BENZYL CHLORIDE (BENZL KLORR)

Table of Contents

BENZYL CHLORIDE (BENZL KLORR)

BENZYL CHLORIDE(BENZL KLORÜR)

CAS NO: 100-44-7

METATAGS;
BENZYL CHLORIDE;(Chloromethyl)benzene;100-44-7;Benzylchloride;Chloromethylbenzene;alpha-Chlorotoluene;Benzylchlorid;Chlorophenylmethane;Benzene, (chloromethyl)-;Tolyl chloride;Chlorure de benzyle;a-Chlorotoluene;Benzene, chloromethyl-;alpha-Chlortoluol;RCRA waste number P028;NCI-C06360;CHLOROTOLUENE;Toluene, ar-chloro-;Benzile (cloruro di);Benzyle (chlorure de);Benzylchlorid [German];benzyl-chloride;Toluene, alpha-chloro-;alpha-Chlortoluol [German];NSC 8043;CCRIS 79;omega-Chlorotoluene;chloromethyl-benzene;Chlorure de benzyle [French];.alpha.-Chlortoluol;UNII-83H19HW7K6;HSDB 368;Oxsol 10;.alpha.-Chlorotoluene;.omega.-Chlorotoluene;Benzile (cloruro di) [Italian];Benzyle (chlorure de) [French];(Chloromethyl)-benzene;EINECS 202-853-6;UN1738;RCRA waste no. P028;Toluene, .alpha.-chloro-;AI3-15518;CHEBI:615597;KCXMKQUNVWSEMD-UHFFFAOYSA-N;EINECS 246-698-2;SBB040645;BRN 0471308;Benzyl chloride-(ring-13C6);benzyi chloride;alpha-chloro-toluene;Benzile(cloruro di);Phenylmethyl chlorid;1-chloromethylbenzene;Benzyle(chlorure de);(chloromethyl)-benzen;1-(chloromethyl)benzene;ACMC-1BSIO;AC1L1OWP;C6H5CH2Cl;DSSTox_CID_153;TOLUENE,ALPHA-CHLORO;AC1Q3U1S;AC1Q3U9J;SCHEMBL7413;WLN: G1R;akos bbs-00003953;DSSTox_RID_75405;DSSTox_GSID_20153;Benzyl chloride, unstabilized;METHYL, CHLOROPHENYL-;KSC163A7T;Benzene, (chloromethyl)- (VA;CHEMBL498878;Benzyl chloride, AR, >=99%;DTXSID0020153;NSC8043;MolPort-000-871-728;83H19HW7K6;NSC-8043;ZINC1586371;Tox21_200266;ANW-42399;LS-305;MFCD00000889;ZINC01586371;AKOS000118784;Benzyl chloride [UN1738] [Poison];MCULE-5056501597;RP19719;TRA0066090;UN 1738;Benzyl chloride [UN1738] [Poison];NCGC00090818-01;NCGC00090818-02;NCGC00257820-01;AJ-27548;AK110173;BC210975;CAS-100-44-7;CJ-05522;CJ-25238;OR000552;OR252253;OR252254;OR252255;OR259267;SC-19574;Benzyl chloride, 99%, stabilized 500g;Benzyl chloride, purum, >=99.0% (GC);DB-058434;KB-200535;LS-154029;RT-000110;B0412;Benzyl chloride, puriss., >=99.5% (GC);FT-0622815;ST24026336;ST50214092;C19167;29457-EP2272817A1;29457-EP2277878A1;29457-EP2284157A1;29457-EP2298746A1;29457-EP2305668A1;29457-EP2308875A1;29457-EP2311825A1;29457-EP2311842A2;29457-EP2371831A1;41092-EP2298734A2;41092-EP2305668A1;41092-EP2308873A1;41092-EP2311831A1;108795-EP2284166A1;108795-EP2298762A2;108795-EP2298769A1;4-05-00-00809 (Beilstein Handbook Reference);I01-4511;Q-200697;F2190-0251;Benzyl chloride, unstabilized [UN1738] [Poison, Corrosive];Benzyl chloride, unstabilized [UN1738] [Poison, Corrosive];InChI=1/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H;Benzyl chloride, ReagentPlus(R), 99%, contains <=1% propylene oxide as stabilizer;27987-13-9;9CL;alpha-chlorotoluene;benzyl chloride;benzyl chloride, 14C-labeled;Benzyl chloride;(Chloromethyl)benzene;Chlormethyl)benzol [German] [ACD/IUPAC Name];(Chloromethyl)benzene [ACD/IUPAC Name];(Chlorométhyl)benzène [French] [ACD/IUPAC Name];100-44-7 [RN];246-698-2 [EINECS];261-790-2 [EINECS];Benzene, (chloromethyl)- [ACD/Index Name];BENZENE, CHLOROMETHYL;Benzyl chloride [Wiki];Chloromethylbenzene [Wiki];toluene, ?