DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
CAS NUMBER:15827-60-8
EC NUMBER:206-896-8
SYNONYMS:DTPMP; Diethylenetriamine-penta(methylene phosphonic acid); DTPMP; DTMPA; DETA-Phos; Dietilentriamin penta (metilen fosfonik asit) DETA-Phos Phosphonomethyl imino bis ethanediylnitrilobis metilen tetrakis-fosfonik asit; Diethylenetriamine Penta (Methylene Phosphonic Acid), DTPMP; DETPMP; DTPMPA; [[(phosphonomethyl)imino]bis[ethane-2,1-diylnitrilobis(methylene)]]tetrakisphosphonic acid; Diethylenetriaminepenta(methylene-phosphonic acid); Dequest 2060A; Dequest 2060S; Briquest 543-45AS; Diethylenetriaminepentakis(methylphosphonic acid) solution; DTPMP; DTMPA; DETA-Phos; [[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis- Phosphonic acid; Hepta sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid) (DTPMP•Na7); DTPMP•Na7; Hepta sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid) (DTPMP.Na7);DUYCTCQXNHFCSJ-UHFFFAOYSA-N; diethylenetriaminepenta(methylenephosphonic) acid;diethylenetriaminepenta(methylenephosphonic) acid, ammonium salt; diethylenetriaminepenta(methylenephosphonic) acid, calcium salt; diethylenetriaminepenta(methylenephosphonic) acid, calcium, octasodium (1:1:8) salt; diethylenetriaminepenta(methylenephosphonic) acid, calcium, sodium salt; diethylenetriaminepenta(methylenephosphonic) acid, dicalcium, hexasodium (1:2:6) salt; diethylenetriaminepenta(methylenephosphonic) acid, dicalcium, sodium (1:2:1) salt; diethylenetriaminepenta(methylenephosphonic) acid, sodium salt; diethylenetriaminepenta-(methylenephosphonic acid); DTPMP cpd; 15827-60-8; Diethylenetriaminepenta(methylene-phosphonic acid); Diethylenetriaminepenta(methylenephosphonic) acid; [bis[2; [bis(phosphonomethyl)amino]ethyl]amino]methylphosphonic acid; Phosphonic acid, [[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-; Diethylenetriaminepentakis(methylphosphonic acid) solution; 244775-22-2; 67774-91-8; UNII-0Q75589TM3; C9H28N3O15P5; Phosphonic acid, (((phosphonomethyl)imino)bis(2,1-ethanediylnitrilobis(methylene)))tetrakis-; Phosphonic acid, P,P’,P”,P”’-(((phosphonomethyl)imino)bis(2,1-ethanediylnitrilobis(methylene)))tetrakis-; Phosphonic acid, P,P’,P”,P”’-[[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-; EINECS 239-931-4; DETPMP; DTPMP; DTPMPA; dequest®2060; Dequest® 2060; AC1L38UF; SCHEMBL22924; Diethylenetriamine, pentamethylenepentaphosphonic acid; DTXSID0027775; MolPort-001-786-883; [(bis{2-[bis(phosphonomethyl)amino]ethyl}amino)methyl]phosphonic acid; MFCD00129718; ZINC59129438; AKOS025310980; 0Q75589TM3; (((Phosphonomethyl)imino)bis(ethane-2,1-diylnitrilobis(methylene)))tetrakisphosphonic acid; Phosphonic acid, [[(phosphonomethyl)imino] bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis -; AN-19197; OR076724; OR326034; P074; SC 47238; 70714-66-8 (unspecified ammonium salt); FT-0624891; ST24046570; 22042-96-2 (unspecified hydrochloride salt); diethylenetriamine pentamethylene phosphonic acid; diethylenetriamine pentamethylenephosphonic acid; 827D608; A809915; J-009490; Diethylenetriaminepenta(methylenephosphonic acid) solution; [BIS({2-[BIS(PHOSPHONOMETHYL)AMINO]ETHYL})AMINO]METHYLPHOSPHONIC ACID; Diethylenetriaminepentakis(methylphosphonic acid) solution 50% in 15% HCl: 35% H2O; Diethylenetriaminepentakis(methylphosphonic acid) solution, technical, ~50% (T); 291513-72-9; DTPMP heptasaodium salt; DTPMP Diethylenetriaminepenta (Methylene Phosphonic Acid); Ca-DTPMP; DETPMP; DTPF; DTPMP [Wiki]; DTPMPA; DTPPA; Dequest 2060A; Dequest® 2060; Diethylenetriamine-N,N,N’,N”,N”-pentakis(methylenephosphonic acid); Diethylenetriaminepenta(methylene-phosphonic acid); Diethylenetriaminepentakis(methylphosphonic acid); Diethylenetriaminepentakis(methylphosphonic acid) solution; EINECS:239-931-4; Phosphonic acid, (((phosphonomethyl)imino)bis(2,1-ethanediylnitrilobis(methylene)))tetrakis-; Phosphonic