HEKZAHDROFTALK ANHDRT (HEXAHYDROPHTHALIC ANHYDRIDE)

HEXAHYDROPHTHALIC ANHYDRIDE (HEKZAHDROFTALK ANHDRT)

CAS No. : 85-42-7

EC No. : 201-604-9

Synonyms:

Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ; 85-42-7 ; Hexahydroisobenzofuran-1,3-dione ; HHPA ;1,2-Cyclohexanedicarboxylic anhydride ; 1,3-Isobenzofurandione, hexahydro- ; Lekutherm Hardener H ; Hexahydrophthalic anhydride acid anhydride ; Cyclohexane-1,2-dicarboxylic anhydride ; Araldite HT 907 ; 1,2-Cyclohexanedicarboxylic acid anhydride ; NT 907 ; octahydro-2-benzofuran-1,3-dione ; Hexahydro-2-benzofuran-1,3-dione ; NSC 8622 ; Hexahydrophthalic anhydride, HHPA ; CHEBI:103210 ; EINECS 201-604-9 ; 14166-21-3 ; Cyclohexane-1,2-dicarboxylic acid anhydride ; hexahydro-1,3-isobenzofurandione ; trans-Hexahydroisobenzofuran-1,3-dione ; 1,2-Cyclohexane dicarboxylic anhydride ; 3a,4,5,6,7,7a-hexahydroisobenzofuran-1,3-dione ; 3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione ; trans-Cyclohexane-1,2-dicarboxylic anhydride ; (+)-trans-1,2-Cyclohexanedicarboxylic Anhydride ; Hexahydrophthalic anhydride(HHPA);Hexahydroisobenzofuran-1,3-dione ; 1,3-Isobenzofurandione, hexahydro-, trans- ; HSDB 7912 ; EINECS 238-009-9 ; (3aR,7AS)-hexahydroisobenzofuran-1,3-dione ; ACMC-209bly ; ACMC-209cml ; hexahydrophtalic anhydride ; DSSTox_CID_6515 ; Epitope ID:122664 ; EC 201-604-9 ; DSSTox_RID_78131 ; DSSTox_GSID_26515 ; SCHEMBL15324 ; KSC448E8F ; CHEMBL273968 ; DTXSID8026515 ; NSC8622 ; KS-000011GL ; NSC-8622 ; Tox21_200661 ; BBL011768 ; MFCD00064863 ; SBB058760 ; STK387488 ; Hexahydro-2-benzofuran-1,3-dione # ; 2,4,5,6-tetrahydrophthalic anhydride ; Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ; AKOS000119684 ; AKOS016352936 ; DS-4586 ; MCULE-6093566981 ; NE49491 ; CAS-85-42-7 ; NCGC00248785-01 ; NCGC00258215-01 ; AC-19638 ; K526 ; SC-46774 ; DB-042035 ; DB-042579 ; DB-056869 ; LS-183520 ; C1417 ; C1657 ; FT-0623877 ; FT-0627011 ; FT-0637021 ; FT-0657907 ; FT-0659322 ; NS00005320 ; ST50902927 ; rel-(3aR,7aR)-Hexahydroisobenzofuran-1,3-dione ; 4,5,6,7,3a,7a-hexahydroisobenzofuran-1,3-dione ; A807788 ; A841328 ; J-501171 ; J-521450 ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; Q26840977 ; F0001-0429 ; (7aS,3aR)-4,5,6,7,3a,7a-hexahydroisobenzofuran-1,3-dione ; trans-cyclohexane-1,2-dicarboxylic anhydride;1,3-Isobenzofurandione, hexahydro-, polymer with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol and 1,3-isobenzofurandione;cyclohexane-1,2-dicarboxylic anhydride;Cyclohexane-1,2-dicarboxylic anhydride;1,3-Isobenzofurandione, hexahydro-;Hexahydrophthalic anhydride ; Hexahydrophthalic anhydride ; 85-42-7 ; Hexahydroisobenzofuran-1,3-dione ; HHPA ;1,2-Cyclohexanedicarboxylic anhydride ; 1,3-Isobenzofurandione, hexahydro- ; Lekutherm Hardener H ; Hexahydrophthalic anhydride acid anhydride ; Cyclohexane-1,2-dicarboxylic anhydride ; Araldite HT 907 ; 1,2-Cyclohexanedicarboxylic acid anhydride ; NT 907 ; octahydro-2-benzofuran-1,3-dione ; Hexahydro-2-benzofuran-1,3-dione ; NSC 8622 ; Hexahydrophthalic anhydride, HHPA ; CHEBI:103210 ; EINECS 201-604-9 ; 14166-21-3 ; Cyclohexane-1,2-dicarboxylic acid anhydride ; hexahydro-1,3-isobenzofurandione ; trans-Hexahydroisobenzofuran-1,3-dione ; 1,2-Cyclohexane dicarboxylic anhydride ; 3a,4,5,6,7,7a-hexahydroisobenzofuran-1,3-dione ; 3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione ; trans-Cyclohexane-1,2-dicarboxylic anhydride ; (+)-trans-1,2-Cyclohexanedicarboxylic Anhydride ; Hexahydrophthalic anhydride(HHPA);Hexahydroisobenzofuran-1,3-dione ; 1,3-Isobenzofurandione, hexahydro-, trans- ; HSDB 7912 ; EINECS 238-009-9 ; (3aR,7AS)-hexahydroisobenzofuran-1,3-dione ; ACMC-209bly ; ACMC-209cml ; hexahydrophtalic anhydride ; DSSTox_CID_6515 ; Epitope ID:122664 ; EC 201-604-9 ; DSSTox_RID_78131 ; DSSTox_GSID_26515 ; SCHEMBL15324 ; KSC448E8F ; CHEMBL273968 ; DTXSID8026515 ; NSC8622 ; KS-000011GL ; NSC-8622 ; Tox21_200661 ; BBL011768 ; MFCD00064863 ; SBB058760 ; STK387488 ; Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ; Hexahydro-2-benzofuran-1,3-dione # ; 2,4,5,6-tetrahydrophthalic anhydride ; AKOS000119684 ; AKOS016352936 ; DS-4586 ; MCULE-6093566981 ; NE49491 ; CAS-85-42-7 ; NCGC00248785-01 ; NCGC00258215-01 ; AC-19638 ; K526 ; SC-46774 ; DB-042035 ; DB-042579 ; DB-056869 ; LS-183520 ; C1417 ; C1657 ; Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ; FT-0623877 ; FT-0627011 ; FT-0637021 ; FT-0657907 ; FT-0659322 ; NS00005320 ; ST50902927 ; rel-(3aR,7aR)-Hexahydroisobenzofuran-1,3-dione ; 4,5,6,7,3a,7a-hexahydroisobenzofuran-1,3-dione ; Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ; A807788 ; A841328 ; J-501171 ; J-521450 ; Q26840977 ; F0001-0429 ; (7aS,3aR)-4,5,6,7,3a,7a-hexahydroisobenzofuran-1,3-dione ; trans-cyclohexane-1,2-dicarboxylic anhydride;1,3-Isobenzofurandione, hexahydro-, polymer with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol and 1,3-isobenzofurandione;cyclohexane-1,2-dicarboxylic anhydride;Cyclohexane-1,2-dicarboxylic anhydride;1,3-Isobenzofurandione, hexahydro-;Hexahydrophthalic anhydride ; Hexahydrophthalic anhydride ; HEKZAHDROFTALK ANHDRT ; hekzahidroftalik anhidrit ; Hekzahidroftalik Anhidrit ; HEXAHYDROPHTHALC ANHYDRDE ;