-chloro-;CHLOROTOLUENE;(Chloromethyl)benzene; ?-Chlorotoluene;120-51-4 [RN];190-44-7;2,2-bis(4-methylphenyl)-1-cyclopropanecarboxylic acid;2,6-dichloro-5-fluoropyridine-3-carboxylic acid;33712-34-4 [RN];4-05-00-00809 (Beilstein Handbook Reference) [Beilstein];68661-11-0 [RN];82671-06-5 [RN];Benzile (cloruro di);Benzile (cloruro di) [Italian];Benzile(cloruro di);Benzyl benzoate [ACD/IUPAC Name] [Wiki];Benzyl chloride [UN1738] [Poison];BENZYL CHLORIDE-(RING-13C6);Benzyl chloride, unstabilized [UN1738] [Poison, Corrosive];Benzyl-2,3,4,5,6-d5 Chloride;Benzylchlorid;Benzylchlorid [German];benzylchloride [Wiki];benzyl-chloride;Benzyl-d7 Chloride;Benzyle (chlorure de);Benzyle (chlorure de) [French];Benzyle(chlorure de);Benzyl-?,?-d2 chloride;C6H5CH2Cl;Chlorophenylmethane;Chlorure de benzyle;Chlorure de benzyle [French];EINECS 202-853-6;EINECS 246-698-2;InChI=1/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H;Phenylmethyl Chloride;ST5214092;Toluene, ar-chloro-;Toluene, ?-chloro-;TOLUENE,?-CHLORO;UN 1738;UNII:83H19HW7K6;UNII-83H19HW7K6;WLN: G1R;XS8925000;Chlorotoluene;Chlorotoluene;Chlorotoluene (Benzylchloride);Chlortoluol;Chlortoluol;Chlortoluol [German];Chlorotoluene;Benzene, (chloromethyl)-; Toluene, ?-chloro-; ?-Chlorotoluene; ?-Chlorotoluene; (Chloromethyl)benzene; Chlorophenylmethane; C6H5CH2Cl; ?-Chlortoluol;Benzile (cloruro di); Benzylchlorid; Benzyle (chlorure de); Chlorure de benzyle; NCI-C06360; Rcra waste number P028; UN 1738; Phenylmethyl chloride; NSC 8043; Tolyl chloride;Benzene, (chloromethyl)-;Benzyl Chloride;(Chloromethyl)benzene;phenylmethyl chloride;Chlorotoluene;(chloro-deuterio-methyl)-benzene;deuterio-benzyl chloride;Deuterio-benzylchlorid;benzyl chloroacetylcarbamate;benzyl 2-chloroacetylcarbamate;Benzyl-chloracetylcarbamat;Benzylchlorid-7-14C;Benzylchlorid;Benzylchlorid-14C-7;Chlorotoluene;(Chloromethyl)benzene;(Chloromethyl)benzene (IUPAC Name); Alpha-chlorotoluene; (Chloromethyl)-benzene; Chloromethyl-benzene; Chloromethylbenzene; alpha-Chloro-toluene;Bzl-Cl;Benzile;Benzyle;NSC 8043;ai3-15518;C6H5CH2Cl;NCI-C06360;Benzylchlorid;tolylchloride;?-Chlortoluol;Choline chloride Diethylstilbestrol 4-Nitrobenzyl chloride 2-Bromobenzoyl chloride 3,5-Bis(trifluoromethyl)benzoyl chloride Benzoyl chloride BENZOYL-CARBONYL-13C CHLORIDE Benzyl chloride Benzyl Benzyl alcohol Phenylacetone Benzyltriethylammonium chloride Ammonium chloride Benzyl isocyanate Sodium chloride 4-Methylbenzyl chloride BENZAL CHLORIDE 4-(DICYANOMETHYLENE)-2-METHYL-6-(JULOLIDIN-4-YL-VINYL)-4H-PYRAN BENZYL CHLORIDE Building Blocks Aryl C7 100-44-7 A-CHLOROTOLUENE ALPHA-CHLOROTOLUENE AKOS BBS-00003953 Organic Building Blocks Protection and Derivatization Protecting and Derivatizing Reagents Others Synthetic Reagents Halogenated Hydrocarbons Reagents for Oligosaccharide Synthesis (chloromethyl)-benzen (Chloromethyl)benzene (chloromethyl)-Benzene 1-Chloromethylbenzene 