio [talyanca]
G4962QA067
hidroklorik asit lityum tuzu
LiCl [Formül]
Lityumklorür [Almanca] [ACD/IUPAC Ad]
[7447-41-8] [RN]
16712-20-2 [RN]
20233-17-4 [RN]
404596-80-1 [RN]
7789-01-7 [RN]
85144-11-2 [RN]
CHEMBL69710
Chlorku Litu
Chlorku litu [Lehçe]
klorolityum
Chlorure de lityum [Franszca]
litio’nun rengi
D018021
EINECS 231-212-3
Elektrolit kayb
LiCl231-212-3MFCD00011078
lithii chloridum [Latince]
lithii kloridum
Lityum klorür (toz)
Lityum klorür, susuz
Lityum klorür eksik
LTYUM MONOKLORÜR
lityum;klorür
LTYUM-7LI KLORÜR
lityumklorür
Lityum eksik
Lopac0_000604
MFCD00011078 [MDL numaras]
MFCD00149764
MFCD00190539
MolMap_000071
OmniPur Lityum Klorür
ATAMAN KMYA’NIN LGNZ ÇEKEBLECEK DER ÜRÜNLER:
Lityum astatid
Lityum bromür
Lityum karbonat
Lityum florür
Lityum Hidroksit
Lityum iyodür
Lityum Nitrat