hexahydrophthalic anhydride

Cyclohexane-1,2-dicarboxylic acid anhydride , also called hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) , is a chemical compound from the group of cyclic carboxylic acid anhydrides . There are two carboxylic acid groups in the ortho position on a cyclohexane ring , which together form an anhydride .

Extraction and representation

Cyclohexane-1,2-dicarboxylic acid anhydride is produced by the nuclear hydrogenation of phthalic anhydride . [4] This additional process step is one reason for the higher price compared to the aromatic phthalic anhydride.

Manufacture of HH-PSA

Usage

Cyclohexane-1,2-dicarboxylic acid anhydride is used as a monomer in various areas of polymer chemistry . So is z. B. to mention the application as an alternative to phthalic anhydride(Hekzahidroftalik anhidrit ) . What is desired here is better weather resistance, especially against UV light , with high hardness at the same time, which can be achieved by using hexahydrophthalic anhydride(Hekzahidroftalik anhidrit ). [5] Furthermore, with the help of cyclohexane-1,2-dicarboxylic acid anhydride, binders, polyester resins , for paint applications with a significantly lower viscosity compared to those based on isophthalic acidbe generated. This results in a higher processing solids content which is of great interest in times when a lot of attention is paid to environmental protection . [5] Processing solids are understood to be the non-volatile content of a paint system. Since the volatile components are mostly organic solvents ( VOC ), their share should be kept as low as possible. In addition to reducing the absolute amount of paint required or switching to aqueous systems, increasing the processing solids is the best option here.

In addition to being used as a binder in paints, cyclohexane-1,2-dicarboxylic acid anhydride can also be used as an anhydride hardener for epoxy resins . One application would be casting resin compounds which can cure at room temperature or at elevated temperatures. The higher price compared to phthalic anhydride should also be noted here. [6]

Structural formula

Structural formula of hexahydrophthalic anhydride(Hekzahidroftalik anhidrit )

General

Surname Cyclohexane-1,2-dicarboxylic anhydride

other names

HH-PSA

1,2-cyclohexanedicarboxylic anhydride

Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit )

Molecular formula C 8 H 10 O 3

Brief description

vitreous, colorless and odorless mass [1]

External identifiers / databases

CAS number 85-42-7

H and P phrases H: 317-318-334

P: 261-280-284-304 + 340-305 + 351 + 338 + 310 [1]

Authorization procedure under REACH

of particular concern : serious effects on human health are considered likely

Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit ) Chemical Properties,Uses,Production

Description

Hexahydrophthalic anhydride (HHPA(Hekzahidroftalik anhidrit )) is widely used for electronics applications, e.g. HHPA(Hekzahidroftalik anhidrit ) cured epoxy resins have excellent dielectric properties, high-temperature stability, and high glass transition temperatures. HHPA(Hekzahidroftalik anhidrit , Hexahydrophthalic anhydride) is used as a curing agent in adhesive coatings and sealant materials, e.g. for the second-generation two-part epoxy adhesive synthesis. Hexahydrophthalic anhydride is also used in the manufacture of alkyd and polyester resins, insecticides, and rust preventives.

References

[1] Guy Rabilloud, High Performance Polymers. Vol. 1 Conductive Adhesives, 1997

[2] John Burke Sullivan and Gary R. Krieger, Clinical Environmental Health and Toxic Exposures, 2001

[3] B. A. G. Jönsson, H. Welinder, C. Hansson and B. Ståhlbom, Occupational exposure to hexahydrophthalic anhydride(Hekzahidroftalik anhidrit ) : air analysis, percutaneous absorption, and biological monitoring, International Archives of Occupational and Environmental Health 1993, vol. 65, 43-47

Chemical Properties

White crystalline powder

Uses

Intermediate for alkyds, plasticizers, insect repellents, and rust inhibitors; hardener in epoxy resins.

Definition

ChEBI: A cyclic dicarboxylic anhydride that is the cyclic anhydride of hexahydrophthalic anhydride acid. (Hekzahidroftalik anhidrit )

Hazard

Toxic by inhalation, strong irritant to eyes and skin.