1-Chlorome-thylbenzene ai3-15518 alpha-chloro-toluen alpha-Chlortoluol alpha-tolylchloride Benzene, (chloromethyl)- benzene,(chloromethyl)- benzene,chloromethyl- Benzile Benzile(cloruro di) benzile(clorurodi) Benzylchlorid benzylchloride(dot) benzylchloride00 Benzyle Benzyle(chlorure de) benzyle(chlorurede) benzyle(chlorurede)(french) C6H5CH2Cl chloromethylbenzene chloromethyl-benzene Chlorophenylmethane Chlorure de benzyle chloruredebenzyle chloruredebenzyle(french) NCI-C06360 omega-Chlorotoluene Phenylmethyl chloride Phenylmethylchloride Rcra waste number P028 rcrawastenumberp028 Toluene, alpha-chloro- Toluene,?-chloro- tolylchloride ?-Chlortoluol BENZYL HALIDE BENZYL CHLORIDE, REAGENTPLUS, 99% Bzl-Cl Benzyl chloride, pure, 90%;A-CHLOROTOLUENE;ALPHA-CHLOROTOLUENE;BENZENE,(CHLOROMETHYL)-;BENZYL CHLORIDE;(CHLOROMETHYL)BENZENE;CHLOROMETHYLBENZENE;CHLOROPHENYLMETHANE;NCI-C06360;NCI-CO6360;OMEGA-CHLOROTOLUENE;PHENYLMETHYL CHLORIDE;TOLUENE, ALPHA-CHLORO-;TOLYL CHLORIDE;alpha-Chlorotoluene; Benzylchloride anhydrous; Benzylchloride, stabilized;Chloromethyl benzene; chlorophenylmethane; ?-tolyl chloride;Chlorophenylmethane; a-chlorotoluene; DEA Code 8570; Benzene, (chloromethyl)-;Benzyl chloride; Benzene, (chloromethyl)-; Toluene, ?-chloro-; ?-Chlorotoluene; ?-Chlorotoluene; (Chloromethyl)benzene; Chlorophenylmethane; C6H5CH2Cl; a-Chlorotoluene; ?-Chlortoluol; Benzile(cloruro di); Benzylchlorid; Benzyle(chlorure de); Chlorure de benzyle; NCI-C06360; Benzile; Benzyle; Rcra waste number P028; Phenylmethyl chloride; a-Chlortoluol;omega-Chlorotoluene; Chlorophenylmethane; (chloromethyl)Benzene;alpha-Chlorotoluene; tolyl chloride ;Benzyl chloride; benzylchloride; benzil klorür; benzilklorür; chlorophenylmethane; chloro phenyl methane; klorofenilmetan; kloro fenil metan; klorofenil metan;Chlorotoluene; ?-klorotoluen; alfa klorotoluen; alfa kloro toluen; BnCl; chloromethylbenzene; chloro methyl benzene; klorometilbenzen; chloro methylbenzene; kloro metilbenzen;
chloro; methyl; benzene; kloro; metil; benzen;alpha-chlorotoluene;benzyl chloride;benzyl chloride, 14C-labeled;BENZYL CHLORIDE;(Chloromethyl)benzene;100-447;Benzylchloride;Chloromethylbenzene;alpha-Chlorotoluene;Benzene, (chloromethyl)-;Benzylchlorid;Tolyl chloride;Chlorophenylmethane;Chlorure de benzyle;CHLOROTOLUENE;Toluene, ar-chloro-;Benzene, chloromethyl-;benzyl-chloride;chloromethyl-benzene;.alpha.-Chlortoluol;Oxsol 10;.alpha.-Chlorotoluene;.omega.-Chlorotoluene;Benzile (cloruro di);Benzyle (chlorure de);Benzylchlorid [German];Toluene, alpha-chloro-;NSC 8043;RCRA waste no. P028;Toluene, .alpha.-chloro-;alpha-Chlortoluol [German];BENZL KLORÜR;BENZLKLORÜR;BENZIL KOLRUR;BENZILKLORUR;BENZYL CHLORIDE;BENZYLCHLORIDE;BENZYL CHLORDE;BENZYLCHLORDE;alpha-chlorotoluene; chlorophenylmethane; chloromethylbenzene;omega-Chlorotoluene; Chlorophenylmethane;(chloromethyl)-Benzene; ¥ø-Chlorotoluene; Chlorophenylmethane; Tolyl chloride; a-Chlorotoluene; Benzile(cloruro di); Benzylchlorid; Benzyle(chlorure de); Chlorure de benzyle; Phenylmethyl chloride

