HYPOPHOSPHORIC ACID (HPOFOSFORK AST)
HYPOPHOSPHORIC ACID
CAS NO: 7803-60-3
METATAGS;Hypophosphoric acid;phosphonophosphonic acid;7803-60-3;UNII-CY8Z35442Z;hypodiphosphoric acid;Unterdiphosphorsaeure;AC1L2NI4;AC1Q7DL6;H4P2O6;DTXSID0064886;CHEBI:29263;CTK2H8649;TVZISJTYELEYPI-UHFFFAOYSA-N;CY8Z35442Z;bis[dihydroxidooxidophosphorus](P–P);[(HO)2P(O)P(O)(OH)2];IN003741;IN018993;1,1,2,2-Tetrahydroxydiphosphine 1,2-dioxide;Acide hypodiphosphorique ;Hypodiphosphoric acid ;Hypodiphosphorsure ;Hypophosphoric acid ;[(HO)2P(O)P(O)(OH)2];bis[dihydroxidooxidophosphorus](P–P);bis[dihydroxidooxidophosphorus](P–P); hypodiphosphoric acid;H4P2O6;phosphonophosphonic acid;phosphonophosphonicacid;UNII:CY8Z35442Z;UNII-CY8Z35442Z;Unterdiphosphorsaeure;HYPOPHOSPHORIC ACID;HYPOPHOSPHORICACID;HYPOPHOSPHORICASIT;HYPOPHOSPHORIC ASIT;HYPOPHOSTORIK ASIT;HYPOPHOSTORIK ACID;Hypophosphoric Acid;Hypophosphoric Asit;Hypophosphorik Asit;Hypophosphoric acid;Hypophosphoric asit;HypophosphoricAcid;HypophosphoricAsit;HypophosphorikAsit;Hypophosphoricacid;Hypophosphoricasit;hydrofosforikasit;hydrofosforkast;hydrophosparikasit;hydrofosforik asit;hydrofosforik acid;hyprofosforik asit;hypropshorik asit;hydrofosfork acid;hydrofosforik asit;hypophosphorc acd;hypophosphorik asit kullanm alanlar;hyfosforik asit kullanm alanlar;hydrofosforkasit ve kozmetik;hypophosphorc acd and cosmetics;HDROFOSFORK AST;hidrofosforikasit;hypofosforic acid;Hipofosforik asit;Hipofosforikasit;HIPOFOSFORIKASIT;HIPOFOSFORIK ASIT
Chemical and Physical Properties of Hypophosphoric Acid
Computed Properties of Hypophosphoric Acid
Property Name
Molecular Weight: 161.974 g/mol
Hydrogen Bond Donor Count: 4
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 1
Complexity: 135
Topological Polar Surface Area: 115 A^2
Monoisotopic Mass: 161.948 g/mol
Exact Mass: 161.948 g/mol
XLogP3-AA: -3.2
Compound Is Canonicalized: true
Formal Charge: 0
Heavy Atom Count: 8
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1
Hypophosphoric Acid, H3PO3, together with phosphorous and phosphoric acids, was first produced by the slow oxidation of phosphorus in the air and in the presence of water at a moderately low temperature (5 to 10 C.); it was isolated through the formation of a sparingly soluble sodium salt.
It was also produced by the slow oxidation of phosphorus with silver nitrate in neutral or ammoniacal solution.
Oxidation of yellow phosphorus by copper nitrate in the presence of nitric acid at about 60 C. also yielded hypophosphoric acid along with phosphoric acid and copper phosphide. These reactions have been expressed by the equations
4P + 5Cu(NO3)2 + 8H2O = Cu3P2 + 2Cu + 10HNO3 + 2H3PO4
4P + 4Cu(NO3)2 + 6H2O = Cu3P2 + Cu + 8HNO3 + H4P2O6
Better yields were obtained by the electrolysis of 1 to 2 per cent, sulphuric acid using anodes of copper or nickel phosphide.
Hypophosphorous Acid Uses
Bleaching Agent
Hypophosphorous Acid is used as a bleaching or decolorizing agent for plastics, synthetic fibers, and chemicals
Color Stabilizer
HPA is used as a decolorizing agent and for color stabilization during the manufacture of chemicals and several plastics including: nylon fibers, polyamides, polyester fiber, polyacrilonitrile, alkyd rsins, epoxies, fatty acid esters, and glycerols.
