ADIPIC ACID DIHYDRAZIDE

Table of Contents

ADIPIC ACID DIHYDRAZIDE

ADIPIC ACID DIHYDRAZIDE
CAS NUMBER: 1071-93-8
EC NUMBER: 213-999-5


SYNONYMS: Adipic dihydrazide; Adipohydrazide; 1071-93-8; Adipic acid dihydrazide; Hexanedihydrazide; Hexanedioic acid, dihydrazide; Hexanediohydrazide; Adipyl hydrazide; Adipic acid, dihydrazide; Adipodihydrazide; Adipoyl hydrazide; Hexanedioic acid, 1,6-dihydrazide; Hexanedioic acid dihydrazide; IBVAQQYNSHJXBV-UHFFFAOYSA-N; MFCD00007614; LN: ZMV4VMZ; butane-1,4-dicarbohydrazide; Adip dihydr; Adipoyldihydrazine; dipic dihydrazone; adipoyl dihydrazide; adipinic dihydrazide; Hexanedihydrazide #; NSC 3378; EINECS 213-999-5; NSC 29542; Adipic acid dihyrazide; adipic acid dihydrizide; zerenex zx005030; ACMC-1BQYJ; AI3-22640; C1L24NT; DSSTox_CID_24361; DSSTox_RID_80169; VK98I9YW5M; DSSTox_GSID_44361; CHEMBL49856; KSC490O5J; Adipic Acid Dihydrazide (ADH); Jsp000643; CHEMBL3185968; DTXSID0044361; SCHEMBL11037942; Adipic acid, dihydrazide (8CI); TK3J0754; KS-00000INN; NSC3378; MolPort-000-146-044; BB_SC-0094; ACN-S001959; ALBB-011767; NSC-3378; NSC29542; STR02658; ZINC1666741; Tox21_301067; NW-15495; BBL022965; NSC-29542; SBB038773; STK709135; AKOS000267183; MCULE-3799591323; RP23642; RTR-001401; TRA0008268; NCGC00248276-01; NCGC00257525-01; K163609; AN-48397; CJ-26984; KB-74518; LP124564; OR020018; SC-19119; CAS-1071-93-8; DB-022418; TR-001401; A0170; Adipic acid dihydrazide, >=98% (titration); FT-0621914; ST24045925; ST45027596; Y-8670; Adipic acid dihydrazide, purum, >=97.0% (NT); A801603; J-660023; Q-200600; S14-1488; 56812730; F1943-0024; 124246-54-4; 98152-55-7; InChI=1/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12; adipic acid dihydrazide; adipic dihydrazide; hexanedihydrazide; InChI=1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12); IBVAQQYNSHJXBV-UHFFFAOYSA-N; C(CCC(=O)NN)CC(=O)NN; VK98I9YW5M; ADH; ZERENEX ZX005030;HEXANEDIOIC ACID; DIHYDRAZIDE; HEXANEDIHYDRAZIDE; HEXANEDIOHYDRAZIDE; ADH; ADIPINIC dIHYDRAZIDE; ADIPIC DIHYDRAZIDE; ADIPIC ACID DIHYDRAZIDE; adipik; adipikasit; adipik aist dihidrazid; adipik asit dihidrazit; adipik asit dihidrazide; adipikasitdihitrazit; dihitrazit; Adipic Dihydrazide; ADH; Hexandihydrazide; Hexanedioic acid, 1,6-dihydrazide; ADIP; adipkastdydrazit; adpk; adpcacide; adpcastdihitrat; adipikasitttdiidrazit; 1071-93-8; NH2NHCO(CH2)4CONHNH2; 174.20; MFCD00007614; 973863; IBVAQQYNSHJXBV-UHFFFAOYSA-N; Adipic Dihydrazide; ADH; Hexandihydrazide; Hexanedioic acid, 1,6-dihydrazide; C6H14N4O2; ADH; 403; dihydrazide; Adip dihydr; WLN: ZMV4VMZ; Adipohydrazide; ZERENEX; ZX005030; ADIPODIHYDRAZIDE; ADIPYL HYDRAZIDE; adipoyl hydrazide; CBNumber:CB4129556; CAS DataBase