 

EC Number: 202-853-6

Benzyl chloride belongs to the family of Substituted Benzenes. These are aromatic compounds containing a benzene substituted at one or more positions.

Benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and pharmaceutical products and as a photographic developer. The acute (short-term) effects of benzyl chloride from inhalation exposure in humans consist of severe irritation of the upper respiratory tract, skin, eyes, and mucous membranes, and lung damage along with pulmonary edema (fluid in lungs). Exposure to high concentrations also causes effects on the central nervous system (CNS). Animal data indicate that long-term exposure to benzyl chloride by gavage (placing it experimentally in the stomachs of mice) increased the incidence of benign and malignant tumors at multiple sites and resulted in a significant increase in thyroid tumors in female rats. EPA has classified benzyl chloride as a Group B2, probable human carcinogen.

Names and Identifiers of Benzyl Chloride
Computed Descriptors of Benzyl Chloride

IUPAC Name of Benzyl Chloride
chloromethylbenzene

Molecular Formula of Benzyl Chloride
C7H7Cl

Experimental Properties of Benzyl Chloride

Physical Description of Benzyl Chloride
BENZYL CHLORIDE is a colorless liquid with an irritating odor. Toxic by inhalation and skin absorption. Flash point 153°F. Slightly soluble in water. Corrosive to metals and tissue. A lachrymator. Density 9.2 lb /gal.

Color of Benzyl Chloride
Colorless to slightly yellow liquid

Odor of Benzyl Chloride
Rather unpleasant, irritating odor

Boiling Point of Benzyl Chloride
354° F at 760 mm Hg

Melting Point of Benzyl Chloride
-54 to -45° F

Flash Point of Benzyl Chloride
153° F

Density of Benzyl Chloride
1.1 at 68° F


Benzyl chloride is an effective electrophile used in organic chemistry for introducing benzyl groups. Benzyl chloride can be used for the benzyl protection of amines and alcohols, however this is more commonly performed with benzyl bromide.

Benzyl chloride, or ?-chlorotoluene, is an organic compound with the formula C6H5CH2Cl. This colourless liquid is a reactive organochlorine compound that is a widely used chemical building block.

Uses
Benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and pharmaceutical, perfume and flavor products. It is also used as a photographic developer.Benzyl chloride can be used in the manufacture of synthetic tannins and as a gum inhibitor in petrol.Benzyl chloride has been used as an irritant gas in chemical warfare.

Hazard Summary
Benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and pharmaceutical products and as a photographic developer.  The acute (short-term) effects of benzyl chloride from inhalation exposure in humans consist of severe irritation of the upper respiratory tract, skin, eyes, and mucous membranes, and lung damage along with pulmonary edema (fluid in lungs).  Exposure to high concentrations also causes effects on the central nervous system (CNS).  Animal data indicate that longterm exposure to benzyl chloride by gavage (placing it experimentally in the stomachs of mice) increased the incidence of benign and malignant tumors at multiple sites and resulted in a significant increase in thyroid tumors in female rats.  EPA has classified benzyl chloride as a Group B2, probable human
carcinogen.

 

Chemical Properties of Benzyl Chloride
Colorless to yellow liquid

Uses of Benzyl Chloride
An intermediate in the preparation of phenylacetic acid (precursor to phamaceuticals). Also a precursor molecule to benzyl esters which are used as plasticizer, flavorants, and perfumes.

Definition of Benzyl Chloride
ChEBI: A member of the class of benzyl chlorides that is toluene substituted on the alpha-carbon with chlorine.

General Description of Benzyl Chloride
A colorless liquid with an irritating odor. Toxic by inhalation and skin absorption. Flash point 153°F. Slightly soluble in water. Corrosive to metals and tissue. A lachrymator. Density 9.2 lb /gal.


