TETRA ISOPROPYL TITANATE
Tetra isopropyl titanate, a chemical compound with the formula Ti{OCH(CH3)2}4, is commonly used as a precursor or catalyst in various chemical processes, including the synthesis of organic and inorganic materials.
Tetra isopropyl titanate is typically used as a metal catalyst in producing polyolefins and polycarbonate, improving the yield of olefin polymerization, esterification, condensation, and addition reactions while eliminating unwanted byproducts.
Tetra isopropyl titanate, also known as titanium tetraisopropoxide, is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.
CAS Number: 546-68-9
EC Number: 208-909-6
Molecular Formula: C12H28O4Ti
Molecular Weight: 284.22
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Tetra isopropyl titanate can be used as an esterification catalyst for plasticizers, polyesters, methacrylic esters, resins, polycarbonates, polyolefins and RTV silicone sealants.
Tetra isopropyl titanate can also be used for coating chemicals as a cross linker for wire enamel varnish, glass and zinc flake coatings.
Tetra isopropyl titanate is most suitable for use in the glass and glass fiber manufacturing. TIPA may be used as an adhesion promoter for packaging ink such as flexo and gravure.
Tetra isopropyl titanate, is a chemical compound with the formula Ti{OCH(CH3)2}4.
This alkoxide of titanium(IV) is used in organic synthesis and materials science.
Tetra isopropyl titanate is a diamagnetic tetrahedral molecule.
Tetra isopropyl titanate is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.
The structures of the Tetra isopropyl titanates are often complex.
Crystalline titanium methoxide is tetrameric with the molecular formula Ti4(OCH3)16.
Alkoxides derived from bulkier alcohols such as isopropyl alcohol aggregate less.
Tetra isopropyl titanate is mainly a monomer in nonpolar solvents.
Tetra isopropyl titanate is a titanium alkoxide, specifically a tetraalkoxy derivative of titanium.
Tetra isopropyl titanate is commonly used as a precursor or catalyst in various chemical processes, including the synthesis of organic and inorganic materials.
The “tetraisopropyl” part of the name indicates that there are four isopropyl (C3H7) groups bonded to the titanium atom.
Tetra isopropyl titanate is often employed in the preparation of sol-gel derived materials, coatings, and as a crosslinking agent in the production of polymers.
Tetra isopropyl titanate is reactivity with hydroxyl-containing compounds makes it useful in bonding processes and surface modification applications.
As with many titanium alkoxides, Tetra isopropyl titanate is sensitive to moisture, and precautions are often taken to handle it under dry conditions.
Tetra isopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol.
Tetra isopropyl titanate, vapors heavier than air.
Tetra isopropyl titanate is used in organic synthesis and materials science.
Tetra isopropyl titanate is a diamagnetic tetrahedral molecule.
Tetra isopropyl titanate, about the same density as water.
The structures of the Tetra isopropyl titanate are often complex.
Crystalline Tetra isopropyl titanate is tetrameric with the molecular formula Ti4(OCH3)16.
Alkoxides derived from bulkier alcohols such as Tetra isopropyl titanate aggregate less.
Tetra isopropyl titanate is mainly a monomer in nonpolar solvents.
Tetra isopropyl titanate is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.
Tetra isopropyl titanate is a widely used item of commerce and has acquired many names in addition to those listed in the table.
Tetra isopropyl titanate belongs to the product group of organic titanates, which are known to be highly reactive organics that can be used in a broad range of processes and applications.
Tetra isopropyl titanate a colorless, slighty yellowish liquid that is very sensitive to moisture.
Tetra isopropyl titanate has a complex structure.
Tetra isopropyl titanate, also commonly referred to as titanium tetraisopropoxide or is a chemical compound with the formula Ti{OCH(CH3)2}4.
Tetra isopropyl titanate is a component of the Sharpless epoxidation, a method for the synthesis of chiral epoxides.
In crystalline state, Tetra isopropyl titanate is a tetramer.
Non-polymerized in non-polar solvents,Tetra isopropyl titanate is a tetrahedral diamagnetic molecule.