Reference1071-93-8(CAS DataBase Reference); NIST Chemistry ReferenceAdipic dihydrazide(1071-93-8); EPA Substance Registry SystemHexanedioic acid, dihydrazide(1071-93-8); Adipic dihydrazide for synthesis; Adipic dihydrazide for synthesis; Adipic Dihydrazide >99.0%(HPLC); Adipic Dihydrazide >99.0%(HPLC); Adipic dihydrazide, 97%; A291595; Adipic Acid Dihydrazide; Hexanedioic Acid Dihydrazide; ADH; ADH (hydrazide); ADH 4S; ADH-J; ADH-S; Adipic Dihydrazide; Adipoyl Dihydrazide; Adipoyl Hydrazide; Adipoyldihydrazine; Ajicure ADH; BK 1000Z; BT 1000Z; NSC 29542; NSC 3378; Qualimer ADH; T 2210; Adipohydrazide; hexanedioic acid; hexanedihydrazide; Adipic acid dihydrazide; 10g; C6H14N4O2; MFCD00007614; mw 174.20; [1071-93-8]; RM10643-50g; Adipohydrazide; InChI=1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12); IBVAQQYNSHJXBV-UHFFFAOYSA-N; Adipic acid dihydrazide; Adipyl hydrazide; Adipic acid dihyrazide; Hexanedioic acid, dihydrazide; 403; adipohydrazide; Hexanedioic-d8 Acid Dihydrazide; Adipic acid dihydrazide; Adipyl hydrazide; MFCD00007614; 4156-1-14; 213-999-5; Hexanedioic acid dihydrazide; adipic acid dihydrazide; dimethyl adipate; adipic acid hydrazine hydrate; methanol; Adipic acid dihydrazide; Adipyl hydrazide; Adipic acid dihyrazide; Hexanedioic acid, dihydrazide; 403; Hexanedihydrazide; Adipic acid; Hexamethylenediamine; adipic acid; laurolactam; caprolactam polymer; octafluoroadipic acid; Carbonic dihydrazide; Adipic acid monoethyl ester; Terephthalic dihydrazide; Carbonothioic dihydrazide; dimethyladipic acid; Adipic acid; diphenyl ester; Adipic dihydrazide; exanedihydrazide; HexanedioicAcid; dihydrazide; Adipic Dihydrazide; 4 – Chlorobenzene Sulfonylchloride; 5 – Sulpho Isophthalic Acid Sodiumsalt; Adipic Acid Dihydrazide; Amino – Tris – Methylphosphonic Acid; Benzene Sulphonic Acid (70%, 90% And 98%); Benzene Sulphonyl Chloride; Bloodorange; Evernox 1330; Evernox 3114; Evernox 76; Evernox B310; Glycine; Grapefruit 1x Fold, 3x Fold, 5x Fold, 10x Fold | Hydroxyethylidenediphosphonic Acid Sodium Salt | Methyltriacetoxysilane | N – Butyl – Benzene Sulphonamide; N-(2-Aminoethyl)-3-Aminopropyl-Methyldimethoxysilane; N-(3-trimethoxysilylpropyl)Diethylentriamine; N-(Benzyl)-2-Aminoethyl-3-Aminopropyltrimethoxysilane HCl Salt; ADH; ADIPIC DIHYDRAZIDE; Adipic acid dihyrazide; Adipic dihydrazide; Adipohydrazide; Adipyl hydrazide; 403; Adipic acid dihydrazide; Adipic acid dihyrazide; Adipyl hydrazide; Hexanedioic acid, dihydrazide; adipohydrazide; Hexanedioic acid dihydrazide; Adipodihydrazide; Adipic dihydrazide; slightly yellow crystalline powder; aidipikasitdihidrazit; hidrazit; adipik; adipikasit; aidipic; acide; aidipicasidedihydrazide; dihydrazide