Description of Benzyl Chloride

Benzyl chloride is a colorless to slightly yellow liquid with a pungent, aromatic odor. It is soluble in alcohol, ether, and chloroform, and is insoluble in water. It is very refractive. Benzyl chloride is combustible and is corrosive to metal. It reacts with steam and oxidizing agents and is slowly hydrolyzed by water (HSDB, 1991). Benzyl chloride also rapidly decomposes when heated in the presence of iron


Benzyl chloride is an industrial intermediate chemical used in the production of a variety of materials. The primary purpose of benzyl chloride is to add benzyl functionality to different molecules to change their chemical properties. This is used in the production of plasticizers, sanitizing agents and oil extraction materials.

GENERAL DESCRIPTION AND APPLICATIONS of Benzyl Chloride

Toluene (methylbenzene) has a methyl group attached to a benzene ring. alpha-Chlorinated toluenes are organic compounds which one of the hydrogen atoms in the methyl group has been substituted by a chlorine atom instead of the substitution in the benzene ring . All three hydrogens in the methyl group can be replaced by chlorine atoms thtough the free radical chain reaction. These reactions are catalysed by light and sometimes called photochemical reaction. They reacts vigorously with strong oxidants and water to produce hydrogen chloride and attacks many metals except nickel and lead in the presence of water. Chloromethylated aromatic compounds are used as monomer for a copolymerization and as intermediate in organic synthesis for the introduction of the benzyl protecting group for alcohols and carboxylic acids such as benzaldehyde and cinnamic acid. Benzyl chloride, (monochloromethyl)benzene, is a clear to yellowish liquid; melts at -39 C; boils at 179 C. Its oxidation reaction produces benzaldehyde.Benzyl Chloride is widely used as an intermediate for manufacturing organic compounds including benzyl alcohol, benzyl cyanide and other benzyl compounds. It is used in fuel as a gum inhibitor. Benzal chloride, (dichloromethyl)benzene, is a clear to yellowish liquid; melts at -17 C; boils at 206 C. Its oxidation reaction with an alkali produces benzaldehyde. alpha-Chlorinated toluenes are used in the end applications of perfumery, dyes, pharmaceuticals, synthetic resins, photographic chemicals, warfare chemicals, penicillins, quaternary ammonium compounds, plasticizer and esters.


BENZOYL CHLORIDE, benzenecarbonyl chloride. Molecular weight: 140.57, boiling point: 197 ° C.

The colorless liquid with a sharp bacon is slightly soluble in water and slowly hydrolyzed. It is mixed with ether, benzene, carbonsulfur and oils. It is mainly used with alcohols, phenols and amines to introduce the benzoyl group. This reaction is called the Schotten-Baumann reaction. In addition, in the preparation of benzoyl peroxide, it is used in the synthesis of colorants, in the preparation of derivatives which enable them to be recognized in the analysis of organic compounds. Irritant effect on skin, eyes and mucous membranes.

CHEMICAL DANGERS of Benzyl Chloride
Very hot poisonous and corrosive gases containing phosgene, hydrogen chloride, on hot surfaces or flammable substances. This material is contacted with warming or alkaline, alcohol, amines and dimethylsulfoxide (see ICSC 0459), causing fire and explosion. It reacts violently with strong oxidants. It reacts with water or steam, forming heat, and corrosive fumes of hydrogen chloride (see ICSC 0163). Flammable when in contact with metal salts
Hydrogen gases (see ICSC 0001).

 

 

 

 

 

 

 

 

 

 

 

EC Numaras: 202-853-6

Benzil klorür, Sübstitüe Benzenlerin ailesine aittir. Bunlar, bir veya daha fazla konumda ikame edilmi benzen içeren aromatik bileiklerdir.

Benzil klorür, baz boyalarn ve farmasötik ürünlerin imalatnda kimyasal ara madde olarak ve fotorafik bir gelitirici olarak kullanlr. nklasyona maruz kalma olayndan kaynaklanan benzil klorürün akut (ksa süreli) etkileri, üst solunum yollarnn, deri, göz ve müköz membranlarda iddetli tahri ve akcier hasaryla birlikte akcier ödemi (akcierlerde sv) oluur. Yüksek konsantrasyonlara maruz kalma, merkezi sinir sistemi (CNS) üzerinde de etkilere neden olur. Hayvan verileri, gavaj yoluyla uzun süre benzil klorid’e maruz braklmasnn (farelerin midelerinde deneysel olarak yerletirilmesi), birden fazla bölgede benign ve malign tümörlerin görülme skln arttrdn ve dii sçanlarda tiroid tümörlerinde belirgin bir arta neden olduunu göstermektedir. EPA, benzil klorürü Grup B2, olas insan kanserojeni olarak snflandrmtr.