Tetra isopropyl titanate, also known as titanium isopropoxide, titanium tetraisopropoxide is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Tetra isopropyl titanate has a complex structure.
In crystalline state, Tetra isopropyl titanate is a tetramer.
Non-polymerized in non-polar solvents, Tetra isopropyl titanate is a tetrahedral diamagnetic molecule.
Tetra isopropyl titanate is an intermediate derived from titanium.
Tetra isopropyl titanate appears as a light yellow, transparent liquid.
Tetra isopropyl titanate can be used as a catalyst additive in coating primers or added to that formulation as an adhesion promoter.
Tetra isopropyl titanate is a type of very lively primary alcohol titanium oxide; Tetra isopropyl titanate hydrolyzes when contacted with moisture in air.
Tetra isopropyl titanate is mainly used as catalyst in esterification reaction or transesterification,also being used as catalyst of polyolefin.
Tetra isopropyl titanate can be used to improve the adherence and crosslinking of resin having alcohol group or carboxyl group, used in heat resistant and corrosion resistant coating.
Tetra isopropyl titanate also can be used in the manufacture of glass and glass fiber.
Tetra isopropyl titanate can only be used in oil system.
Tetra isopropyl titanate, also known as titanium isopropoxide, titanium tetraisopropoxide is the isopropoxide of titanium (IV), used in organic synthesis and materials science.
Tetra isopropyl titanate is a 100% active tetra-isopropyl titanate in liquid form.
Tetra isopropyl titanate is typically used as a metal catalyst in producing polyolefins and polycarbonate.
Tetra isopropyl titanate improves the yield of olefin polymerization, esterification, condensation, and addition reactions while eliminating unwanted byproducts.
Compared to other Tetra isopropyl titanate, Tetraisopropyl titanate is highly moisture sensitive and will decompose when exposed to water.
Tetra isopropyl titanate is useful as a replacement for tin, organostannanes, and sulfuric acid in esterification reactions when toxicity reduction is desired.
Tetra isopropyl titanate is even more efficient than sulfuric acid in esterification reactions.
When added to solvent-based paints, Tetra isopropyl titanate will cross-link hydroxyl and carboxyl functional polymers to increase chemical and heat resistance.
Tetra isopropyl titanate is also used as a catalyst in the preparation of certain cyclopropanes in the Kulinkovich reaction.
Prochiral thioethers are oxidized enantioselectively using a catalyst derived from Ti(O-i-Pr)4.
Tetra isopropyl titanate reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH
This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
Tetra isopropyl titanate, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.
Tetra isopropyl titanate, isopropyl alcohol and liquid ammonia are esterified in toluene, absorbed and filtered to remove by-product ammonium chloride, and then distilled to obtain the finished product.
Raw material consumption (kg/t) toluene (98%) 1000 titanium tetrachloride (99%) 1500 isopropanol (98%) 1600 liquid ammonia 1400
Tetra isopropyl titanate will be easily ignited by heat, sparks or flames.
Tetra isopropyl titanate vapors may form explosive mixtures with air.
Tetra isopropyl titanate vapors may travel to source of ignition and flash back.
Tetra isopropyl titanate vapors are heavier than air.
Tetra isopropyl titanate will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
Tetra isopropyl titanate vapor explosion hazard indoors, outdoors or in sewers.
Tetra isopropyl titanate designated with a may polymerize explosively when heated or involved in a fire.
Tetra isopropyl titanate runoff to sewer may create fire or explosion hazard.
Tetra isopropyl titanate containers may explode when heated.
Tetra isopropyl titanate many liquids will float on water.
Metal alkyls, such as Tetra isopropyl titanate, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones.
Tetra isopropyl titanate, they are likely to ignite on contact with alcohols.
Tetra isopropyl titanate is highly flammable.
Tetra isopropyl titanate fumes in air. Soluble in water.
Tetra isopropyl titanate decomposes rapidly in water to form flammable isopropyl alcohol.