 

 

 

 

 

 

ADH is crosslinker of wanterborne acryl emulsions. ADH is a crosslinker of waterborne acryl emulsions. It is also useful as an epoxy resin hardener and a formaldehyde scavenger. ADH is also useful as an epoxy resin hardener and a formaldehyde scavenger. Adipic Acid Dihydrazide is a chemcial intermediate and specialty chemical often used in adhesive and coating-manufacturing applications. Adipic Acid Dihydrazide offers amino- and keto-functionality at either end of the molecule which makes it an excellent cross-linking agent for water-based emulsions. Adipic acid dihydrazide is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages. Adipic acid dihydrazide is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation. Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines. ADH reacts very rapidly with ketone groups. For example, it reacts easily with ketone groups of diacetone acrylamide or aldehyde groups of formaldehyde. In addition, ADH also reacts with the epoxy group like an amino compound.
Adipic Acid Dihydrazide (ADH) is widely used as cross-linker in waterborne acrylic emulsions. Adipic acid dihydrazide (ADH) is obtained through the reaction of adipic acid and hydrazine. It is a white powder. Adipic acid dihydrazide (ADH) is used as hardener for epoxy systems and as a crosslinking agent for water born acryl systems. Dihydrazides will cure an isocyanate through the primary amine to form the urea. This reaction is useful as chain extender and crosslinking agent for urethane coatings, adhesives and emulsions. ADH is water soluble.

Adipic Acid Dihydrazide is used as chain extender in the preparation of waterborne polyurethane binders and secondly as crosslinker in waterbased coatingsused as chain extender in the preparation of waterborne polyurethane binders and secondly as crosslinker in waterbased coatings. Adipic Acid Dihydrazide is used as chain extender in the preparation of waterborne polyurethane binders and secondly as crosslinker in waterbased coatings. In the past, Adipic Acid Dihydrazide was reported to be used in the formulation of fragrances and sachets.

The synthesis of adipic acid dihydrazide by two steps was investigated in this paper. Adipic acid was first esterified with methanol under the catalysis of KHSO4 to give dimethyl adipate, which was further reacted with hydrazine hydrate to produce adipic acid dihydrazide (ADH) with a high purity. The optimal conditions for the esterification reaction were determined as catalyst amount was 5.5% of the weight amount of adipic acid, molar ratio of methanol to adipic acid was 4.0, reaction time was 1.0 h. Under these conditions, the purity of dimethyl adipate was as high as 998% and the yield was 77%. For the hydrazide reaction, the optimal conditions were: molar ratio of both hydrazine hydrate and methanol to dimethyl adipate was 4.0, reaction time was 1.5 h. Under these conditions, the yield of adipic acid dihydrazide reached 99% and the purity was 99.5%.

PROPERTIES
Appearance: White Crystals
Formula: C6H14N4O2
Mol.weight: 174.2
Purity: MN. 98%
Loss on drying: max. O.4%
Melting Point: 177-184 C
Solubility in Water: 9.1 g / water at 20 C
Specific Gravity: 1.25 g / cm3
Boiling point 426°C
Melting point 181°C
Ignition temperature 360°C
Density at 20°C 1.29 g/cm3


Adipic acid dihydrazide (ADH) is obtained through the reaction of adipic acid and hydrazine. It is a white powder. Adipic acid dihydrazide (ADH) is used as hardener for epoxy systems and as a crosslinking agent for water born acryl systems. Adipic Acid Dihydrazide (ADH) is a high melting point compound by the reaction of organic acid and hydrazine. It can be used as epoxy resin (EP) of the potential curing agent. The powder coating by using EP/SPH as binding materials has very good flexibility, water resistance, weather resistant, anti-corrosion, insulation and decorative features.