Benzyl Chloride isimleri ve tanmlayclar
Benzil Klorid Hesaplamal Tanmlayclar

Benzil Klorid’n IUPAC Ad
klorometilbenzen

Benzil Klorür Moleküler Formülü
C7H7Cl

Benzil Klorür Deneysel Özellikleri

Benzil Kloridin Fiziksel Tanm
BENZL KLORÜR rahatsz edici bir kokuya sahip, renksiz bir svdr. Teneffüs edilmesi ve cildi emmesi zehirlidir. Parlama noktas 153 ° F. Suda az çözünür. Metallere ve dokulara kar koroziftir. Çakmak tutucusu. Younluk 9,2 lb / gal.

Benzil Klorid Rengi
Renksiz ila hafif sar sv

Benzil Klor Koku
Oldukça rahatsz edici, tahri edici koku.

Benzil Klorid Kaynama Noktas
760 mm Hg’de 354 ° F

Benzil Klorid Erime Noktas
-54 ila -45 ° F

Benzil Klorid Parlama Noktas
153 ° F

Benzil Klorid Younluu
1,1 in 68 ° F

 

Benzil klorür, organik kimyada benzil gruplarnn katlmas için kullanlan etkili bir elektrofildir. Benzil klorür, aminlerin ve alkollerin benzil korumas için kullanlabilir, ancak bu daha sk benzil bromid ile yaplr.

Benzil klorür veya p-klorotoluen, C6H5CH2Cl formülüne sahip organik bir bileiktir. Bu renksiz sv, yaygn olarak kullanlan kimyasal yap ta olan reaktif bir organoklorin bileiidir.

Kullanmlar
Benzil klorür, baz boyalarn ve farmasötik, parfüm ve lezzet ürünlerinin imalatnda bir kimyasal ara madde olarak kullanlr. Ayrca fotorafik bir gelitirici olarak kullanlr. Benzil klorür, sentetik tanenlerin imalatnda ve petrolün sakz önleyicisi olarak kullanlabilir. Benzil klorür, kimyasal savata tahri edici bir gaz olarak kullanlmtr.

Tehlike Özeti
Benzil klorür, baz boyalarn ve farmasötik ürünlerin imalatnda kimyasal ara madde olarak ve fotorafik bir gelitirici olarak kullanlr. nklasyona maruz kalma olayndan kaynaklanan benzil klorürün akut (ksa süreli) etkileri, üst solunum yollarnn, deri, göz ve müköz membranlarda iddetli tahri ve akcier hasaryla birlikte akcier ödemi (akcierlerde sv) oluur. Yüksek konsantrasyonlara maruz kalma, merkezi sinir sistemi (CNS) üzerinde de etkilere neden olur. Hayvan verileri, gavaj yoluyla uzun süre maruz braklarak benzil klorid’e maruz brakldn (farelerin midelerinde deneysel olarak yerletirildiinde), benign ve malign tümörlerin birden fazla bölgede görülme skln artrdn ve dii sçanlarda tiroid tümörlerinde belirgin bir arta neden olduunu göstermektedir. EPA, benzil klorürü Grup B2, olas insan
kanserojen.

Benzil Klorürin Kimyasal Özellikleri
Renksiz ila sar sv

Benzil Kloridin Kullanm
Fenilasetik asit (phamaceuticals öncüsü) hazrlanmasnda bir ara madde. Ayrca, plastikletirici, lezzet verici maddeler ve parfümler olarak kullanlan benzil esterlere öncülük eden bir molekül.

Benzil Klorür Tanm
ChEBI: Alfa-karbon üzerinde klor ile sübstitüe edilmi toluen olan benzil klorid snfnn bir üyesidir.

Benzyl Chloride Genel Açklamas
Tahri edici bir kokuya sahip, renksiz bir sv. Teneffüs edilmesi ve cildi emmesi zehirlidir. Parlama noktas 153 ° F. Suda az çözünür. Metallere ve dokulara kar koroziftir. Çakmak tutucusu. Younluk 9,2 lb / gal.


