BENZYL GLYCDYL ETHER (BENZL GLSDL ETER)
CAS NO:2930-05-4
EC NO:920-007-0
METATAGS:BENZYL GLYCIDYL ETHER; 2-(phenylmethoxymethyl)oxirane; (+); (Benzyloxymethyl)oxirane; (+)-Benzyl glycidyl ether; (R)-Benzyl glycidyl ether; (S)-Benzyl glycidyl ether; 2-[(Benzyloxy)methyl]oxiran [German] [ACD/IUPAC Name]; 2-[(Benzyloxy)methyl]oxirane [ACD/IUPAC Name]; 2-[(Benzyloxy)méthyl]oxirane [French] [ACD/IUPAC Name]; Oxirane, [(phenylmethoxy)methyl]-; Oxirane, 2-[(phenylmethoxy)methyl]- [ACD/Index Name]; ((Phenylmethoxy)methyl)oxirane; (-)-BENZYL (R)-GLYCIDYL ETHER; (Benzyloxymethyl)oxirane; (R)-(-)-;(Benzyloxymethyl)oxirane; (R)-(-)-Benzyl glycidyl ether; (r)-benzyloxymethyl-oxirane; (S)-(+)-Benzyl glycidyl ether; (S)-Benzyloxymethyl-oxirane; [2930-05-4]; 1-(Benzyloxy)-2,3-epoxypropane; 100643-27-4 [RN]; 14618-80-5 [RN]; 16495-13-9 [RN]; 2-((Benzyloxy)methyl)oxirane; 2-(Benzyloxymethyl)oxirane; 2-(phenylmethoxymethyl)oxirane; 2930-05-4 [RN]; 2930-05-4,; 2930-05-4;; 2-Benzyloxymethyl-oxirane; 766-36-9 [RN]; 89616-40-0 [RN]; Benzyl (R)-(-)-Glycidyl Ether; Benzyl (S)-(+)-Glycidyl Ether; Benzyl Glycidyl Ether; benzyl-glycidyl ether; BENZYLGLYCIDYLETHER; Epoxy Reactive Diluent; MFCD00068664 [MDL number]; oxiran-2-yl(phenylmethoxy)methane; Oxirane, ((phenylmethoxy)methyl)- (9CI); Oxirane,2-[(phenylmethoxy)methyl]-; Propane, 1-(benzyloxy)-2,3-epoxy-; Benzyl glycidyl ether; 2930-05-4; 2-((Benzyloxy)methyl)oxirane; 2-[(benzyloxy)methyl]oxirane; (Benzyloxymethyl)oxirane; Oxirane, [(phenylmethoxy)methyl]-; Propane, 1-(benzyloxy)-2,3-epoxy-; 1-(Benzyloxy)-2,3-epoxypropane; 2-Benzyloxymethyl-oxirane; 2-(Benzyloxymethyl)oxirane; ((Phenylmethoxy)methyl)oxirane; 89616-40-0; QNYBOILAKBSWFG-UHFFFAOYSA-N; EINECS 220-899-5; SBB060420; BRN 0115279; AK101061; OXIRANE,2-[(PHENYLMETHOXY)METHYL]-; Oxirane, ((phenylmethoxy)methyl)-; (R)-(-)-Benzylglycidylether; (S)-(+)-Benzylglycidylether; (-)-Benzyl (R)-glycidyl ether; benzyl-glycidylether; benzyloxymethyloxirane; benzyl-glycidyl ether; PubChem22384; 2-benzyloxymethyloxirane; ACMC-209cwl, ACMC-209drx; 5-17-03-00016 (Beilstein Handbook Reference); BENZYLGLYCIDYLETHER; AC1L3RTQ; ACMC-2097cc; 2,3-epoxypropyl benzyl ether; KSC492S2D; SCHEMBL153049; 2-(phenylmethoxymethyl)oxirane; 3-benzyloxy-1,2-epoxypropane; 1-Benzyloxy-2,3-epoxypropane; 469785_ALDRICH; [(phenylmethoxy)methyl]-oxirane; (S)-2-(benzyloxymethyl)oxirane; CTK3J2921; oxiran-2-yl(phenylmethoxy)methane; MolPort-000-255-134; (+/-)-2-(phenylmethoxymethyl)oxirane; (-)-(R)-2-[(benzyloxy)methyl]oxirane;; Oxirane, ((phenylmethoxy)methyl)- (9CI)
5-TMP,2Na;Z-DL-Gln-OH;azepan-3-one;PCy3 Pd G2 95%;RARECHEM AK HZ 0049;(r)-o-benzylglycidol;spiro[4.5]decylamine;(R)-(-)-Benzyl glyci;2’O-Me-rC(tac) CPG500;Graphene oxide sheets;benzyl glycdyl ether; benzyl, glycdyl, ether; benzil, glisidil, eter; benzil glisidil eter; phenylmethyloxirane; phenyl, methyl, oxirane; fenil, metil, oksiran; fenil metil oksiran.