Uses of Tetra Isopropyl Titanate:
Tetra isopropyl titanate is widely used in sol-gel processing, a method for producing ceramics and thin films.
Tetra isopropyl titanate is a precursor in the formation of titanium dioxide (TiO2) thin films, which find applications in optical coatings, sensors, and photovoltaic devices.
Tetra isopropyl titanate can be used as a crosslinking agent in the production of polymers.
Tetra isopropyl titanate reacts with polymers containing hydroxyl groups, contributing to the crosslinking of the polymer chains.
This enhances the mechanical and thermal properties of the polymers.
Tetra isopropyl titanate is employed as an adhesion promoter in coatings and adhesives.
Tetra isopropyl titanate helps improve the adhesion of coatings to various substrates, such as metals, glass, and ceramics.
Tetra isopropyl titanate is used for surface modification of materials, particularly in the development of functionalized surfaces with improved properties.
This can be relevant in areas like biomaterials and catalysis.
Tetra isopropyl titanate is sometimes used as a catalyst or a component in catalyst formulations, especially in reactions involving transesterification or esterification processes.
Tetra isopropyl titanate serves as a reagent in various chemical synthesis processes, contributing to the formation of new compounds.
In the rubber industry, Tetra isopropyl titanate can be used as a crosslinking agent for elastomers, contributing to improved mechanical properties and stability.
Tetra isopropyl titanate can be used as a photocatalyst in environmental applications, such as air and water purification.
Tetra isopropyl titanate can also be used as surface modifier, adhesion promoter and paraffin and oil additives.
Tetra isopropyl titanate for ester exchange reaction.
Tetra isopropyl titanate used as an auxiliary agent and chemical product intermediate.
Tetra isopropyl titanate used to make adhesives, used as a catalyst for transesterification and polymerization reactions.
Binders for preparing metals and rubber, metals and plastics, also used as catalysts for transesterification and polymerization reactions and raw materials for the pharmaceutical industry.
Tetra isopropyl titanate for esterification reaction, transesterification reaction of acrylic acid and other esters.
Tetra isopropyl titanate in polymerization reactions such as epoxy resin, phenolic plastic, silicone resin, polybutadiene, etc., Tetra isopropyl titanate has high stereoselectivity.
Tetra isopropyl titanate, a variety of polymers or resins play a cross-linking role, improve the anti-corrosion ability of the coating, etc., and also promote the adhesion of the coating to the surface.
Tetra isopropyl titanate can be directly used as material surface modifier, adhesive promoter.
Tetra isopropyl titanate especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2.
Tetra isopropyl titanate complexing agent in sol-gel process.
Tetra isopropyl titanate is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films.
Tetra isopropyl titanate is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes.
Tetra isopropyl titanate is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides.
Tetra isopropyl titanate is involved as a catalyst in the preparation of cyclopropanes.
Tetra isopropyl titanate can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Tetra isopropyl titanate is used in the following products: pH regulators and water treatment products, laboratory chemicals and water treatment chemicals.
Tetra isopropyl titanate is used in the following areas: health services and scientific research and development.
Tetra isopropyl titanate is used for the manufacture of: Chemicals.
Release to the environment of Tetra isopropyl titanate can occur from industrial use: manufacturing of the substance.
Other release to the environment of Tetra isopropyl titanate is likely to occur from : ndoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).
Tetra isopropyl titanate is used in the following products: polymers, fuels, coating products, lubricants and greases, pH regulators and water treatment products and laboratory chemicals.
Tetra isopropyl titanate has an industrial use resulting in manufacture of another substance.
Tetra isopropyl titanate is used in the following areas: health services and scientific research and development.
Tetra isopropyl titanate is used for the manufacture of: chemicals and plastic products.
Release to the environment of Tetra isopropyl titanate can occur from industrial use: as processing aid, as an intermediate step in further manufacturing of another substance (use of intermediates), of substances in closed systems with minimal release and in processing aids at industrial sites.
Tetra isopropyl titanate for the esterification reaction is used for the transesterification reaction of esters such as acrylic acid and the polymerization of epoxy resin, phenolic plastic, silicone resin, polybutadiene, PP and PE.