acid, [[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-; Phosphonicacid, [[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-(9CI); [(bis{2-[bis(phosphonomethyl)amino]ethyl}amino)methyl]phosphonic acid; [bis[2-[bis(phosphonomethyl)amino]ethyl]amino]methylphosphonic acid(IUPAC); dequest®2060; diethylenetriamine penta(methylene phosphonic acid); Diethylenetriaminepenta(methylenephosphonicacid) sodium salt; tpmp-na;DTPMPA.XNA;DEQUEST2066;PhosphonateSalt;Sodium Salt of DTPMP;SODIUM DIETHYLENETRIAMINE PENTAMETHYLENE PHOSPHONATE;diethylenetriaminepenta(methylenephosphonic acid)-sodium;(((PHOSPHONOMETHYL)IMINOBIS((2,1-ETHANEDIYLNITRILO)-BIS(ME.;(((PHOSPHONOMETHYL)IMINO)BIS((2,1-ETHANEDIYLNITRILO)-BIS(M.;Diethylenetriaminepenta(methylenephosphonicacid) sodium salt; DTPMP;DETPMP;DTPMPA;Diethylenetriaminepenta(methylene Phosphonic acid); KOR PD (DTPMP); Diethylenetriamine Penta (Methylene Phosphonic Acid), DTPMP; DETPMP; DTPMPA; [[(phosphonomethyl)imino]bis[ethane-2,1-diylnitrilobis(methylene)]]tetrakisphosphonic acid; Diethylenetriaminepenta(methylene-phosphonic acid; DTPMP % 47 ( DEQ.2060 muadili );Hepta sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid) (DTPMP?Na7)22042-96-2 (x-Na) 68155-78-2 (7-Na)C9H21O15N3P5Na7; Hepta sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid); Sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid); DTPMPoNax; sodium hydrogen [10,10-dihydroxy-10-oxido-2,5,8-tris(phosphonomethyl)-2,5,8-triaza-10lambda~5~-phosphadec-1-yl]phosphonate; icosasodium [(bis{2-[bis(diphosphonatomethyl)amino]ethyl}amino)(phosphonato)methyl]phosphonate (non-preferred name); Diethylenetriaminepenta(Methylenephosphonicacid) Sodium Salt; D ETLEN TR AMN PENTA METHYLENE FOSFONK AST; DI ETILEN TRI AMIN PENTA METHYLENE FOSFONIK ASIT; d etlen tr amn penta fosfonk ast; di etilen tri amin penta methylene fosfonik asit; di ; etilen ; tri; amin; penta ; fosfonik; acid; di ethylene tr amin penta phsophonic acid ; asid; di ethylene tri amin penta methylene fosfonik asit; d ethylene tr amn penta methylene fosfonk acd; di ethylene tri amin penta methylene phosphonic acid; tiri; tr; etlene ; ethylene ; etlen; amn; amin ; tri amin; tr amn; pentha; fosfonk; acd; asd; phosphonc acd; asid;
1. Use
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
This product is excellent corrosion – scale inhibitor for cyclic cooling water and boiler water. It is particularly suitable to be used in base cyclic cooling water as not-changing pH scale – corrosion inhibitor and can be used as scale – corrosion inhibitor in oilfield filling water, cooling water, boiler water which has high barium carbonate content. It also can be used as stablizer of germicide of chlorine dioxide. The scale deposition would be still very little even if using this product alone without adding dispersant.
2. Characteristic
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
This product is water-soluable. It has good effect of scale inhibiting to calcium sulfate, calcium carbonate and barium sulfate; especially to calcium carbonate even though in base solution (PH 10~11). It take on two unique performances:
(1). Although in base solution (PH10-11), it yet keep good effect of scale inhibiting to calcium carbonate which is 1~2 times higher than that of HEDP, ATMP.
(2). It has good effect of scale inhibiting to barium sulfate.
(3). It has better effect of corrosion inhibiting than HEDP, ATMP.
(4). It is stablizer of germicide of chlorine dioxide.
3. Specification
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Appearance Amber transparent liquid
Active content ?50.0%
Phosphorous acid (as PO33-) ?3.0%
PH (1% water solution 25?) ?2.0
Density (20?) 1.35 ~ 1.45 g/cm3
Calcium sequestration ?500 mg CaCO3/g
Chloride 12.0 ~ 17.0%
4. Usage
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Decided dose according water condition, generally it is 5~10mg/L.It shows a synergy effect when compound
with copolymer of poly carboxylic acids.