Purification Methods

It has been obtained by heating the trans-acid or anhydride at 200o. Crystallise it from *C6H6/Et2O or distil it. [Kohler & Jansen J Am Chem Soc 60 2145 1938, Abell J Org Chem 22 769 1957, Beilstein 17 II 452, 17 III/IV 5931.]

Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit ) Preparation Products And Raw materials

Raw materials

Tetrachlorophthalic anhydride

Preparation Products

Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit ) Suppliers

HHPA!is!a!solid!anhydride!hardener!for!epoxy!resins,!manufactured!by!Polynt!SpA.!Due!to!its!

high!resistance!to!discoloration,!HHPA!is!preferred!over!other!alicyclic!anhydrides!in!casting!and!

coating!applications.!In!addition, HHPA’s!low!melt!viscosity,!as!well!as!its!high!mix!ratio!with!

epoxy,!makes!it!particularly!suitable!for!applications!where!high!filler!loadings!are!required.!!

HHPA!is!also!used!as!an!intermediate!for!alkyds,!plasticizers,!insect!repellents!and!rust!

inhibitors.

Chemical!Name:!!!!!!!!! Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) !!!

Molecular!Formula: C8H10O3

Molecular!Weight:!!! 154.17

CAS!Number:!!!!!!!!!!!!!!85R42R7

Typical$Applications$for$HHPA$Cured$Epoxy$Resins

• Durable,!high!gloss,!weather!resistant!coatings!!

• Potting!compounds!

• Pressure!gelation!moldings!for!outdoor!electrical!applications

HexaHydroPhthalic Anhydride is a white solid or clear liquid if melted with molecular formula C8H10O3.

Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit )

HexaHydroPhthalic Anhydride Chemical Structure Composition.

Uses

HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit )

is mainly used as an intermediate for coating resins (alkyds, polyesters), plasticizers, sealant, curing agent in adhesive, insect repellents, rust inhibitors, electronics applications.

HHPA’s Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) low melt viscosity, as well as its high mix ratio with epoxy resins, makes it particularly suitable as hardener for epoxy resin for applications where high filler loadings are required.

HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) is preferred over other aromatic anhydrides in casting and coating applications for his higher resistance to yellowing.

HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) has high-temperature stability, excellent dielectric properties, and high glass transition temperatures.

Description: Hexahydrophthalic Anhydride (HHPA, Hekzahidroftalik anhidrit) is a saturated dicarboxylic anhydride and will undergo most of the reactions typical of this class of compounds. It is supplied as a white low-melting solid (38°C) which is miscible with most organic solvents. In water, it hydrolyzes to hexahydrophthalic anhydride acid Hekzahidroftalik anhidrit.

Application Information: Milldride HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) is a very effective curing agent for epoxy resins. It is also used in the preparation of alkyd and polyester resins where good color stability is important. HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) cured epoxies are characterized by reduced color and improved electrical and physical properties as compared to amine-cured products. The low melting point of HHPA allows it to be easily handled and blended with liquid resins. Viscosities of the HHPA-epoxy Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) mixtures are lower, pot life is extended in the absence of catalyst and curing reaction is less exothermic than with other hardeners. Areas of application including casting, laminating, embedding, coating, and impregnating electrical components.

Chemical Formula: C8H10O3

Post-shift and next-morning urine was sampled from workers exposed to hexahydrophtalic anhydride (HHPA) Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) , an epoxy hardener, sensitising at low exposure levels. Exposure levels of HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) in air (gas chromatography, GC) in the range of 30-270 micrograms/m3 corresponded to urinary concentrations of 0.9-2.8 mumol hexahydrophthalic anhydride acid (HHP acid Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) ; GC-mass spectrometry)/mmol creatinine. In the morning samples the concentrations were less than 0.04-0.3 mumol HHP Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) acid/mmol creatinine. In unexposed controls, the level was less than 0.1 mumol/mmol creatinine. A correlation was found between the time-weighted levels of HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) in air and HHP acid in the post-shift urine (rs = 0.93; P less than 0.023), indicating that the determination of HHP acid Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) in urine is suitable for biologic monitoring of HHPA Hexahydrophthalic Anhydride(Hekzahidroftalik anhidrit ) exposure.

Methyl hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) is produced from methyl tetrahydrophthalic anhydride by catalytic hydrogenation. It is a high-performance product among acid anhydride-type solidifying agent, not only has the typical performances as methyl tetrahydrophthalic anhydride: high purity, light color liquid, low viscosity, low volatility, low toxicity, low heating loss, stable performances, long use life, low freezing point, and can be stored for a long time under room temperature; but also has more excellent performances than that of methyl tetrahydrophthalic anhydride: colorless, transparent, basically unchange color after being added accelerant and epoxyl solidified substance appears white; good resistance to heat, especially under the temperature lower than 150°C, epoxyl solidified substance are of excellent mechanical and electric properties, excellent weatherability, not be affected by light and heat, good moisture resistance, high reaction activity, fast solidifying speed and short gelation time.

Uses:

1.as solidifying agent for epoxy resins: MHHPA hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) is heating-solidification type acid anhydride solidifying agent, mainly used in electrical and electronic field, with low melting point, the compounding matter with alicyclic epoxy resin is of low viscosity, long use life, excellent heat resistance and high-temperature electric properties, can be used in dipping of coil of electric apparatus, casting of electric parts and sealing of semiconductor.

2.as adhesive: the alicyclic epoxy adhesive made from MHHPA hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) has similar refractive index as optical glass, low internal stress after solidifying, high adhesion strength, color unchangeable, resistance to aging, applicable for cohering large-area optical parts.