Tetra isopropyl titanate can also be used as raw materials for the pharmaceutical industry and the preparation of metal and rubber, metal and plastic adhesives.
Tetra isopropyl titanate for the Sharpless asymmetric epoxidation reaction of allyl alcohol; as a Tetra isopropyl titanate for transesterification reaction with various alcohols under neutral conditions; titanium tetraisopropoxide can be formed by a sol-gel two-step method New metal oxide/phosphonate hybrid; used as a raw material for barium strontium titanate film; used to prepare porous titanosilicate, which is a potential ion exchange material for removing radioactive waste; Tetraisopropyl titanateis used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes.
Tetra isopropyl titanate has been proved that it can undergo light-induced electron transfer
Tetra isopropyl titanate is mainly used for transesterification and condensation reactions in organic synthesis Catalyst.
Tetra isopropyl titanate is often used as a precursor to prepare titanium dioxide (TiO2).
A new metal oxide/phosphonate hybrid can be formed from Tetra isopropyl titanate by sol-gel two-step method.
The raw material of barium strontium Tetra isopropyl titanate film.
Tetra isopropyl titanate is used to prepare porous titanosilicates, which are potential ion exchange materials for the removal of radioactive wastes.
Tetra isopropyl titanate is used to form heterogeneous supramolecules composed of TiO2 nanocrystals-violet essence electron acceptor complexes, which have been shown to be capable of light-induced electron transfer.
Tetra isopropyl titanate can be used directly or in directly as a catalyst or catlyst additive,as a coating primer or added to formulation as a adhesion promoter and as the base material in the formation fo sol-get systems or nanoparticle systems or products.
Tetra isopropyl titanate can be used as sharpless oxidation catalyst.
Tetra isopropyl titanate can be used as a precursor for ambient conditions vapour phase deposition such as infiltration into polymer thin films.
Tetra isopropyl titanate is used in the formulation of coatings and paints.
Tetra isopropyl titanate can contribute to improved adhesion, durability, and weather resistance of the coatings.
In the ceramics industry, Tetra isopropyl titanate is utilized as a precursor for the synthesis of ceramic materials, including ceramics used in electronic components.
Tetra isopropyl titanate can be employed in glass manufacturing processes, contributing to the improvement of certain properties of glass, such as hardness and scratch resistance.
Tetra isopropyl titanate has been investigated for its potential use in fuel cell applications.
Tetra isopropyl titanate can be part of the fabrication process for materials used in fuel cell technologies.
The hydrophobic nature of Tetra isopropyl titanate-derived coatings makes them suitable for applications where water repellency is desired, such as in self-cleaning surfaces or anti-fog coatings.
Tetra isopropyl titanate is sometimes used in the formulation of coatings designed to provide corrosion resistance to metal surfaces.
Tetra isopropyl titanate can be used as a modifier to impart certain properties to fabrics, such as water repellency or flame retardancy.
Tetra isopropyl titanate has been explored for use in antimicrobial coatings, which can find applications in healthcare settings and other areas where bacterial resistance is a concern.
Tetra isopropyl titanate is employed in the production of thin films for electronic devices, such as semiconductors and sensors.
Tetra isopropyl titanate-derived materials are used in the production of thin films for photovoltaic devices, contributing to the development of solar cells.
Tetra isopropyl titanate can be used as a bonding agent, improving the performance and durability of adhesives.
Tetra isopropyl titanate is a valuable tool in research and development for exploring new materials and synthesizing compounds with specific properties.
Coating Industry uses:
Tetra isopropyl titanate is commonly used as a catalyst in the coating industry.
Tetra isopropyl titanate’s purpose in this field involves promoting the curing process of coatings and improving their overall performance.
The mechanism of action in coatings involves the initiation and acceleration of chemical reactions, leading to the formation of a durable and protective coating layer.
Polymer Industry uses:
Tetra isopropyl titanate is also utilized in the polymer industry as a crosslinking agent.
