ETHOXYLATED ISOTRIDECANOL

ETHOXYLATED ISOTRIDECANOL

ISOTRIDECANOL ETHOXYLATES

CAS Number: 9043-30-5

Chemical family: Alcohol ethoxylates

ETHOXYLATED ISOTRIDECANOL is used as surfactant raw materials in detergents and cleaning products and as auxiliaries in textile production, metalworking, emulsifier technology, and chemical-industrial applications.

ETHOXYLATED ISOTRIDECANOL is a wetting agent, emulsifier, and dispersing agent e.g., in detergents, industrial & institutional cleaners, in emulsion polymerization or wax and silicon emulsions

ETHOXYLATED ISOTRIDECANOL is used in the following products: washing and cleaning products, fillers, putties, plasters, modeling clay, lubricants and greases, coating products, metal surface treatment products, textile treatment products and dyes, pH regulators and water treatment products, and polymers.

The alkylpolyglycol ether series of the isotridecanol are formed by the reaction of isotridecanol with varying amounts of ethylene oxide.

Synonym(s): Isotridecanol ethoxylate, Isotridecyl alcohol polyglycol ether (n EO), PEG isotridecyl ether, Polyethylene glycol monoisotridecyl ether, Polyoxyethylene (n) Isotridecyl Ether, Isotridecanol polyethylene glycol ether, Isotridecyl alcohol ethoxylate, iso-tridecyl alcohol polyglycol ether, Fatty alcohol ethoxylate, Polyoxyethylene (n) isotridecanol,  Alcohols, C13, branched, ethoxylated, alkylpolyethylene glycol ether, C13-oxo alcohol (isotridecanol) Ethoxylate, C13 alcohol ethoxylate, Isotridecyl polyethylene glycol ether with n moles ethylene oxide

n is the number of EO Units in the product.

n can be any number, and a number of EO Units (n) can be chosen depending on the application.

The individual grades of the Isotridecanol ethoxylate series differ in the number of adducted moles of ethylene oxide and cover a broad spectrum of beneficial properties in a wide range of applications.

The individual grades differ in the number n of added moles of ethylene oxide and, accordingly, in the length of the polyethylene glycol ether chain. 

The letter n denotes the average degree of ethoxylation since a range of ethoxylation stages is produced during the preparation. 

The Isotridecanol Ethoxylate grades are, thus, like all alcohol ethoxylates, mixtures of homologous alkyl polyethylene glycol ethers.

Isotridecanol + 1 mol EO/mol = C13 Alcohol 1 EO = Isotridecyl Alcohol 1 EO = Polyoxyethylene (1) Isotridecyl Ether

Isotridecanol + 2 mol EO/mol = C13 Alcohol 2 EO = Isotridecyl Alcohol 2 EO = Polyoxyethylene (2) Isotridecyl Ether

Isotridecanol + 3 mol EO/mol ……

Isotridecanol + 4 mol EO/mol …..

Isotridecanol + 5 mol EO/mol ….

Isotridecanol + 6 mol EO/mol …

Isotridecanol + 7 mol EO/mol ..

Isotridecanol + 8 mol EO/mol .

Isotridecanol + 9 mol EO/mol

Isotridecanol + 10 mol EO/mol

Isotridecanol + 12 mol EO/mol

Isotridecanol + 15 mol EO/mol

Isotridecanol + 20 mol EO/mol

Isotridecanol + 28 mol EO/mol

Isotridecanol + 30 mol EO/mol

Isotridecanol + 40 mol EO/mol

Some Examples:

Isotridecanol Ethoxylate 6EO is the ethoxylated alcohol that conforms to the formula RO(CH2CH2O)nH, where n = the number of moles of ethylene oxide (EO), which has an average value of 6, and R = the hydrocarbon chain of isotridecyl alcohol.

Technical Names:

Isotridecanol + 6 mol EO/mol

.alpha.-Isotridecyl-.omega.-Hydroxy-Poly(Oxy-1,2-Ethanediyl)

Isotridecanol Ethoxylated

Isotridecyl Alcohol 6EO

Polyethylene Glycol (6) Isotridecyl Ether

Polyoxyethylene (6) Isotridecyl Ether

Isotridecanol Ethoxylate 8 EO is the ethoxylated alcohol that conforms to the formula RO(CH2CH2O)nH, where n = the number of moles of ethylene oxide (EO), which has an average value of 8, and R = the hydrocarbon chain of isotridecyl alcohol.

