ZINC DIMETHYLDITHIOCARBAMATE (ZDMC)
ZINC DIMETHYLDITHIOCARBAMATE (ZDMC)
Zinc Dimethyldithiocarbamate (ZDMC) is one of the most commonly used accelerators in natural rubber latex technology because of the properties of the corresponding vulcanizates.
Zinc Dimethyldithiocarbamate (ZDMC) is a fast-curing primary or secondary ultra-accelerator in BR, EPDM, IR, NBR, NR, and SBR polymers and their latexes.
Synonym(s): Zinc dimethyl dithiocarbamate, Dimethyldithiocarbamic acid zinc salt, Ziram, Bis(dimethyldithiocarbamoto-S,S’)zinc, DIMACIT ZDMC, Perkacit ZDMC, Ziram P, ZINC BIS DIMETHYLDITHIOCARBAMATE, (T-4)-bis(Dimethylcarbamodithioato-S,S’)zinc, zinc bis(dimethylcarbamodithioate), zinc bis(dimethyldithiocarbamate), zinc N,N-dimethylcarbamodithioate, Zinc N,N-dimethyldithiocarbamate, ZINC ME2DTC;
Linear Formula: (CH3)2NCSSZnSCSN(CH3)2
Mol. formula: C6H12N2S4Zn
CAS Number: 137-30-4
Molecular Weight: 305.82
EC Number: 205-288-3
MDL Number: MFCD00064797
PubChem Substance ID: 24859808
Typical Properties of Zinc Dimethyldithiocarbamate:
Appearance: Creamy-white powder
Density: +/-0.40 g/mL
Molecular Formula: C6H12N2S4Zn
Molecular Weight: 305.8
Octanol-water partition coefficient, log Pow: 1.086
Solubility: Insoluble in water
Zinc Dimethyldithiocarbamate (ZDMC) is active over a wide temperature range and is usually used with a thiazole modifier.
Zinc Dimethyldithiocarbamate (ZDMC) is often used as a secondary accelerator. In latex, better results are obtained when combined with thiazole accelerators.
Zinc Dimethyldithiocarbamate (ZDMC) is also used for rubber-coated fabrics, latex products, and rubber cement.
Zinc Dimethyldithiocarbamate is an accelerator in vulcanized rubber.
ZDMC (Zinc Dimethyldithiocarbamate) is a creamy-white powder used in the rubber industry.
Zinc Dimethyldithiocarbamate is widely used in rubber processing as an ultra accelerator for low-temperature cures, alone or activating for other accelerators, chiefly the thiazoles.
Zinc Dimethyldithiocarbamate (ZDMC) can be used:
Without sulfur (2 – 4% on the weight of the gum)
With sulfur in conjunction with zinc oxide and fatty acid as activators (0.1 – 1 % TMTD on the weight of the gum)
In conjunction with accelerators such as mercaptobenzothiazole (0.25 – 0.5 TMTD on the weight of the gum)
Zinc Dimethyldithiocarbamate (ZDMC) accelerates the rapid vulcanization of natural- and synthetic rubber such as NBR, SBR, and EPDM.
ZDMC provides excellent tensile and resilience properties.
ZDMC, Zinc Dimethyldithiocarbamate, is recommended as an antioxidant for improving resistance to aging.
ZDMC Zinc Dimethyldithiocarbamate offers a longer scorch time and a faster total curing time.
Application of Zinc Dimethyldithiocarbamate (Ziram) in CROP PROTECTION (AGRICULTURE)
Zinc Dimethyldithiocarbamate (Ziram) is a Broad-spectrum, protectant fungicide with excellent disease control and Multisite mode of action.
Ziram fungicide (Zinc Dimethyldithiocarbamate) is a broad-spectrum, protectant fungicide that helps protect fruits, nuts, ornamentals, and vegetables from disease development with multisite activity.
Zinc Dimethyldithiocarbamate is a multisite fungicide (group M3) that inhibits spore germination and mycelium growth by interfering with various enzymes involved in the respiration process.
Its ability to act on many sites of the biochemical process ensures that Zinc Dimethyldithiocarbamate remains at low risk for resistance development and retains its efficacy against many fungi.
Ziram (Zinc dimethyldithiocarbamate) is a dimethyldithiocarbamate fungicide that controls fungal diseases on stone fruits, pome fruits, nut crops, vegetables, and ornamentals.
Zinc Dimethyldithiocarbamate is used to prevent crop damage in the field and is also applied before harvesting to prevent fruits from deteriorating in storage or transport.
Additionally, ZDMC Zinc Dimethyldithiocarbamate is a preservative in adhesives, caulks, sealants, wallboard, and exterior latex paint (in-can-preservative).
Zinc Dimethyldithiocarbamate ZDMC is also registered for residential use as a rabbit repellant on outdoor ornamentals.
Zinc Dimethyldithiocarbamate is also an agricultural fungicide for seeds, plants, and fruits and a repellent for birds and rodents.
Special Application of Zinc Dimethyldithiocarbamate:
Zinc Dimethyldithiocarbamate is also used in metalworking as a lubricant and corrosion inhibitor.
Storage of Zinc Dimethyldithiocarbamate:
Store in a dry, well-ventilated place away from foodstuffs.