Tetra isopropyl titanate’s purpose in this field involves creating strong chemical bonds between polymer chains, resulting in enhanced mechanical properties and stability of the polymers.
The mechanism of action in polymer crosslinking involves the formation of covalent bonds between the Tetra isopropyl titanate and the polymer chains, leading to a three-dimensional network structure.
TiO2 pigments and films:
Micro- or nano-scale TiO2 pigments can be formed from Tetra isopropyl titanate.
Tetra isopropyl titanate can also be used to create a polymeric TiO2 film on surfaces via pyrolytic or hydrolytic processes.
Hair-making uses:
Tetra isopropyl titanate, isopropyl alcohol, and liquid ammonia were heated and dissolved in toluene as a solvent to undergo an esterification reaction.
The reaction product was filtered off by-product ammonium chloride by suction, and the product was obtained by distillation.
Usage In Glass Industry:
Tetra isopropyl titanate is commonly used as a cross-linking agent and catalyst in the glass industry.
Anti-reflective coatings:
Tetra isopropyl titanate is often used as a cross-linking agent in anti-reflective coatings for glass.
The coating helps to reduce glare and improve visibility, making Tetra isopropyl titanate ideal for applications like eyeglasses, camera lenses, and flat panel displays.
Self-cleaning coatings:
Tetra isopropyl titanate is also used to create self-cleaning coatings for glass.
When exposed to sunlight, the coating reacts with oxygen to produce free radicals that break down organic matter on the surface of the glass.
This helps to keep the glass clean and reduces the need for manual cleaning.
Pigments:
As I mentioned earlier, Tetra isopropyl titanate is used as a precursor for the synthesis of titanium dioxide (TiO2) nanoparticles.
These nanoparticles are used as pigments in glass and ceramic applications, providing improved optical properties and color saturation.
They are often used in products like decorative glassware, ceramic tiles, and automotive glass.
Scratch-resistant coatings:
Tetra isopropyl titanate can also be used to create scratch-resistant coatings for glass.
When added to the coating, Tetra isopropyl titanate reacts with the hydroxyl groups on the surface of the glass to create a durable, cross-linked network.
This network helps to protect the glass from scratches, abrasion, and chemical damage, making Tetra isopropyl titanate ideal for applications like smartphone screens and protective eyewear.
Usage In Ink Industry:
Tetra isopropyl titanate is commonly used in the ink industry as a cross-linking agent and as a catalyst for polymerization reactions.
Here are some specific ways that Tetra isopropyl titanate is used in the ink industry:
UV-curable inks:
Tetra isopropyl titanate is often used as a cross-linking agent in UV-curable inks.
When exposed to UV light, the ink undergoes a polymerization reaction that cross-links the ink molecules and hardens the ink film. Tetra isopropyl titanate can be added to the ink formulation to promote cross-linking and improve the ink’s adhesion, durability, and resistance to abrasion and chemical attack.
Pigment dispersions:
Tetra isopropyl titanate is also used as a dispersant in pigment dispersions for ink formulations.
Tetra isopropyl titanate helps to stabilize the pigment particles and prevent them from settling out of the ink.
This improves the color consistency and print quality of the ink.
Metal printing:
Tetra isopropyl titanate can be used as a catalyst for the polymerization of acrylic resins used in metal printing.
The resin is applied to the metal substrate as an ink and then cured using Tetra isopropyl titanate as a catalyst.
This creates a durable and scratch-resistant coating on the metal surface.
Inkjet printing:
Tetra isopropyl titanate can be added to inkjet inks as a cross-linking agent to improve the ink’s adhesion and durability on various substrates, such as paper, plastic, and metal.
Overall, Tetra isopropyl titanate is a valuable tool in the ink industry, helping to improve the performance and quality of ink formulations.
Tetra isopropyl titanate’s ability to promote cross-linking, stabilize pigments, and catalyze polymerization reactions makes it a versatile material for ink manufacturers.