Technical Names:

Isotridecanol + 8 mol EO/mol

.alpha.-Isotridecyl-.omega.-Hydroxy-Poly(Oxy-1,2-Ethanediyl)

Isotridecanol Ethoxylated

Isotridecyl Alcohol 8EO

Polyethylene Glycol (8) Isotridecyl Ether

Polyoxyethylene (8) Isotridecyl Ether

Solubility

*The solubility of Isotridecanol Ethoxylates in water increases with increasing degree of ethoxylation.

The lower ethoxylates (3-6 mol EO), in which the alkyl group predominates as the hydrophobic component, are only sparingly soluble in water. 

However, they dissolve in nonpolar organic solvents and are used, for example, as w/o-emulsifiers. 

In contrast, the higher ethoxylates are readily soluble in water.

Cloud Point

The cloud point is an important parameter for characterizing nonionic surfactants and is determined by a simple test method. 

The phenomenon of the cloud point can be explained as follows: the solubility of ethoxylates in water is based on the hydration of the oxygen group via hydrogen bonds.

Since this hydration decreases with increasing temperature, the solubility of the surfactants in water decreases accordingly.

At a specific temperature, the initially clear solution of an ethoxylate immediately becomes cloudy because a water-immiscible surfactant phase is formed. This process is reversible; i.e., the solution clarifies at the same temperature upon cooling. 

The temperature at which this clouding occurs is specific for each ethoxylate and is referred to as the surfactant’s cloud point.

The cloud point is a function of concentration and is usually determined in 1% or 2% aqueous surfactant solutions. 

If the ethoxylate is insoluble or only sparingly soluble in water, the cloud point can also be determined in aqueous butyldiglycol solution. 

For ethoxylates, whose aqueous solutions do not turn cloudy even at the boiling point of water, a cloud point can be determined by adding sodium chloride. The addition of electrolytes lowers the cloud point of the ethoxylates.

Foaming

The foaming capacity of Isotridecanol Ethoxylates varies from moderate to slight according to the degree of ethoxylation.

Isotridecanol + 1 mol EO/mol has the slightest tendency to foam. 

The foaming capacity slightly increases with increasing EO content but does not equal that of anionic surface-active compounds.

Wetting effect

The wetting effect increases with the degree of ethoxylation to attain an optimum in readily water-soluble Isotridecanol + 8 mol EO/mol. 

The wetting capacity of Isotridecanol + 8 mol EO/mol is particularly marked in the low-temperature range.

Surface tension

The ability to lower the surface tension of water is also related to the degree of ethoxylation.

The most effective grades are Isotridecanol + 6 mol EO/mol and Isotridecanol + 8 mol EO/mol. 

The effect on the surface tension of water decreases as the degree of ethoxylation increases.

Cleaning properties

Isotridecanol Ethoxylates are noted for their excellent cleaning properties.

Whereas Isotridecanol + 6 EO has a decisive degreasing action and is preferred when grease-bound contamination is to be removed, Isotridecanol + 8 EO is mainly used to remove pigmented contamination.

Owing to their excellent surface-active properties, isotridecanol ethoxylates have numerous uses. 

Having excellent wetting action, especially in the low-temperature range, and marked degreasing and emulsifying properties, they are suitable raw materials and mixture components for manufacturing universal cleaners in every form.

Final product applications:

Additives

Adhesives

Agricultural chemicals

Auxiliaries for Textile and Leather Processing

Coatings

Detergents and cleaners

Detergents for household purposes

Emulsifier in Metalworking Fluids

Flavors and fragrances

Industrial and institutional cleaning

Industrial applications

Inks

Leather processing

Lubricants

Metalworking and fuel additives

Oil and gas

Paints

Paper chemicals

Personal care

Plastic and rubber additives

Silicone Emulsions for Technical Applications

Specialty

Textile

Water-based Defoamer Emulsions

Water treatment

Function: Dispersing Agent

Application: Emulsion Polymerisation

ETHOXYLATED ISOTRIDECANOL acts as a dispersant. The surface-active, hydrophobic part of the surfactant anchors on the polymer particles, and the hydrophilic chain of ethylene oxide groups acts as a steric stabilization, thereby preventing the agglomeration of the polymeric particles.

Function: Surfactant, Emulsifier, and Foaming agent.

Application: Textile and Plastic Additives

ETHOXYLATED ISOTRIDECANOL is a biodegradable, nonionic surfactant, emulsifier, and foaming agent. 

ETHOXYLATED ISOTRIDECANOL is derived from branched C13 alcohol and ethoxylated to an average of n moles of ethylene oxide. 