3.as insecticide, plasticizer and antirust, etc.

method for manufacturing hexahydrophthalic anhydride diglycidyl ester is provided to improve outdoor weather resistance with maintaining heat resistance, transparency and electrical insulation. A method for manufacturing hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) diglycidyl ester comprises the steps of mixing hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) with epichlorohydrin in the presence of a solvent to produce hexahydrodicarboxylic acid by hydrolysis; mixing hexahydrodicarboxylic acid (Hekzahidroftalik anhidrit ) , epichlorohydrin and a catalyst to produce chlorohydrin ester capable of dechlorination; and putting the chlorohydrin ester to an alkali metal compound to produce hexahydrophthalic anhydride diglycidyl ester (See the reaction scheme).

Extraction and representation

Manufacture of HH-PSA

Usage

Cyclohexane-1,2-dicarboxylic acid anhydride is used as a monomer in various areas of polymer chemistry . So is z. B. to mention the application as an alternative to phthalic anhydride . What is desired here is better weather resistance, especially against UV light , with high hardness at the same time, which can be achieved by using hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) . [5] Furthermore, with the help of cyclohexane-1,2-dicarboxylic acid anhydride, binders, polyester resins , for paint applications with a significantly lower viscosity compared to those based on isophthalic acidbe generated. This results in a higher processing solids content which is of great interest in times when a lot of attention is paid to environmental protection . [5] Processing solids are understood to be the non-volatile content of a paint system. Since the volatile components are mostly organic solvents ( VOC ), their share should be kept as low as possible. In addition to reducing the absolute amount of paint required or switching to aqueous systems, increasing the processing solids is the best option here.

Structural formula

Structural formula of hexahydrophthalic anhydride(Hekzahidroftalik anhidrit )

General

Surname Cyclohexane-1,2-dicarboxylic anhydride

other names

HH-PSA

1,2-cyclohexanedicarboxylic anhydride

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

Molecular formula C 8 H 10 O 3

Brief description

vitreous, colorless and odorless mass [1]

H and P phrases H: 317-318-334

P: 261-280-284-304 + 340-305 + 351 + 338 + 310 [1]

Authorization procedure under REACH

of particular concern : serious effects on human health are considered likely

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) Chemical Properties,Uses,Production

Description

Hexahydrophthalic anhydride (HHPA, (Hekzahidroftalik anhidrit ) ) is widely used for electronics applications, e.g. HHPA (Hekzahidroftalik anhidrit, Hexahydrophthalic anhydride ) cured epoxy resins have excellent dielectric properties, high-temperature stability, and high glass transition temperatures. HHPA (Hekzahidroftalik anhidrit, Hexahydrophthalic anhydride ) is used as a curing agent in adhesive coatings and sealant materials, e.g. for the second-generation two-part epoxy adhesive synthesis. Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit) is also used in the manufacture of alkyd and polyester resins, insecticides, and rust preventives.

References

[1] Guy Rabilloud, High Performance Polymers. Vol. 1 Conductive Adhesives, 1997

[2] John Burke Sullivan and Gary R. Krieger, Clinical Environmental Health and Toxic Exposures, 2001

[3] B. A. G. Jönsson, H. Welinder, C. Hansson and B. Ståhlbom, Occupational exposure to hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) : air analysis, percutaneous absorption, and biological monitoring, International Archives of Occupational and Environmental Health 1993, vol. 65, 43-47

Chemical Properties

White crystalline powder

Uses

Intermediate for alkyds, plasticizers, insect repellents, and rust inhibitors; hardener in epoxy resins.

Definition

ChEBI: A cyclic dicarboxylic anhydride that is the cyclic anhydride of hexahydrophthalic anhydride acid. (Hekzahidroftalik anhidrit )

Hazard

Toxic by inhalation, strong irritant to eyes and skin.

Purification Methods

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) Preparation Products And Raw materials

Raw materials

Tetrachlorophthalic anhydride

Preparation Products

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) Suppliers

HHPA!is!a!solid!anhydride!hardener!for!epoxy!resins,!manufactured!by!Polynt!SpA.!Due!to!its!

high!resistance!to!discoloration,!HHPA!is!preferred!over!other!alicyclic!anhydrides!in!casting!and!

coating!applications.!In!addition, HHPA’s!low!melt!viscosity,!as!well!as!its!high!mix!ratio!with!

epoxy,!makes!it!particularly!suitable!for!applications!where!high!filler!loadings!are!required.!!

HHPA!is!also!used!as!an!intermediate!for!alkyds,!plasticizers,!insect!repellents!and!rust!

inhibitors.

Chemical!Name:!!!!!!!!! Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) !!!

Molecular!Formula: C8H10O3

Molecular!Weight:!!! 154.17

CAS!Number:!!!!!!!!!!!!!!85R42R7

Typical$Applications$for$HHPA$Cured$Epoxy$Resins

• Durable,!high!gloss,!weather!resistant!coatings!!

• Potting!compounds!

• Pressure!gelation!moldings!for!outdoor!electrical!applications

HexaHydroPhthalic Anhydride (Hekzahidroftalik anhidrit ) is a white solid or clear liquid if melted with molecular formula C8H10O3.

Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit )

HexaHydroPhthalic Anhydride (Hekzahidroftalik anhidrit ) Chemical Structure Composition.

Uses

HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) is mainly used as an intermediate for coating resins (alkyds, polyesters), plasticizers, sealant, curing agent in adhesive, insect repellents, rust inhibitors, electronics applications.

HHPA’s Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) low melt viscosity, as well as its high mix ratio with epoxy resins, makes it particularly suitable as hardener for epoxy resin for applications where high filler loadings are required.

HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) is preferred over other aromatic anhydrides in casting and coating applications for his higher resistance to yellowing.

HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) has high-temperature stability, excellent dielectric properties, and high glass transition temperatures.