Adipic Acid Dihydrazide (ADH) is widely used as cross-linker in waterborne acrylic emulsions. Adipic Acid Dihydrazide is used to functionalize magnetic nanoparticles for gylcopeptitde enrichment and identification. Adipic Acid Dihydrazide can also be used as a chain extension for liquid rubber.

Adipic Acid (also called hexanedioic acid) is a white, crystalline compound of C6 straight-chain dicarboxylic acid; slightly soluble in water and soluble in alcohol and acetone. Almost all of the commercial adipic acid is produced from cyclohexane through two sequent oxidation processes. The first oxidation is the reacting of cyclohexane with oxygen in the presents of cobalt or manganese catalysts at a temperature of 150 – 160 C, which produce cyclohexanol and cyclohexanone. Then, the intermediates are further reacted with nitric acid and air with a catalyst (copper or vanadium) or without nitric acid. Cyclohexane can be prepared by the hydrogenation of benzene. There are other ways such as the reactions using phenol, butadiene, and various fats as the starting material. Adipic acid consumption is linked almost 90% to nylon production by the polycondensation with hexamethylenediamine. Nylon, having a protein-like structure, is further processed into fibers for applications in carpeting, automobile tire cord and clothing. Adipic acid is used in manufacturing plasticizers and lubricants components. It is used in making polyester polyols for polyurethane systems. Food grade adipic acid is used as gelling aid, acidulant, leavening and buffering agent. Adipic acid has two carboxylic acid, -COOH, groups, which can yield two kinds of salts. Its derivatives, acyl halides, anhydrides, esters, amides and nitriles, are used in making target products such as flavoring agents, internal plasticizers, pesticides, dyes, textile treatment agents, fungicides, and pharmaceuticals through further reactions of substitution, catalytic reduction, metal hydride reduction, diborane reduction, keto formation with organometallic reagents, electrophile bonding at oxygen, and condensation.
Hydrazine (anhydrous) is a clear, fuming, corrosive liquid with an ammonia-like odor; melting at 1.4 C, boiling at 113.5 C, specific gravity 1.011. It is very soluble in water and soluble in alcohol. It decomposes on heating or exposure to UV to form ammonia, hydrogen, and nitrogen, which may be explosive with a blue flame when catalysed by metal oxides and some metals such as platinum or Raney nickel. It is prepared from ammonia with chloramine in the presence of glue or gelatin (to inhibit decomposition of the hydrazine by unreacted oxidants) as the hydrate form usually (100% monohydrate contains 64% by weight hydrazine). Hydrazine is also prepared from sodium hypochlorite with urea in the presence of glue or gelatin. Botht ammonia and amines are nitrogen nucleophiles which donate electrons (they are Lewis bases). But hydrazine (diamine) has much stronger nucleophilicity which makes it more reactive than ammonia. Hydrazine has dibasic and very reactive properties. Hydrazine is used as a component in jet fuels because it produce a large amount of heat when burned. Hydrazine is used as rocket fuel. Hydrazine is used as an oxygen scavenger for water boiler feed and heating systems to prevent corrosion damage. Hydrazine is used as a reducing agent for the recovery of precious metals. It is used as a polymerization catalyst and a chain extender in urethane coatings. It and its derivatives are versatile intermediates. They have active applications in organic synthesis for agrochemicals, pharmaceuticals, photographic, heat stabilizers, polymerization catalysts, flame-retardants, blowing agents for plastics, explosives, and dyes. Recently, hydrazine is applied to LCD (liquid crystal displays) as the fuel to make faster thin-film transistors. Hydrazide is an acyl hydrazine. Acyl (-CO) is an organic radical formed by removal of a hydroxyl group from an organic acid (carboxyl group). Adipoyl hydrazide is used as polyurethane dispersion.