5. Package and Storage
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
250kg plastic drum or 1250kg IBC,to be stored in cool and ventilated room with a shelf time of one year.
APPLICATIONS
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Phosphonates derived from phosphorous (phosphonic) acid are employed in the applications of scale Inhibition, sequestration, dispersion and corrosion inhibition in addition to the main applications of agricultural chemicals such as fertilizers, pesticides, and soil conditioners. Phosphonates offer a wide range of sequestrants to control metal ions in aqueous systems. By forming stable water soluble complexes with multivalent metal ions, phosphonates prevent undesired interaction by blocking normal reactivity of metal ions. This ability contributes to function as threshold industrial water treatment and metal treatment processes (antiscalants, corrosion inhibitors, chelants, sludge conditioners, pulp bleachings, deflocculants, dispersants, metal cleaners, electroplating and crystal growth modifiers). Phosphonates are also used in manufacturing detergents, cosmetics and personal care products for special functions such as low levels iron control, stain removal, bleach stabilization, peroxide stabilization and anti-encrustation. Phosphonates existing in various compounds as acids or salts are marketed in the form of concentrated solutions.
GENERAL DESCRIPTION OF CHELATING AGENT
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Chelation is a chemical combination with a metal in complexes in which the metal is part of a ring. Organic ligand is called chelator or chelating agent, the chelate is a metal complex. The larger number of ring closures to a metal atom is the more stable the compound. This phenomenon is called the chelate effect; it is generally attributed to an increase in the thermodynamic quantity called entropy that accompanies chelation. The stability of a chelate is also related to the number of atoms in the chelate ring. Monodentate ligands which have one coordinating atom like H2O or NH3 are easily broken apart by other chemical processes, whereas polydentate chelators, donating multiple binds to metal ion, provide more stable complexes. Chlorophyll, green plant pigment, is a chelate that consists of a central magnesium atom joined with four complex chelating agent (pyrrole ring). The molecular structure of the chlorophyll is similar to that of the heme bound to proteins to form hemoglobin, except that the latter contains iron(II) ion in the center of the porphyrin. Heme is an iron chelate. Chelation is applied in metal complex chemistry, organic and inorganic chemistry, biochemistry, and environment protection. It is used in chemotherapeutic treatments for metal poisoning. Chelating agents offers a wide range of sequestrants to control metal ions in aqueous systems. By forming stable water soluble complexes with multivalent metal ions, chelating agents prevent undesired interaction by blocking normal reactivity of metal ions. EDTA, ethylenediaminetetraacetate (hexadentating), is a good example of common chelating agent which have nitrogen atoms and short chain carboxylic groups. The sodium salt of EDTA is used as an antidote for metal poisoning, an anticoagulant, and an ingredient in a variety of detergents. Chelating agents are important in the field of soap, detergents, textile dyeing, water softening, metal finishing and plating, pulp and paper, enzyme deactivation, photo chemistry, and bacteriocides.
1. Kullanm
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Bu ürün, siklik soutma suyu ve kazan suyu için mükemmel anma önleyici inhibitördür. Özellikle bazik siklik soutma suyunda, deimeyen pH ölçeinde korozyon önleyici olarak kullanlmak için uygundur ve ya sahas dolum suyu, soutma suyu, yüksek baryum karbonat içeriine sahip kazan suyu için ölçek – korozyon önleyicisi olarak kullanlabilir. Ayn zamanda, klor dioksit mikrop öldürücü dengeleyici olarak kullanlabilir. Bu ürünü datma maddesi eklemeden tek bana kullansanz bile, tortu birikimi çok az olacaktr.
2. Karakteristik
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Bu ürün suda çözünürdür. Kalsiyum sülfata, kalsiyum karbonata ve baryum sülfata engelleyici etki yaratr; özellikle baz çözeltisinde (PH 10 ~ 11) bile kalsiyum karbonata dönüür. ki benzersiz performans sergiliyor:
(1). Baz çözeltisinde (PH10-11) olmasna ramen, yine de, kalsiyum karbonatn, HEDP, ATMP’inkinden 1 ila 2 kat daha fazla inhibe edici etkisini iyi korur.
(2). Baryum sülfata engelleyici etki gösteren iyi bir etkiye sahiptir.
(3). Korozyon önleyici etkisi HEDP, ATMP’den daha iyidir.
(4). Klor dioksit mikrop öldürücüdür.