Description: Hexahydrophthalic Anhydride (HHPA, (Hekzahidroftalik anhidrit ) ) is a saturated dicarboxylic anhydride and will undergo most of the reactions typical of this class of compounds. It is supplied as a white low-melting solid (38°C) which is miscible with most organic solvents. In water, it hydrolyzes to hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) acid.

Application Information: Milldride HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) is a very effective curing agent for epoxy resins. It is also used in the preparation of alkyd and polyester resins where good color stability is important. HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) cured epoxies are characterized by reduced color and improved electrical and physical properties as compared to amine-cured products. The low melting point of HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) allows it to be easily handled and blended with liquid resins. Viscosities of the HHPA-epoxy Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) mixtures are lower, pot life is extended in the absence of catalyst and curing reaction is less exothermic than with other hardeners. Areas of application including casting, laminating, embedding, coating, and impregnating electrical components.

Chemical Formula: C8H10O3

Post-shift and next-morning urine was sampled from workers exposed to hexahydrophtalic anhydride (HHPA, (Hekzahidroftalik anhidrit ) ), an epoxy hardener, sensitising at low exposure levels. Exposure levels of HHPA in air (gas chromatography, GC) in the range of 30-270 micrograms/m3 corresponded to urinary concentrations of 0.9-2.8 mumol hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) acid (HHP Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) acid; GC-mass spectrometry)/mmol creatinine. In the morning samples the concentrations were less than 0.04-0.3 mumol HHP Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) acid/mmol creatinine. In unexposed controls, the level was less than 0.1 mumol/mmol creatinine. A correlation was found between the time-weighted levels of HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) in air and HHP Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) acid in the post-shift urine (rs = 0.93; P less than 0.023), indicating that the determination of HHP acid in urine is suitable for biologic monitoring of HHPA Hexahydrophthalic Anhydride (Hekzahidroftalik anhidrit ) exposure.

Uses:

3.as insecticide, plasticizer and antirust, etc.

method for manufacturing hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) diglycidyl ester is provided to improve outdoor weather resistance with maintaining heat resistance, transparency and electrical insulation. A method for manufacturing hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) diglycidyl ester comprises the steps of mixing hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) with epichlorohydrin in the presence of a solvent to produce hexahydrodicarboxylic acid by hydrolysis; mixing hexahydrodicarboxylic acid, epichlorohydrin and a catalyst to produce chlorohydrin ester capable of dechlorination; and putting the chlorohydrin ester to an alkali metal compound to produce hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) diglycidyl ester (See the reaction scheme).

13 2012/10/18 Member State

Norway The Norwegian CA supports that hexahydrophthalic anhydride (HHPA, (Hekzahidroftalik anhidrit ) )fulfill the criteria of article 57 f) since evidence exists of serious effects to humans which give rise to equivalent level of concern as CMR substances. HHPA hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) is harmonized classified as a strong respiratory sensitizer (Resp. Sens. 1) in the CLP regulation and no “safe” no effect level can be derived as regards to the induction of sensitization. During the elicitation phase, the substance may evoke chronic inflammation of the lungs and this can lead to serious and permanent impairment of the lungs. The induced sensitization is irreversible, and exposure of the substance may result in a considerable increased risk of elicitation of respiratory sensitization of affected persons. This may cause limitations of normal working life and could require long term medication. We support that the criteria of article 57 f) is fulfilled and that this substance is of equivalent level of concern as CMR (Cat. 1 or 2) substances. HHPA should be identified as a SVHC substance. Member State

Sweden We agree with the argumentation put forward in the Annex XV dossier and therefore consider hexahydrophthalic anhydride – HHPA hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) to be a SVHC substance of equivalent level of concern according to Article 57(f). The substance is a classified respiratory sensitizer which may cause severe and irreversible health effects, which clearly affect the quality of life of affected individuals and also high costs for society. It is difficult to establish safe exposure levels for respiratory sensitizers like HHPA hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) , which is another reason for concern. Further, it is noted that this severe endpoint has not been taken into account by registrants in their chemical safety assessment in the Registration dossier.

1. Introduction of Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ), with the CAS registry number 85-42-7, is also known as 1,2-Cyclohexanedicarboxylic acid anhydride, 1,3-Isobenzofurandione, hexahydro-. It belongs to the product categories of Diels-Alder Adducts; Organics. What’s more, its systematic name is Hexahydro-2-benzofuran-1,3-dione. Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) can be used as coatings, epoxy curing agent, polyester resin, adhesive, plasticizer, intermediate of plasticizers and insect repellents. This chemical should be sealed and stored in a cool, ventilated and dry place. Moreover, it should be protected from moisture, sunburn and fire.

2. Properties of Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

(1)ACD/LogP: 0.762; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.76; (4)ACD/LogD (pH 7.4): 0.76; (5)ACD/BCF (pH 5.5): 2.24; (6)ACD/BCF (pH 7.4): 2.24; (7)ACD/KOC (pH 5.5): 61.91; (8)ACD/KOC (pH 7.4): 61.91; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 43.37 Å2; (13)Index of Refraction: 1.502; (14)Molar Refractivity: 36.813 cm3; (15)Molar Volume: 124.728 cm3; (16)Polarizability: 14.594×10-24cm3; (17)Surface Tension: 42.23 dyne/cm; (18)Density: 1.236 g/cm3; (19)Flash Point: 143.909 °C; (20)Enthalpy of Vaporization: 52.227 kJ/mol; (21)Boiling Point: 283.351 °C at 760 mmHg; (22)Vapour Pressure: 0.003 mmHg at 25°C.

3. Structure Descriptors of Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

(1)SMILES: O=C1OC(=O)C2C1CCCC2

(2)Std. InChI: InChI=1S/C8H10O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h5-6H,1-4H2

(3)Std. InChIKey: MUTGBJKUEZFXGO-UHFFFAOYSA-N

4. Safety Information of Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

Hazard Symbols:HarmfulXn

Risk Codes:

R41:Risk of serious damage to the eyes.