FEATURES
ADH reacts very rapidly with ketone groups.
For example, it reacts easily with ketone groups of diacetone acrylamide or aldehyde groups of formaldehyde.
In addition, ADH also reacts with the epoxy group like an amino compound. Adipic Acid Dihydrazide is a chemcial intermediate and specialty chemical often used in adhesive and coating-manufacturing applications. It offers amino- and keto-functionality at either end of the molecule which makes it an excellent cross-linking agent for water-based emulsions. Specialty Chemicals, Chemical Intermediates, Adhesives, Coatings and Sealants Chemicals, Intermediates, Cross-linking Agent, Industrial, Resin & Coating, Specialty Chemicals, Plastics.
Homobifunctional cross-linking reagent that is specific for aldehydes resulting in relatively stable hydrazone linkages. This is commonly used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation. Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines. Note that the hydrazone bond may be stabilized by selective reduction using, for example, sodium cyanoborohydride.


Physical Description
DryPowder
OtherSolid


APPLICATIONS
Adipic acid dihydrazide is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages. Adipic acid dihydrazide is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation. Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines.

Room temperature crosslinkable waterborne coatings .
Acryl emulsion comprising acryl monomers and diacetone acrylamide crosslinks with amino groups of ADH very rapidly.
The coating has excellent water resistance.

Formaldehyde scavenger.
ADH reacts with formaldehyde and prevents volatilizing of formaldehyde in the air. Epoxy resin hardener; ADH reacts with epoxy resin at high temperature and is useful for powder coating. Reforming of plastic and fiber processing.

ADH is widely applied in the decorative powder, insulation powder, fire retardent powder, electricals powder, heavy-duty powders. Particularly in the manufacturing high-quality heavy-duty high-temperature fast-curing powder and oil pipelines, aerospace, aviation fuel, and other areas, it acts as essential potential curing agent. It also has the features to increase strength in epoxy powders and UPR products with very satisfactory results.

INDUSTRY USES
Intermediates
Paint additives and coating additives not described by other categories, Paints and Coatings.

 

 

 

 

 

 

 

ADH, wanterborne akril emülsiyonlarnn çapraz balaycdr. ADH su bazl akril emülsiyonlarnn çapraz balaycdr. Ayn zamanda bir epoksi reçine sertletiricisi ve bir formaldehit temizleyici olarak da yararldr. ADH, epoksi reçine sertletiricisi ve formaldehit temizleyicisi olarak da kullanldr. Adipik Asit Dihidrazid, yapkan ve kaplama üretim uygulamalarnda skça kullanlan kimyasal bir ara ürün ve özel kimyasaldr. Adipik Asit Dihidrazid, su bazl emülsiyonlar için mükemmel bir çapraz balayc ajan haline getiren molekülün her iki ucunda amino ve keto ilevsellii sunar. Adipik asit dihidrazid, aldehitler için spesifik olan ve nispeten kararl hidrazon balar oluturan homobifonksiyonel çapraz balama reaktifi. Adipik asit dihidrazid, tipik olarak periyodat oksidasyonunu takiben, siteye özgü bir tarzda, antikorlar gibi glikoproteinlerin balanmasnda kullanlr. Oksidasyon ve balanma, primer aminler tarafndan rekabeti önleyen, hidrazidin düük pKa’s nedeniyle, pH 5.0’de uygun bir ekilde gerçekletirilebilir. ADH, keton gruplaryla çok hzl tepki verir. Örnein, diaseton akrilamid veya aldehid formaldehit gruplarnn keton gruplar ile kolayca reaksiyona girer. Buna ek olarak, ADH ayn zamanda bir amino bileii gibi epoksi grubuyla reaksiyona girer.
Adipik Asit Dihidrazid (ADH), su bazl akrilik emülsiyonlarda çapraz balayc olarak yaygn olarak kullanlr. Adipik asit dihidrazid (ADH), adipik asit ve hidrazin reaksiyonu yoluyla elde edilir. Beyaz bir toz. Adipik asit dihidrazid (ADH) epoksi sistemleri için sertletirici olarak ve sudan üretilen akrilik sistemler için çapraz balayc bir madde olarak kullanlr. Dihidrazitler üre oluturmak üzere birincil amin araclyla bir izosiyanat sertletireceklerdir. Bu reaksiyon, üretan kaplamalar, yaptrclar ve emülsiyonlar için zincir uzatc ve çapraz balama ajan olarak yararldr. ADH suda çözünür.