Features of Tetra Isopropyl Titanate:
Organic compound composed of titanium and isopropyl groups
Colorless liquid with a low melting point
Low toxicity and is considered relatively safe to handle
Reacts readily with water and air
Other Features:
Balanced pH value, Purity
Non-toxic
Safe to use
Benefits of Tetra Isopropyl Titanate:
Versatile:
Tetra isopropyl titanate is a versatile compound that can be used in various industries, including pigment production, organic synthesis, and polymer synthesis.
Efficient:
As a catalyst, Tetra isopropyl titanate can facilitate organic reactions in a fast and efficient manner.
High-quality products:
Tetra isopropyl titanate is used as a precursor for the production of high-quality titanium dioxide pigment used in paints, cosmetics, and food products.
Precursor for other compounds:
Tetra isopropyl titanate is used as a starting material for the synthesis of other titanium compounds.
Adhesion promoter:
Tetra isopropyl titanate can also act as an adhesion promoter, improving the adhesion of coatings and adhesives to various substrates.
Overall, the features and benefits of Tetra isopropyl titanate make it a valuable compound in various industries, providing an efficient and versatile solution for the production of high-quality products.
Air And Water Reactions of Tetra Isopropyl Titanate:
Tetra isopropyl titanate fumes in the air.
Tetra isopropyl titanate is soluble in water.
Tetra isopropyl titanate decomposes rapidly in water to form flammable isopropyl alcohol.
Preparation of Tetra Isopropyl Titanate:
Tetra isopropyl titanate is prepared by treating titanium tetrachloride with isopropanol.
Hydrogen chloride is formed as a coproduct:
TiCl4 + 4 (CH3)2CHOH → Ti{OCH(CH3)2}4 + 4 HCl
Purification Methods of Tetra Isopropyl Titanate:
Dissolve Tetra isopropyl titanate in dry *C6H6 , filter if a solid separates, evaporate and fractionate.
Tetra isopropyl titanate is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o
Properties of Tetra Isopropyl Titanate:
Tetra isopropyl titanate reacts with water to deposit titanium dioxide:
Ti{OCH(CH3)2}4 + 2 H2O → TiO2 + 4 (CH3)2CHOH
This reaction is employed in the sol-gel synthesis of TiO2-based materials in the form of powders or thin films.
Typically water is added in excess to a solution of the alkoxide in an alcohol.
The composition, crystallinity and morphology of the inorganic product are determined by the presence of additives (e.g. acetic acid), the amount of water (hydrolysis ratio), and reaction conditions.
Tetra isopropyl titanate is also used as a catalyst in the preparation of certain cyclopropanes in the Kulinkovich reaction.
Prochiral thioethers are oxidized enantioselectively using a catalyst derived from Ti(O-i-Pr)4.
Handling And Storage of Tetra Isopropyl Titanate:
Precautions for safe handling:
Advice on safe handling:
Work under hood.
Take precautionary measures against static discharge.
Hygiene measures:
Change contaminated clothing.
Wash hands after working with substance.
Conditions for safe storage, including any incompatibilities
Storage conditions:
Handle under nitrogen, protect from moisture.
Store under nitrogen.
Keep container tightly closed in a dry and well-ventilated place.
Hydrolyzes readily
Stability And Reactivity of Tetra Isopropyl Titanate:
Reactivity:
Metal alkyls, such as Tetra isopropyl titanate, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones.
Thus, they are likely to ignite on contact with alcohols.
Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
May decompose on exposure to moist air or water.
Possibility of hazardous reactions:
No data available
Safety Profile of Tetra Isopropyl Titanate:
Tetra isopropyl titanate is flammable.
Tetra isopropyl titanate should be stored away from open flames, sparks, and heat sources.
Adequate ventilation is essential to prevent the accumulation of flammable vapors.
Tetra isopropyl titanate reacts violently with water, releasing flammable gases.
Tetra isopropyl titanate should be kept away from moisture, and contact with water or humid conditions should be avoided.
Tetra isopropyl titanate is corrosive to metals.
Tetra isopropyl titanate can cause corrosion and damage to certain materials.
Tetra isopropyl titanatecan cause irritation to the skin and eyes.