R42/43:May cause sensitization by inhalation and skin contact.

Safety Description:

S23:Do not breathe vapour.

S24:Avoid contact with skin.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S37/39:Wear suitable gloves and eye/face protection.

5. Preparation of Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit )

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) can be prepared by cyclohex-1-ene-1,2-dicarboxylic acid anhydride at the temperature of 95 °C. This reaction will need reagent H2 and solvent dimethylformamide with the reaction time of 3 hours. This reaction will also need catalyst Raney-Ni. The yield is about 88%.

1,3-Isobenzofurandione, hexahydro- can be prepared by cyclohex-1-ene-1,2-dicarboxylic acid anhydride at the temperature of 95 °C

6. Uses of Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit )

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) can be used to produce 2-trichloroacetyl-1-cyclohexanecarboxylic acid at the temperature of 60 °C. It will need reagent dibenzo-18-crown-6 and solvent acetonitrile with the reaction time of 6 hours. The yield is about 81%.

1,3-Isobenzofurandione, hexahydro- can be used to produce 2-trichloroacetyl-1-cyclohexanecarboxylic acid at the temperature of 60 °C

7. Other details of Hexahydrophthalic anhydride(Hekzahidroftalik anhidrit )

When you are using this chemical, please be cautious about it as the following:

Hexahydrophthalic anhydride (Hekzahidroftalik anhidrit ) has a risk of serious damage to eyes and it may cause sensitisation by inhalation and skin contact. You should not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). When using it, you must avoid contact with skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective gloves and eye/face protection.

Hekzahidroftalik anhidrit

Sikloheksan-1,2-dikarboksilik asit anhidrit , ayrca heksahidroftalik anhidrit Hexahydrophthalic anhydride, siklik karboksilik asit anhidritler grubundan kimyasal bir bileiktir . Bir sikloheksan halkas üzerinde orto pozisyonunda birlikte bir anhidrit oluturan iki karboksilik asit grubu vardr .

Çkarma ve temsil

Sikloheksan-1,2-dikarboksilik asit anhidrit, ftalik anhidritin nükleer hidrojenasyonu ile üretilir. [4] Bu ek ilem aamas, aromatik ftalik anhidrit ile karlatrldnda daha yüksek fiyatn bir nedenidir .

HH-PSA üretimi

Kullanm

Sikloheksan-1,2-dikarboksilik asit anhidrit, polimer kimyasnn çeitli alanlarnda bir monomer olarak kullanlr . Z de öyle. B. uygulamadan ftalik anhidrüre bir alternatif olarak deinmek . Burada arzu edilen , heksahidroftalik anhidrit Hexahydrophthalic anhydride kullanlarak elde edilebilen, ayn zamanda yüksek sertlik ile özellikle UV na kar daha iyi hava direncidir . [5] Ayrca, sikloheksan-1,2-dikarboksilik asit anhidrit, balayclar, polyester reçineler yardmyla , izoftalik asit esasl olanlara göre önemli ölçüde daha düük viskoziteli boya uygulamalar içinüretilecek. Bu , çevrenin korunmasna çok dikkat edildii zamanlarda büyük ilgi gören daha yüksek bir ileme kat içerii ile sonuçlanr . [5] Katlarn ilenmesi, bir boya sisteminin uçucu olmayan içerii olarak anlalr. Uçucu bileenler çounlukla organik çözücüler ( VOC ) olduundan, paylar mümkün olduunca düük tutulmaldr. Gerekli olan mutlak boya miktarn azaltmaya veya sulu sistemlere geçmeye ek olarak, ileme katlarn artrmak burada en iyi seçenektir.

Boyalarda balayc olarak kullanlmasnn yan sra, sikloheksan-1,2-dikarboksilik asit anhidrit , epoksi reçineler için bir anhidrit sertletirici olarak da kullanlabilir . Bir uygulama, oda scaklnda veya yüksek scaklklarda sertleebilen reçine bileiklerinin dökümü olabilir. Ftalik anhidrit ile karlatrldnda daha yüksek fiyat da burada belirtilmelidir. [6]

Yapsal formül

Heksahidroftalik anhidritin (Hexahydrophthalic anhydride) yapsal formülü

Genel

Soyad Sikloheksan-1,2-dikarboksilik anhidrit

dier isimler

HH-PSA

1,2-sikloheksandikarboksilik anhidrit

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride)

Moleküler formül C 8 H 10 O 3

Ksa açklama

cams, renksiz ve kokusuz kütle [1]

Yönetmelik (EC) No. 1272/2008 (CLP) ‘ den GHS tehlikeli madde etiketlemesi , [2] muhtemelen geniletilmi [1]

08 – Sala zararl 05 – Andrc

Tehlike

H ve P ifadeleri H: 317-318-334

P: 261-280-284-304 + 340-305 + 351 + 338 + 310 [1]

REACH kapsamnda yetkilendirme prosedürü

özellikle endie verici : insan sal üzerinde ciddi etkilerin muhtemel olduu düünülmektedir [3]

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Kimyasal Özellikleri, Kullanmlar, Üretimi

Açklama

Hekzahidroftalik anhidrit (HHPA, (Hexahydrophthalic anhydride)), elektronik uygulamalar için yaygn olarak kullanlmaktadr; örnein, HHPA (Hexahydrophthalic anhydride, Hekzahidroftalik anhidrit) ile kürlenmi epoksi reçineler, mükemmel dielektrik özelliklere, yüksek scaklk stabilitesine ve yüksek cam geçi scaklklarna sahiptir. HHPA(Hexahydrophthalic anhydride, Hekzahidroftalik anhidrit), yapkan kaplamalarda ve szdrmazlk malzemelerinde, örnein ikinci nesil iki parçal epoksi yapkan sentezi için bir kürleme ajan olarak kullanlr. Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) ayrca alkid ve polyester reçineleri, böcek öldürücüler ve pas önleyici maddelerin üretiminde de kullanlr.