Hypophosphite Salts
Hypophosphorous Acid is used in the production of Hypophosphite Salts (i.e., Calcium, Magnesium, Manganese, Potassium, Iron, and Ammonium) which are in turn used in synthetic fibers as wetting dispersing, emulsifying, and anti-static agents
Chemical Intermediate
Used in organic synthesis and organo phosphinic acid production
Neturalizing Agent
Used as a moderately strong monobasic acid
Catalyst
Used as a polymerization and polycondensation catalyst
Wetting Agent
Used as a wetting, dispersing, or emulsifying agent in electroplating
Reducing Agent
May be used for its strong but slow reducing action
Antioxidant
Hypophosphorous Acid may be used as an antioxidant
Pharmaceutical
HPA may be used as a stimulant in pharmaceuticals.
Hipofosforik Asitin Kimyasal ve Fiziksel zellikleri
Hipofosforik Asidin Hesaplanan zellikleri
zellik ad
Molekler Arlk: 161.974 g / mol
Hidrojen Bam Balayc Says: 4
Hidrojen Ba Alc Says: 6
Dnebilen Ba Saym: 1
Karmaklk: 135
Topolojik Polar Yzey Alan: 115 A ^ 2
Monoizotopic Ktle: 161.948 g / mol
Tam Ktle: 161.948 g / mol
XLogP3-AA: -3.2
Bileik Canonicalized: true
Resmi arj: 0
Ar Atom Says: 8
Tanml Atom Stereocenter Says: 0
Tanmsz Atom Stereocenter Says: 0
Tanmlanm Bond Stereocenter Says: 0
Tanmlanmam Bond Stereocenter Says: 0
zotop Atom Says: 0
Kovalent Bal Birim Says: 1
Hipofosforik Asit, H3PO3, fosfor ve fosforik asitlerle birlikte, fosforun havadaki yava oksidasyonu ve orta derecede dk bir scaklkta (5 ila 10 C) su varlnda retildi; Az znen bir sodyum tuzunun olumasyla izole edildi.
Ntr veya amonyakl zeltideki gm nitratla fosforun yava oksidasyonu ile de retildi.
Yaklak 60 C`de nitrik asit varlnda bakr nitrat ile sar fosforun oksidasyonu ayrca fosforik asit ve bakr fosfitle birlikte hipofosforik asit vermitir. Bu reaksiyonlar denklemlerle ifade edilmitir
4P + 5Cu (NO3) 2 + 8H2O = Cu3P2 + 2Cu + 10HNO3 + 2H3PO4
4P + 4Cu (NO3) 2 + 6H2O = Cu3P2 + Cu + 8HNO3 + H4P206
Bakr ya da nikel fosfat anotlar kullanlarak slfrik asidin yzde 1 ila 2`sinin elektrolizi ile daha iyi verim elde edildi.
Hipofosforik Asit Kullanmlar
Aartc madde
Hypophosphorous Asit, plastik, sentetik lifler ve kimyasallar iin aartc veya renk giderici ajan olarak kullanlr
Renk Sabitleyici
HPA, renk giderici madde olarak ve naylon lifler, poliamidler, polyester lif, poliakrilonitril, alkid reineleri, epoksiler, ya asidi esterleri ve gliseroller gibi kimyasallarn ve birka plastik retiminde renk dengelemesi iin kullanlr.
Hipofosfit Tuzlar
Hipofosfor Asidi, slak dispersiyon, emlsiyon haline getirici ve anti-statik ajanlar olarak sentetik liflerde kullanlan Hypophosphite Tuzlarnn (yani, Kalsiyum, Magnezyum, Manganez, Potasyum, Demir ve Amonyum) retiminde kullanlr.
Kimyasal Ara
Organik sentez ve organo fosfinik asit retiminde kullanlr
viletirici ajan
Orta derecede gl bir monobazik asit olarak kullanlr
katalizatr
Polimerizasyon ve polikondensasyon katalizr olarak kullanlr.
Islatc Ajan
Elektrodasyonda slak, dispersiyon haline getirici veya emlsiyon haline getirici bir ajan olarak kullanlr.
ndirgen madde
Gl fakat yava yava azaltma eylemi iin kullanlabilir
Antioksidan
Hypophosphorous Asit bir antioksidan olarak kullanlabilir
la
HPA, ilalarda uyarc olarak kullanlabilir