Benzil Klorid’in tanm

Benzil klorür, keskin, aromatik bir kokuya sahip, renksiz ila hafif sar bir svdr. Alkol, eter ve kloroformda çözünür ve suda çözünmez. Çok refraktif. Benzil klorür yancdr ve metali andrcdr. Buhar ve oksitleyici ajanlar ile reaksiyona girer ve su ile yava yava hidrolize olur (HSDB, 1991). Benzil klorür ayrca demir varlnda stldnda hzla ayrr


Benzil klorür, çeitli materyallerin üretiminde kullanlan endüstriyel bir ara kimyasaldr. Benzil kloridin birincil amac, kimyasal özelliklerini deitirmek için farkl moleküllere benzil ilevsellii eklemektir. Bu plastikletiriciler, sanitizing ajanlar ve ya ekstraksiyon materyalleri üretiminde kullanlr.


Benzil Kloridin GENEL TANIMI VE UYGULAMALARI

Tolüen (metilbenzen), bir benzen halkasna bal bir metil grubuna sahiptir. Alfa-Klorlu toluenler, metil grubundaki hidrojen atomlarndan birinin benzen halkasnda ikame yerine bir klor atomu ile ikame edildii organik bileiklerdir. Metil grubundaki üç hidrojen de, serbest radikal zincir reaksiyonu ile klor atomlar ile deitirilebilir. Bu reaksiyonlar kla katalize edilir ve bazen fotokimyasal reaksiyon olarak adlandrlr. Hidrojen klorür üretmek için güçlü oksitleyiciler ve su ile kuvvetli tepki verirler ve su varlnda nikel ve kurun hariç birçok metali öldürürler. Klorometilletirilmi aromatik bileikler bir kopolimerizasyon için monomer olarak ve benzaldehit ve sinamik asit gibi alkoller ve karboksilik asitler için benzil koruma grubunun girii için organik sentezde ara madde olarak kullanlr. Benzil klorür (monoklorometil) benzen berrak ila sarmtrak bir svdr; -39 ° C’de erir; 179 ° C’de kaynar. Oksidasyon reaksiyonu benzaldehidi üretir. Benzil Klorid, benzil alkol, benzil siyanür ve dier benzil bileiklerini içeren organik bileiklerin imalat için bir ara madde olarak yaygn olarak kullanlr. Tutkal inhibitörü olarak yaktta kullanlr. Benzal klorür (diklorometil) benzen berrak ila sarmtrak bir svdr; -17 ° C’de erir; 206 ° C’de kaynar. Bir alkali ile oksidasyon reaksiyonu, benzaldehidi üretir. Parfümeri, boyalar, ilaçlar, sentetik reçineler, fotorafik kimyasallar, sava kimyasallar, penisilinler, kuaterner amonyum bileikleri, plastikletirici ve esterlerin son uygulamalarnda alfa-Klorlu toluenler kullanlr.


BENZOL KLORÜR, benzenkarbonil klorür. Molekül arl: 140.57, kaynama noktas: 197 ° C

Keskin bir domuz pastrmas olan renksiz sv, suda az çözünür ve yava yava hidrolize olur. Eter, benzen, karbonsülfür ve yalarla kartrlr. Genellikle alkoller, fenoller ve aminler ile benzoyl grubunu tantmak için kullanlr. Bu reaksiyona Schotten-Baumann reaksiyonu denir. Ek olarak, benzoil peroksitin hazrlanmasnda, organik bileiklerin analizinde tannmalarn salayan türevlerin hazrlanmasnda renk vericilerinin sentezinde kullanlr. Ciltte, gözlerde ve müköz zarlarda tahri edici etki.

Benzil Klorürün KMYASAL TEHLKELER
Scak zeminlerde veya yanc maddelerde fosgen, hidrojen klorür içeren çok scak zehirli ve andrc gazlar. Bu materyal, stma ya da alkalin, alkol, aminler ve dimetilsülfoksitle (ICSC 0459’a baknz) temas halinde olup, yangn ve patlamaya neden olur. Güçlü oksidanlarla iddetle tepki gösterir. Su veya buharla reaksiyona girerek s oluturur ve hidrojen kloritin andrc dumanlaryla reaksiyona girer (bkz. ICSC 0163). Metal tuzlarla temas ettiinde tutuabilir
Hidrojen gaz (bkz. ICSC 0001).

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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