Function: Cleaning Agent, Emulsifier

Application: Cosmetics, Detergents, and Lubricants

agents for removing oil stains resulting from weaving processes.

dishwashing liquids,

cleaning hard surfaces,

liquid detergents and softeners,

products for commercial washing,

cleaning kitchen soiling,

institutional cleaning products,

hair care,

products for bleaching cotton,

removing dye from a dyebath,

soaps

ETHOXYLATED ISOTRIDECANOL is a cleaning agent or “surfactant” used in detergents, cosmetics, metal processing, and lubricants. 

Our customers use it in their products to remove dirt and deposits. ETHOXYLATED ISOTRIDECANOL surrounds dirt particles to loosen them from the surface they’re attached to so they can be rinsed away.

Examples are household cleaning and washing agents and specialist preparations for cleaning various hard surfaces, particularly degreasing compositions with high alkalinity or acidity. 

Such products include pre-washing agents and alkaline active foams for washing vehicles, graffiti removers, and high-acid detergents for removing bathroom sediments.

ETHOXYLATED ISOTRIDECANOL is a water-soluble emulsifier used in personal care products. It is applicable to all kinds of liquid personal cleansing products.

Function: Adjuvant, Spray retention aid, O/W emulsifier, Wetting agent

Application: Crop Protection

Emulsifiable concentrate

Suspension concentrate

Suspo emulsion

Emulsion in water

ETHOXYLATED ISOTRIDECANOL is an effective nonionic wetting agent in agriculture formulations, including pesticides, herbicides, and insecticides.

ETHOXYLATED ISOTRIDECANOL combines low-foam emulsification and wetting properties, which make them the first choice for many NPE-free formulations as an emulsifier, wetting agent, and adjuvant.

Function: Emulsifier, Dispersant

Application: Textile Industry and PDMS /Silicone Emulsions

ETHOXYLATED ISOTRIDECANOL is used to formulate scouring, wetting, degreasing, or dying auxiliaries as well as lubricants or bleaches.

In the leather industry, it is used in soaking and defatting agents.

Isotridecanol Ethoxylates have good emulsifying properties for various oils and solvents. 

In applications where poly dimethyl siloxanes, e.g., are used, Isotridecanol, Ethoxylated, yields fine dispersed water-based emulsions. 

ETHOXYLATED ISOTRIDECANOL advantages:

excellent emulsifier and dispersant,

good wetting agent,

excellent detergency properties,

hydrophilic properties,

stable under oxidizing, reducing, and hard water conditions,

compatible with non-ionic, anionic, and cationic components of the formulation,

shows stability in acidic and alkaline formulations,

improves the capillarity of the dye after the bleaching process has been carried out,

removes oil stains from hard surfaces as well as from knit and woven fabrics,

easily biodegradable,

approved for use as an indirect food additive.

Branched tridecylalcohol, ethoxylated

Isotridecanol, ethoxylated

Poly(oxy-1,2-ethanediyl), alpha-tridecyl-omega-hydroxy-, branched

Polyethylene glycol mono(branched tridecyl) ether

IUPAC names

Alcohol C13, branched, ethoxylated

C13 Alcohol ethoxylate

C13-OXO ALCOHOL ETHOXYLATE

ETHOXYLATED ISOTRIDECANOL

Ethoxylated isotridecyl alcohol

Isotridecanol ethoxylated

ISOTRIDECANOL, ETHOXYLATED

Isotridecanol, ethoxylated

isotridecanol, ethoxylated

Isotridecanol, ethoxylated

Isotridecanol, ethoxylated (3-5 EO)

Isotridecanol, ethoxylated, < 2.5 EO

Isotridecanole ethoxylate

Isotridecanolethoxylate

ITD 030, ITD 050, ITD 060, ITD 070, ITD078, ITD 080 , ITD 090, ITD100, ITD120

Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-, branched

Poly(oxy-1,2-ethanediyl), a-tridecyl-w-hydroxy-, branched

Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy-,

poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy-, branched

Poly(oxy-1,2-ethanediyl),.alpha.-tridecyl-.omega.-hydroxy-,branched

Poly(oxy-1,2-ethanediyl),alpha-tridecyl-omega-hydroxy branched

Polyethylene glycol mono(branched tridecyl) ether

Tridecanol, branched, ethoxylated

Tridecanolethoxylat

Tridecanolethoxylate, branched

Trideceth-n

α-Tridecyl-ω-hydroxypoly(oxy-1,2-diyl), verzweigt