Referanslar

[1] Guy Rabilloud, Yüksek Performansl Polimerler. Cilt 1 letken Yaptrclar, 1997

[2] John Burke Sullivan ve Gary R. Krieger, Klinik Çevre Sal ve Toksik Maruziyetler, 2001

[3] BAG Jönsson, H. Welinder, C. Hansson ve B. Ståhlbom, Hekzahidroftalik anhidrite mesleki maruziyet: hava analiz, perkütan absorpsiyon ve biyolojik izleme, Uluslararas Mesleki ve Çevre Sal Arivleri 1993, cilt. 65, 43-47

Kimyasal özellikler

Beyaz kristal toz

Kullanmlar

Alkidler, plastikletiriciler, böcek kovucular ve pas önleyiciler için ara ürün; epoksi reçinelerde sertletirici.

Tanm

ChEBI: Heksahidroftalik asidin siklik anhidriti olan bir siklik dikarboksilik anhidrit.

Tehlike

Solunduunda toksik, gözleri ve cildi kuvvetli tahri edicidir.

Saflatrma Yöntemleri

Trans-asit veya anhidritin 200 ° C’de stlmasyla elde edildi. * C6H6 / Et2O’dan kristalize edin veya damtn. [Kohler & Jansen J Am Chem Soc 60 2145 1938, Abell J Org Chem 22 769 1957, Beilstein 17 II 452, 17 III / IV 5931.]

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Hazrlama Ürünleri ve Hammaddeler

lenmemi içerikler

Tetrakloroftalik anhidrit (Hexahydrophthalic anhydride)

Hazrlk Ürünleri

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Tedarikçiler

Sikloheksan-1,2-dikarboksilik asit anhidrit , ayrca heksahidroftalik anhidrit (Hexahydrophthalic anhydride), siklik karboksilik asit anhidritler grubundan kimyasal bir bileiktir . Bir sikloheksan halkas üzerinde orto pozisyonunda birlikte bir anhidrit oluturan iki karboksilik asit grubu vardr .

Çkarma ve temsil

HH-PSA üretimi

Kullanm

Sikloheksan-1,2-dikarboksilik asit anhidrit, polimer kimyasnn çeitli alanlarnda bir monomer olarak kullanlr . Z de öyle. B. uygulamadan ftalik anhidrüre bir alternatif olarak deinmek . Burada arzu edilen , heksahidroftalik anhidrit (Hexahydrophthalic anhydride) kullanlarak elde edilebilen, ayn zamanda yüksek sertlik ile özellikle UV na kar daha iyi hava direncidir . [5] Ayrca, sikloheksan-1,2-dikarboksilik asit anhidrit, balayclar, polyester reçineler yardmyla , izoftalik asit esasl olanlara göre önemli ölçüde daha düük viskoziteli boya uygulamalar içinüretilecek. Bu , çevrenin korunmasna çok dikkat edildii zamanlarda büyük ilgi gören daha yüksek bir ileme kat içerii ile sonuçlanr . [5] Katlarn ilenmesi, bir boya sisteminin uçucu olmayan içerii olarak anlalr. Uçucu bileenler çounlukla organik çözücüler ( VOC ) olduundan, paylar mümkün olduunca düük tutulmaldr. Gerekli olan mutlak boya miktarn azaltmaya veya sulu sistemlere geçmeye ek olarak, ileme katlarn artrmak burada en iyi seçenektir.

Yapsal formül

Heksahidroftalik anhidritin (Hexahydrophthalic anhydride) yapsal formülü

Genel

Soyad Sikloheksan-1,2-dikarboksilik anhidrit

dier isimler

HH-PSA

1,2-sikloheksandikarboksilik anhidrit

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride)

Moleküler formül C 8 H 10 O 3

Ksa açklama

Yönetmelik (EC) No. 1272/2008 (CLP) ‘ den GHS tehlikeli madde etiketlemesi , [2] muhtemelen geniletilmi [1]

08 – Sala zararl 05 – Andrc

Tehlike

H ve P ifadeleri H: 317-318-334

P: 261-280-284-304 + 340-305 + 351 + 338 + 310 [1]

REACH kapsamnda yetkilendirme prosedürü

özellikle endie verici : insan sal üzerinde ciddi etkilerin muhtemel olduu düünülmektedir [3]

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Kimyasal Özellikleri, Kullanmlar, Üretimi

Açklama

Hekzahidroftalik anhidrit (HHPA, (Hexahydrophthalic anhydride)), elektronik uygulamalar için yaygn olarak kullanlmaktadr; örnein, HHPA (Hexahydrophthalic anhydride, Hekzahidroftalik anhidrit) ile kürlenmi epoksi reçineler, mükemmel dielektrik özelliklere, yüksek scaklk stabilitesine ve yüksek cam geçi scaklklarna sahiptir. HHPA (Hexahydrophthalic anhydride, Hekzahidroftalik anhidrit), yapkan kaplamalarda ve szdrmazlk malzemelerinde, örnein ikinci nesil iki parçal epoksi yapkan sentezi için bir kürleme ajan olarak kullanlr. Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) ayrca alkid ve polyester reçineleri, böcek öldürücüler ve pas önleyici maddelerin üretiminde de kullanlr.

Referanslar

[1] Guy Rabilloud, Yüksek Performansl Polimerler. Cilt 1 letken Yaptrclar, 1997

[2] John Burke Sullivan ve Gary R. Krieger, Klinik Çevre Sal ve Toksik Maruziyetler, 2001

Kimyasal özellikler

Beyaz kristal toz

Kullanmlar

Alkidler, plastikletiriciler, böcek kovucular ve pas önleyiciler için ara ürün; epoksi reçinelerde sertletirici.