Adipik Asit Dihidrazid, suyla tanan poliüretan balayclarn hazrlanmasnda zincir uzatma maddesi olarak ve ikinci olarak, su bazl poliüretan balayclarn hazrlanmasnda zincir uzatcs olarak kullanlan su bazl kaplamalarda çapraz balayc olarak ve ikinci olarak da su bazl kaplamalarda çapraz balayc olarak kullanlr. Adipik Asit Dihidrazid, su bazl poliüretan balayclarn hazrlanmasnda zincir geniletici olarak ve ikinci olarak da su bazl kaplamalarda çapraz balayc olarak kullanlr. Geçmite, Adipik Asit Dihidrazid’in koku ve poet formülasyonunda kullanlmas bildirilmitir.

Bu yazda adipik asit dihidrazid’in iki aamal sentezi aratrlmtr. Adipik asit önce KHSO4 katalizörü altnda metanol ile esterletirilerek dimetil adipat elde edildi ve bu yüksek saflk derecesinde adipik asit dihidrazid (ADH) üretmek üzere hidrazin hidratla daha da reaksiyona sokuldu. Esterifikasyon reaksiyonu için optimal koullar, katalizör miktar, adipik asit arlk miktarnn% 5.5’i, metanolün adipik aside mol oran 4.0, reaksiyon süresi 1.0 saat olarak belirlenmitir. Bu koullar altnda, dimetil adipatn safl% 99.88’e kadar çkt ve verim% 77 idi. Hidrazid reaksiyonu için en uygun koullar: hidrazin hidrat ve metanolün dimetil adipata mol oran 4.0, reaksiyon süresi 1.5 saat idi. Bu koullar altnda, adipik asit dihidrazidin verimi% 99’a ulat ve saflk% 99.5 oldu.

ÖZELLKLER
Görünü: Beyaz Kristaller
Formül: C6H14N4O2
Mol.weight: 174.2
Saflk: MN. % 98
Kurumadaki kayp: maks. O.4%
Erime noktas: 177-184 ° C
Suda Çözünürlük: 20 C’de 9.1 g / su
Özgül Arlk: 1.25 g / cm3
Kaynama noktas 426 ° C
Erime noktas 181 ° C
Tutuma scakl 360 ° C
Younluk 20 ° C’de 1.29 g / cm3


Adipik asit dihidrazid (ADH), adipik asit ve hidrazin reaksiyonu yoluyla elde edilir. Beyaz bir toz. Adipik asit dihidrazid (ADH) epoksi sistemleri için sertletirici olarak ve sudan üretilen akrilik sistemler için çapraz balayc bir madde olarak kullanlr. Adipik Asit Dihidrazid (ADH), organik asit ile hidrazin reaksiyonu sonucu yüksek erime noktal bir bileiktir. Potansiyel kürleme maddesinin epoksi reçinesi (EP) olarak kullanlabilir. EP / SPH’yi balayc malzemeler olarak kullanarak toz boya, çok iyi bir esneklik, suya dayankllk, hava koullarna dayankl, korozyon önleyici, izolasyon ve dekoratif özelliklere sahiptir.

Adipik Asit Dihidrazid (ADH), su bazl akrilik emülsiyonlarda çapraz balayc olarak yaygn olarak kullanlr. Adipik Asit Dihidrazid, gylcopeptitde zenginletirme ve tanmlama için manyetik nanopartiküllerin ilevselletirilmesi için kullanlr. Adipik Asit Dihidrazid sv kauçuk için bir zincir uzants olarak da kullanlabilir.