Protective equipment, such as gloves and safety goggles, should be worn when handling Tetra isopropyl titanate.
First Aid Measures of Tetra Isopropyl Titanate:
General advice:
Show this material safety data sheet to the doctor in attendance.
If inhaled:
After inhalation:
Fresh air.
Call in physician.
In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
In case of eye contact:
After eye contact:
Rnse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
Indication of any immediate medical attention and special treatment needed:
No data available
Fire Fighting Measures of Tetra Isopropyl Titanate:
Extinguishing media:
Suitable extinguishing media:
Foam
Carbon dioxide (CO2)
Dry powder
Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
Further information:
Remove container from danger zone and cool with water.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Accidental Release Measures of Tetra Isopropyl Titanate:
Environmental precautions:
Do not let product enter drains.
Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.
Exposure Controls/Personal Protection of Tetra Isopropyl Titanate:
Personal protective equipment:
Eye/face protection:
Use equipment for eye protection.
Safety glasses
Skin protection:
Handle with gloves.
Wash and dry hands.
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Body Protection:
Flame retardant antistatic protective clothing.
Respiratory protection:
Recommended Filter type: Filter type ABEK
Control of environmental exposure:
Do not let product enter drains.
Identifiers of Tetra Isopropyl Titanate:
CAS Number: 546-68-9
EC number: 208-909-6
MDL number: MFCD00008871
Molecular Formula: C12H28O4Ti
EINECS Number: 208-909-6
HS Code: 29051900
IUPAC Name: Titanium Isopropoxide
InChI: 1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChIKey: VXUYXOFXAQZZMF-UHFFFAOYSA-N
Melting Point: 18-20 °C
Molar Mass: 284.26 g/mol
Molecular Formula: C12H28O4Ti
NFPA 704: H-1,F-2,R-0,C-NA
PG: 3
RTECS Number: NT8060000
Refractive: n20/D 1.464
Properties of Tetra Isopropyl Titanate:
Melting point : 14-17 °C(lit.)
Boiling point : 232 °C(lit.)
Density : 0.96 g/mL at 20 °C(lit.)
Vapor pressure : 60.2hPa at 25℃
Refractive index : n20/D 1.464(lit.)
Fp : 72 °F
Storage temp. : Flammables area
Solubility : Soluble in anhydrous ethanol, ether, benzene and chloroform.
Form : Liquid
Color : Colorless to pale yellow
Specific Gravity : 0.955
Water Solubility : HYDROLYSIS
FreezingPoint : 14.8℃
Sensitive : Moisture Sensitive
Hydrolytic Sensitivity : 7: reacts slowly with moisture/water
Merck : 14,9480
BRN : 3679474
Stability : Stable, but decomposes in the presence of moisture.
Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
InChIKey : VXUYXOFXAQZZMF-UHFFFAOYSA-N
LogP : 0.05
CAS DataBase Reference : 546-68-9(CAS DataBase Reference)
EPA Substance Registry System : 2-Propanol, titanium(4+) salt (546-68-9)
Character light yellow liquid, smoke in humid air.
boiling point 102~104 ℃
freezing point 14.8 ℃
relative density 0.954g/cm3
refractive index 1.46
soluble in a variety of organic solvents.
Kinematic viscosity: Not available
Dynamic viscosity: 3 mPa.s at 25 °C
Water solubility: Insoluble
Partition coefficient (n-octanol/water): Not available
Vapor pressure: 1.33 hPa at 63 °C
Density: 0.96 g/mL at 20 °C
Relative density: 0.96 at 25 °C
Relative vapor density: Not available
Particle characteristics: Not available
Explosive properties: Not available
Oxidizing properties: None
Other safety information: Not available
Molecular Weight: 284.22 g/mol
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 4
Rotatable Bond Count: 0
Exact Mass: 284.1467000 g/mol
Monoisotopic Mass: 284.1467000 g/mol
Topological Polar Surface Area: 92.2 Ų
Heavy Atom Count: 17
Complexity: 10.8
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 5
Compound Is Canonicalized: Yes