3. Teknik Özellikler
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Görünüm Amber effaf sv
Aktif içerik ?% 50
Fosfor asidi (PO33- olarak) ?% 3.0
PH (% 1 su çözeltisi 25 ?) ?2.0
Younluk (20 ° C) 1.35 ~ 1.45 g / cm3
Kalsiyum tutma ?500 mg CaCO3 / g
Klorid 12.0 ~ 17.0%
4. Kullanm
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Su artlarna göre doz belirlenir, genelde 5 ~ 10 mg / L’dir. Bileik olduunda sinerji etkisi gösterir
polikarboksilik asitler kopolimeri ile.
5. Paket ve Depolama
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
250kg plastik tambur veya 1250kg IBC, serin ve havalandrmal odada bir yl raf süresi ile saklanmaldr.
UYGULAMALAR
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
Fosforik (fosfonik) asitten türetilmi fosfonatlar, gübre, zirai ilaçlar ve toprak düzenleyicileri gibi zirai kimyasallarn ana uygulamalarna ek olarak ölçek uygulamas, inhibisyon, saklama, dalm ve korozyon inhibisyonu için kullanlr. Fosfonatlar, sulu sistemlerdeki metal iyonlarn kontrol etmek için çok çeitli kenetleme maddeleri sunmaktadr. Çok deerlikli metal iyonlaryla kararl suda çözünür kompleksler oluturarak fosfonatlar, metal iyonlarnn normal reaktivitesini bloke ederek istenmeyen etkileimi önler. Bu özellik, eik endüstriyel su artm ve metal ileme prosesleri (antiscalantlar, korozyon önleyiciler, çelatçlar, çamur kvamlandrclar, kat hamuru aartma maddeleri, çözülme maddeleri, dispersanlar, metal temizleyiciler, elektrokaplama ve kristal büyüme düzenleyicileri) ilevine katkda bulunur. Fosfonatlar, düük seviyeli demir kontrolü, leke çkarma, aartma stabilizasyonu, peroksit stabilizasyonu ve anti-enkstasyon gibi özel ilevler için deterjanlar, kozmetik ürünleri ve kiisel bakm ürünleri imalatnda da kullanlr. Çeitli bileiklerde asit veya tuz olarak bulunan fosfonatlar konsantre çözeltiler eklinde pazarlanmaktadr.
KLAT ETMENN GENEL TARF
DTPMP (Diethylene Triamine Penta Methylene Phosphonic Acid) (Di Etilen Triamin Penta Metilen Fosfonik Asit);
elasyon, metalin bir halkann parças olduu komplekslerdeki metal ile kimyasal bir kombinasyondur. Organik ligandlara kenetleyici veya kenetleme maddesi denir, kenetleme bir metal kompleksidir. Bir metal atomuna daha çok sayda halka kapanmas, bileimin kararlldr. Bu fenomene elat etkisi denir; genel olarak elasyona elik eden entropi ad verilen termodinamik miktarn artmasna atf yaplr. Bir elatn stabilitesi ayrca elat halkasndaki atomlarn saysyla da ilikilidir. H2O veya NH3 gibi bir koordinat atomuna sahip monodentat ligandlar, dier kimyasal ilemlerle kolaylkla parçalanr, oysa çoklu metal iyonuna balanan polidentat kenetleme maddeleri daha kararl kompleksler salar. Klorofil, yeil bitki pigmenti, dört kompleks kenetleme maddesi (pirol halkas) ile birletirilmi merkezi bir magnezyum atomundan oluan bir elattr. Klorofilin moleküler yaps, hemoglobin oluturmak için proteinlere balanan heme’nin moleküler yaps ile benzerdir, ancak sonuncusu porfirinin merkezinde demir (II) iyonu içermektedir. Heme bir demir elatidir. elasyon, metal kompleks kimyasnda, organik ve inorganik kimyada, biyokimyada ve çevre korumasnda uygulanr. Metal zehirlenmesi için kemoterapötik tedavilerde kullanlr. elat ajanlar, sulu sistemlerdeki metal iyonlarn kontrol etmek için çok çeitli kenetleme maddeleri sunmaktadr. Çok deerlikli metal iyonlaryla kararl suda çözünür kompleksler oluturarak, kenetleme maddeleri, metal iyonlarnn normal reaktivitesini bloke ederek istenmeyen etkileimi önler. EDTA, etilendiamintetraasetat (altadantlandrc), azot atomlar ve ksa zincirli karboksil gruplarna sahip yaygn elatlama maddesinin iyi bir örneidir. EDTA’nn sodyum tuzu metal zehirlenmesinin antidotu, antikoagülan ve çeitli deterjanlardaki bir bileen olarak kullanlr. elat ajanlar, sabun, deterjanlar, tekstil boyama, su yumuatma, metal kaplama ve kaplama, kat hamuru ve kat, enzim devre d brakma, fotoraf kimyas ve bakterisitler alannda önemlidir.