Adipik Asit (ayrca heksandioik asit olarak da adlandrlr), C6 düz zincirli dikarboksilik asidin beyaz, kristal halindeki bir bileiidir; suda az çözünür ve alkol ve asetonda çözünür. Hemen hemen tüm ticari adipik asit iki ardk oksidasyon ilemi vastasyla sikloheksandan üretilir. lk oksidasyon sikloheksanol ve siklohekzanon üreten 150-160 ° C’lik bir scaklkta kobalt veya manganez katalizörlerinin hediyelerinde sikloheksann oksijenle reaksiyona sokulmasdr. Ardndan, ara maddeler, nitrik asit ve hava ile bir katalizör (bakr veya vanadyum) ile veya nitrik asit olmadan daha da reaksiyona sokulur. Sikloheksan, benzen hidrojenasyonu ile hazrlanabilir. Balangç ​​materyali olarak fenol, bütadien ve çeitli yalar kullanan reaksiyonlar gibi baka yollar da vardr. Adipik asit tüketimi, hekzametilendiamin ile polikondansasyon ile neredeyse% 90 naylon üretimiyle balantldr. Protein benzeri bir yapya sahip olan naylon, hal, otomobil lastii kordonu ve giysilerinde kullanlmak üzere liflere daha da ilenir. Adipik asit plastikletiriciler ve yalayc bileenlerinin imalatnda kullanlr. Poliüretan sistemler için poliester poliollerin yapmnda kullanlr. Gda snf adipik asit jelletirme yardmcs, asitleme maddesi, kabartma ve tamponlayc madde olarak kullanlr. Adipik asit, iki çeit karboksilik asit, -COOH grubuna sahiptir ve bu iki çeit tuz oluturabilir. Türevleri, açil halidleri, anhidritleri, esterleri, amidleri ve nitriller, tatlandrc maddeler, iç plastikletiriciler, böcek öldürücüler, boyalar, tekstil ileme maddeleri, fungisitler ve farmasötik maddeler gibi hedef ürünlerin yerine konuma, katalitik indirgeme, metal hidrür indirgemesi, diboran indirgemesi, organometalik ayraçlarla keto oluumu, oksijenle elektrofil balanmas ve younlama.
Hidrazin (susuz), amonyak benzeri bir kokuya sahip, berrak, köpüren, andrc bir svdr; 1,4 ° C’de erime, 113.5 ° C’de kaynama, özgül arlk 1.011. Suda çok çözünür ve alkolde çözünür. Metal oksitler ve platin veya Raney nikeli gibi baz metaller tarafndan katalize edildiinde mavi bir alevle patlayabilen amonyak, hidrojen ve azotu oluturmak için stma veya UV’ye maruz brakldnda ayrr. Hidrat biçimi genellikle (% 100 monohidrat arlk olarak% 64 hidrazin içerdiinden) yapkan veya jelatin varlnda kloramin ile amonyaktan (hidrazinin reaksiyona girmemi oksitleyiciler tarafndan ayrmasn önlemek için) hazrlanr. Hidrazin ayrca sodyum hipokloritten üre ile tutkal veya jelatin varlnda hazrlanr. Hem amonyak hem de aminler, elektronlar balayan azot nükleofilleridir (bunlar Lewis bazlardr). Ancak hidrazin (diamin) amonyaktan daha reaktif hale getiren daha güçlü nükleofiliklie sahiptir. Hidrazin, dibazik ve çok reaktif özelliklere sahiptir. Hidrazin, jet yaktlarnda bir bileen olarak kullanlr, çünkü yanarken çok miktarda s üretir. Hidrazin roket yakt olarak kullanlr. Hidrazin, korozyon hasarn önlemek için su kazan besleme ve stma sistemleri için bir oksijen süpürücüsü olarak kullanlr. Hidrazin, deerli metallerin geri kazanm için indirgeyici bir madde olarak kullanlr. Üretan kaplamalarda polimerizasyon katalizörü ve zincir uzatma maddesi olarak kullanlr. It ve türevleri çok yönlü ara ürünlerdir. Zirai kimyasallar, ilaçlar, fotografik, s dengeleyiciler, polimerizasyon katalizörleri, alev geciktiriciler, plastikler, patlayclar ve boyalar için üfleme ajanlar için organik sentezde aktif uygulamalar bulunmaktadr. Son zamanlarda, daha hzl ince film transistörleri yapmak için yakt olarak LCD’ye (sv kristal ekranlar) hidrazin uygulanmaktadr. Hidrazid bir asil hidrazindir. Asil (-CO), bir organik asitten (karboksil grubu) bir hidroksil grubunun çkarlmasyla oluan organik bir radikaldir. Adipoil hidrazid poliüretan dispersiyonu olarak kullanlr.