No reduction in the assay of the active substance has been observed after storage for 2 years in the original packing under normal conditions.
Use explosion-proof electrical equipment.
Protects against acids and substances liberating acids.
In accidental spillage, the split product should be collected for incineration.
Notify the appropriate authorities immediately if there is any risk of contamination of watercourses.
Translated names
Ziraam (ISO) Tsink bis dimetüülditiokarbamaat (et)
Ziraami (ISO) Sinkkibis(dimetyyliditiokarbamaatti) (fi)
ziram (ISO) bis(dimetyloditiokarbaminian) cynku (pl)
ziram (ISO) cink-bisz(dimetilditiokarbamát) (hu)
ziram (ISO) zinkium-bis(dimetylditiokarbamát) (sk)
Ziram(ISO) bis dimetilditiocarbamat de zinc (ro)
ziramas (ISO) cinko bis(N,Ndimetilditiokarbamatas) (lt)
цирам (ISO) цинков бис диметилдитиокарбамат (bg)
IUPAC names
bis[(dimethylcarbamothioyl)sulfanyl]zinc
UPV1
ziram (ISO)
Zinc bis dimethyldithiocarbamate
zinc bis dimethyldithiocarbamate
zinc bis(dimethylcarbamodithioate)
zinc bis(dimethyldithiocarbamate)
Zinc Dimethyldithiocarbamate
zinc dimethyldithiocarbamate
zinc N,N-dimethylcarbamodithioate
Zinc N,N-dimethyldithiocarbamate
Zinc, bis(N,N-dimethylcarbamodithioato-.kappa.S,.kappa.S’)-, (T-4)-
zinc;N,N-dimethylcarbamodithioate
Ziram
ziram (ISO)
Trade names
Perkacit ZDMC pdr
Perkacit ZDMC pdr-d
ZDMC
Ziram P
OTHER NAMES:
Zinc dimethyldithiocarbamate; (T-4)-Bis(dimethyldithiocarbamato-S,S’)zinc (9CI); Aaprotect; Aaprotent; Aavolex; Aazira; Accelerator L; Aceto ZDED; Aceto zdmd; Alcobam ZM; Antene; Bis(N,N-dimetil-ditiocarbammato) di zinco [Italian]; Bis(dimethylcarbamodithioato-S,S’)zinc; Bis(dimethyldithiocarbamato)zinc; Bis-dimethyldithiocarbamate de zinc [French]; Carbamic acid, dimethyldithio-, zinc salt (2:1); Carbamodithioic acid, dimethyl-, zinc salt; Carbazinc; Corona corozate; Corozate; Crittam; Crittan; Cuman; Cuman L; Cymate; Dimethylcarbamodithioic acid, zinc complex; Dimethylcarbamodithioic acid, zinc salt; Dimethyldithiocarbamate zinc salt; Dimethyldithiocarbamic acid, zinc salt; Drupina 90; ENT 988; Eptac 1; Fuclasin; Fuclasin Ultra; Fuclasin-ultra; Fuklasin; Fungostop; Hermat ZDM; Hexazir; Karbam White; Methasan; Methazate; Methyl Ziram; Methyl zimate; Methyl zineb; Methyl zineb (VAN); Mezene; Micosin F30; Milbam; Molurame; Mycronil; Nocceler pz; Orchard brand ziram; Pomarsol Z forte; Pomarzol Z-forte; Prodaram; Ramedit; Rhodiacid; Rhodiacid (VAN); Rodisan; Sabceler PZ; Soxinal PZ; Soxinol PZ; Tricarbamix Z; Trikagol; Triscabol; Tsimat; Tsiram [Russian]; Vancide MA-96; Vancide MZ-96; Vulcacure ZM; Vulkacit L; Vulkacite L; Weisstaub; Z 75; Z-C spray; Z-C-Spray; Zarlate; Zerlate; Zimate; Zimate, methyl; Zinc N,N-dimethyldithiocarbamate; Zinc bis(dimethyldithiocarbamate); Zinc bis(dimethyldithiocarbamoyl) disulfide; Zinc bis(dimethyldithiocarbamoyl)disulphide; Zinc bis(dimethylthiocarbamoyl) disulfide; Zinc bis(dimethylthiocarbamoyl)disulfide; Zinc dimethyl dithiocarbamate; Zinc, bis(dimethylcarbamodithioato-S,S’)-, (T-4)-; Zinc, bis(dimethyldithiocarbamato)-; Zink-(N,N-dimethyl-dithiocarbamat) [German]; Zink-bis(N,N-dimethyl-dithiocarbamaat) [Dutch]; Zink-bis(N,N-dimethyl-dithiocarbamat) [German]; Zinkcarbamate; Ziradin; Ziram (VAN); Ziram Granuflo; Ziram technical; Zirame; Zirame [ISO-French]; Ziramvis; Zirasan; Zirasan 90; Zirberk; Ziretec; Zirex 90; Zirex Fungicide; Ziride; Zirthane; Zitox; Zinc, bis(dimethylcarbamodithioato-S,S’)-; Zinc, bis(dimethylcarbamodithioato-S,S’)-, (beta-4)-; Zinc, bis(dimethylcarbamodithioato-kappaS,kappaS’)-, (T-4)-; [ChemIDplus] UN2771
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