Tanm

ChEBI: Heksahidroftalik asidin Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) siklik anhidriti olan bir siklik dikarboksilik anhidrit.

Tehlike

Solunduunda toksik, gözleri ve cildi kuvvetli tahri edicidir.

Saflatrma Yöntemleri

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Hazrlama Ürünleri ve Hammaddeler

lenmemi içerikler

Tetrakloroftalik anhidrit (Hexahydrophthalic anhydride)

Hazrlk Ürünleri

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride) Tedarikçiler

1. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), tantm

CAS kayt numaras 85-42-7 olan hekzahidroftalik anhidrit (Hexahydrophthalic anhydride),, 1,2-Sikloheksandikarboksilik asit anhidrit, 1,3-zobenzofurandion, hekzahidro- olarak da bilinir. Diels-Alder Adducts ürün kategorilerine aittir; Organikler. Dahas, sistematik ad Hexahydro-2-benzofuran-1,3-dion’dur. Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride),, kaplamalar, epoksi kürleme maddesi, polyester reçine, yaptrc, plastikletirici, plastikletirici ara maddesi ve böcek kovucu olarak kullanlabilir. Bu kimyasal kapatlmal ve serin, havalandrlan ve kuru bir yerde saklanmaldr. Ayrca nemden, güne yanklarndan ve yangndan korunmaldr.

2. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), özellikleri

(1) ACD / LogP: 0.762; (2) 5 hlal Kuralnn Says: 0; (3) ACD / LogD (pH 5.5): 0.76; (4) ACD / LogD (pH 7.4): 0.76; (5) ACD / BCF (pH 5.5): 2.24; (6) ACD / BCF (pH 7.4): 2.24; (7) ACD / KOC (pH 5.5): 61.91; (8) ACD / KOC (pH 7.4): 61.91; (9) #H ba alclar: 3; (10) #H ba baçlar: 0; (11) # Serbest Dönen Balar: 0; (12) Kutupsal Yüzey Alan: 43.37 Å2; (13) Krlma Endeksi: 1.502; (14) Molar Krlma: 36.813 cm3; (15) Molar Hacim: 124.728 cm3; (16) Polarize edilebilirlik: 14.594 × 10-24cm3; (17) Yüzey Gerilimi: 42.23 din / cm; (18) Younluk: 1,236 g / cm3; (19) Parlama Noktas: 143.909 ° C; (20) Buharlama Entalpisi: 52.227 kJ / mol; (21) Kaynama Noktas: 283.351 ° C, 760 mmHg’de; (22) Buhar Basnc: 25 ° C’de 0,003 mmHg.

3. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), Yap Tanmlayclar

(1) SMILES: O = C1OC (= O) C2C1CCCC2

(2) Std. InChI: InChI = 1S / C8H10O3 / c9-7-5-3-1-2-4-6 (5) 8 (10) 11-7 / h5-6H, 1-4H2

(3) Std. InChIKey: MUTGBJKUEZFXGO-UHFFFAOYSA-N

4. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), Güvenlik Bilgileri

Tehlike Sembolleri: ZararlXn

Risk Kodlar:

R41: Gözlerde ciddi hasar riski.

R42 / 43: Solunduunda ve cilt ile temasnda hassasiyet oluturabilir.

Güvenlik Açklamas:

S23: Buhar solumayn.

S24: Cilt ile temasndan saknn.

S26: Göz ile temas halinde bol su ile ykayn ve tbbi yardm aln.

S37 / 39: Uygun eldiven ve göz / yüz korumas kullann.

5. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), hazrlanmas

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride), 95 ° C scaklkta sikloheks-1-en-1,2-dikarboksilik asit anhidrid ile hazrlanabilir. Bu reaksiyon, reaksiyon süresi 3 saat olan reaktif H2 ve çözücü dimetilformamide ihtiyaç duyacaktr. Bu reaksiyon ayrca katalizör Raney-Ni’ye ihtiyaç duyacaktr. Verim yaklak% 88’dir.

1,3-zobenzofurandion, hekzahidro- 95 ° C scaklkta sikloheks-1-en-1,2-dikarboksilik asit anhidrit ile hazrlanabilir

6. Hekzahidroftalik anhidritin (Hexahydrophthalic anhydride), Kullanm Alanlar

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride),, 60 ° C scaklkta 2-trikloroasetil-1-sikloheksankarboksilik asit üretmek için kullanlabilir. Reaktif dibenzo-18-taç-6 ve 6 saatlik reaksiyon süresine sahip çözücü asetonitrile ihtiyaç duyacaktr. Verim yaklak% 81’dir.

1,3-zobenzofurandion, heksahidro, 60 ° C scaklkta 2-trikloroasetil-1-sikloheksankarboksilik asit üretmek için kullanlabilir.

7. Hekzahidroftalik anhidritin(Hexahydrophthalic anhydride), dier ayrntlar

Bu kimyasal kullanrken, lütfen aadaki gibi dikkatli olun:

Hekzahidroftalik anhidrit (Hexahydrophthalic anhydride), gözlere ciddi zarar verme riski tar ve solunduunda ve cilt ile temasnda hassasiyete neden olabilir. Gaz / duman / buhar / sprey solumamalsnz (uygun ifadeler üretici tarafndan belirtilecektir). Kullanrken cilt ile temasndan kaçnmalsnz. Göz ile temasnda derhal bol su ile ykamal ve tbbi yardm almalsnz. Kullanrken uygun koruyucu eldivenler ve göz / yüz korumas kullanmanz gerekir.

HEKZAHDROFTALK ANHDRT (HEXAHYDROPHTHALIC ANHYDRIDE)

Table of Contents

HEKZAHDROFTALK ANHDRT (HEXAHYDROPHTHALIC ANHYDRIDE)

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