General description
Benzyl glycidyl ether is a glycidyl derivative. Rac-/(R)-benzyl glycidyl ether participates in the synthesis of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s. Biocatalytic resolution of racemic benzyl glycidyl ether by Talaromyces flavus has been described. Resolution of benzyl glycidyl ether to (S)-benzyl glycidyl ether with 30% ee and (R)-3-benzyloxypropane-1,2-diol with 40% ee by whole Bacillus alcalophilus cells has been reported. It reacts with K-, K+(15-crown-5)2 to afford potassium glycidoxide and bibenzyl
R)-(-)-Benzyl glycidyl ether Property
Boiling point : 130 °C (0.1 mmHg)
alpha : -5.4 º (c=5 in toluene)
density : 1.077 g/mL at 25 °C(lit.)
refractive index : n20/D 1.517(lit.)
Fp : >230 °F
storage temp. :2-8°C
Storage : Store at 4° C
Incompatibilities & Reactivities
Strong oxidizers, amines, strong acids, strong bases
Exposure Routes
inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms
irritation eyes, skin; upper respiratory system; skin sensitization; narcosis; possible hematopoietic, reproductive effects; [potential occupational carcinogen]
Target Organs
Eyes, skin, central nervous system, hematopoietic system, reproductive system
Cancer Site
[in animals: nasal cancer]
Applications: [(Phenylmethoxy)methyl]oxirane, is a Glycidol (G615700) derivative. It is also shown that analougues of Phenyl Glycidyl Ether has in Vivo skin sensitizing potency, and is able to induce Nrf2-Dependent Luciferase Activity in the KeratinoSens.
Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Pictograms:
Signal Word: Warning
Hazard Statements: H302, H315, H319, H335
Precautionary Statements: P261, P305 + P351 + P338
Flash Point: 113°
RTECS: TX2860000
Risk Statements: 36/37/38
Safety Statements: 26-37/39
Genel açklama
Benzil glisidil eter, bir glisidil türevidir. Rac – / (R) -benzil glisidil eter, ataktik ve izotaktik dorusal poli (benzil 1,2-gliserol karbonat) sentezine katlr. Rasemik benzil glisidil eterin Talaromyces flavus tarafndan biyokatalitik olarak çözünmesi tarif edilmitir. Benzil glisidil eterin% 30 ee ile (S) -benzil glisidil etere ve% 40 ee ile (R) -3-benziloksipropan-1,2-diol’e tüm Bacillus alcalophilus hücreleri ile çözülmesi bildirilmitir. K-, K + (15-kron-5) 2 ile tepkimeye girerek potasyum glisidoksit ve bibenzil
R) – (-) – Benzil glisidil eter Mülkiyet
Kaynama noktas: 130 ° C (0.1 mmHg)
Alfa: -5.4 º (toluen içinde c = 5)
Younluk: 1.077 g / mL, 25 ° C’de (aydnlk)
Krlma indeksi: n20 / D 1.517 (lit.)
Fp:> 230 ° F
Saklama scakl : 2-8 ° C
Depolama: 4 ° C’de saklayn
Geçimsizlikler ve Reaktivite
Güçlü oksitleyiciler, aminler, güçlü asitler, güçlü bazlar
Pozlama Rotalar
Teneffüs etme, cilt emilimi, yutma, cilt ve / veya göz temas
Belirtiler
Tahri gözleri, cilt; Üst solunum sistemi; Cilt hassaslamas; narkoz; Olas hematopoietik, üreme etkileri; [Potansiyel mesleki kanserojen]
Hedef organlar
Gözler, cilt, merkezi sinir sistemi, hematopoietik sistem, üreme sistemi
Kanser Sitesi
[Hayvanlarda: burun kanseri]
Uygulamalar: [(Fenilmetoksi) metil] oksiran, bir Glisidol (G615700) türevidir. Fenil Glisidil Eter’in analojilerinin in vivo deri hassaslatrma potensine sahip olduu ve KeratinoSens’de Nrf2-Baml Lüsiferaz Aktivitesi indükleyebildii de gösterilmitir.
Madde veya karmn ilgili tespit edilen kullanmlar ve tavsiye edilmeyen kullanmlar Tanmlanan kullanmlar: Laboratuvar kimyasallar, Maddelerin imalat
YANGINLA MÜCADELE ÖNLEMLER
Ykc medya
uygun seçkin medya
Su spreyi, alkole dirençli köpük, kuru kimyasal veya karbon dioksit kullann.
Madde veya karmdan kaynaklanan özel tehlikeler
Karbon oksitler
tfaiye için tavsiyeler
Gerekirse yangn söndürme yönteminde kendi içinden nefes alan alet takn.
Piktogramlar:
Sinyal Kelime: Uyar
Tehlike Açklamalar: H302, H315, H319, H335
htiyati Beyanlar: P261, P305 + P351 + P338
Parlama noktas: 113 °
RTECS: TX2860000
Risk Tablolar: 36/37/38
Emniyet Beyannameleri: 26-37 / 39