ÖZELLKLER
ADH, keton gruplaryla çok hzl tepki verir.
Örnein, diaseton akrilamid veya aldehid formaldehit gruplarnn keton gruplar ile kolayca reaksiyona girer.
Buna ek olarak, ADH ayn zamanda bir amino bileii gibi epoksi grubuyla reaksiyona girer. Adipik Asit Dihidrazid, yapkan ve kaplama üretim uygulamalarnda skça kullanlan kimyasal bir ara ürün ve özel kimyasaldr. Su bazl emülsiyonlar için mükemmel çapraz balayc bir madde haline getiren molekülün her iki ucunda amino ve keto ilevsellii sunar. Özel Kimyasallar, Kimyasal Aralar, Yaptrclar, Kaplamalar ve Szdrmazlk Maddeleri Kimyasallar, Ara ürünler, Çapraz Balayc Ajan, Endüstriyel, Reçine ve Kaplama, Özel Kimyasallar, Plastik. Aldehitler için spesifik olan homojen ilevsel çapraz balama reaktifi, nispeten kararl hidrazon balar oluturur. Bu, periyodat oksidasyonundan sonra, antikorlar gibi glikoproteinlerin siteye özgü bir biçimde balanmasnda skça kullanlr. Oksidasyon ve balanma, primer aminler tarafndan rekabeti önleyen, hidrazidin düük pKa’s nedeniyle, pH 5.0’de uygun bir ekilde gerçekletirilebilir. Hidrazon bann, örnein sodyum siyanoborohidrid kullanlarak seçici indirgeme ile stabilize edilebileceini unutmayn.


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UYGULAMALAR
Adipik asit dihidrazid, aldehitler için spesifik olan ve nispeten kararl hidrazon balar oluturan homobifonksiyonel çapraz balama reaktifi. Adipik asit dihidrazid, tipik olarak periyodat oksidasyonunu takiben, siteye özgü bir tarzda, antikorlar gibi glikoproteinlerin balanmasnda kullanlr. Oksidasyon ve balanma, primer aminler tarafndan rekabeti önleyen, hidrazidin düük pKa’s nedeniyle, pH 5.0’de uygun bir ekilde gerçekletirilebilir.

Oda scaklnda çapraz balanabilir su bazl kaplamalar.
Akrilik monomerler ve ADH amino gruplar ile diaseton akrilamid çapraz balar içeren akrilik emülsiyon çok hzldr. Kaplamann mükemmel su direnci vardr.

Formaldehit temizleyicisi. ADH, formaldehitle reaksiyona girer ve havadaki formaldehitin buharlamasn önler. Epoksi reçine sertletirici; ADH epoksi reçine ile yüksek scaklkta reaksiyona girer ve toz boya için faydaldr. Plastik ve elyaf ilemenin yenilenmesi.

ADH, dekoratif toz, yaltm tozu, yangn geciktirici toz, elektrik tozu, ar tozlarda yaygn olarak kullanlr. Özellikle yüksek kaliteli, ar hizmet tipi, yüksek scaklkta hzl kuruyan toz ve ya boru hatlar, havaclk, havaclk yaktlar ve dier alanlarn imalatnda, gerekli potansiyel kürleme ajan görevi görür. Ayn zamanda epoksi tozlarnda ve UPR ürünlerinde çok tatmin edici sonuçlarla güçlenmeye yönelik özelliklere sahiptir.

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